Skip to main content
SpringerLink
Log in

Synthesis and electrochemical performance of LiNi0.475Mn0.475Al0.05O2 as cathode material for lithium-ion battery from Ni–Mn–Al–O precursor

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

LiNi0.475Mn0.475Al0.05O2 cathode material was prepared by solid-state reaction using Ni–Mn–Al–O solid solution as precursor. The solid solution is of spinel structure, in which nickel, manganese, and aluminum are sufficiently mixed at atomic level. Rietveld refinement of X-ray diffraction data revealed that Al doping in LiNi0.5Mn0.5O2 was significantly effective to decrease the degree of Li/Ni cation mixing. XPS analysis showed that the valence states of nickel and manganese were mainly +2 and +4, respectively. LiNi0.475Mn0.475Al0.05O2 delivered a stable capacity of about 206 mAh g−1 with high reversibility. High-rate capability test was also performed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Ohzuku T, Majumura Y (2001) Chem Lett 30:744–745

    Article  Google Scholar 

  2. Makimura Y, Ohzuku T (2003) J Power Sources 119–121:156–160

    Article  Google Scholar 

  3. Kang K, Meng YS, Breger J, Grey CP, Ceder G (2006) Science 311:977–980

    Article  CAS  Google Scholar 

  4. Hinuma Y, Meng YS, Kang K, Ceder G (2007) Chem Mater 19:1790–1800

    Article  CAS  Google Scholar 

  5. Lu Z, MacNeil DD, Dahn JR (2001) Electrochem Solid-State Lett 4:A191–A194

    Article  CAS  Google Scholar 

  6. Lu Z, Beaulieu LY, Donaberger RA, Thomas CL, Dahn JR (2002) J Electrochem Soc 149:A778–A791

    Article  CAS  Google Scholar 

  7. Chou J, Kim Y, Kim G (2007) J Phys Chem C 111:3192–3196

    Article  Google Scholar 

  8. Zhang B, Chen G, Xu P, Li CC (2008) J Power Sources 176:325–331

    Article  CAS  Google Scholar 

  9. Komaba S, Yoshii K, Ogata A, Nakai I (2009) Electrochim Acta 54:2353–2359

    Article  CAS  Google Scholar 

  10. Zhang B, Chen G, Liang Y, Xu P (2009) Solid State Ionics 180:398–404

    Article  CAS  Google Scholar 

  11. Fergus JW (2010) J Power Sources 195:939–954

    Article  CAS  Google Scholar 

  12. Zhou F, Zhao X, Lu Z, Jiang J, Dahn JR (2008) Electrochem Solid-State Lett 11:A155–A157

    Article  CAS  Google Scholar 

  13. Li DC, Muta T, Noguchi H (2004) J Power Sources 135:262–266

    Article  CAS  Google Scholar 

  14. Li D, Noguchi H (2003) ITE Lett Batter New Technol Med 4:303–307

    CAS  Google Scholar 

  15. Meng XL, Dou SM, Wang W-L (2008) J Power Sources 184:489–493

    Article  CAS  Google Scholar 

  16. Ju SH, Jang HC, Kang YC (2008) Mater Chem Phys 112:536–541

    Article  CAS  Google Scholar 

  17. Myung S-T, Komaba S, Hirosaki N, Hosoya K, Kumagai N (2005) J Power Sources 146:645–649

    Article  CAS  Google Scholar 

  18. Luo W, Dahn JR (2009) Electrochim Acta 54:4655–4661

    Article  CAS  Google Scholar 

  19. Luo W, Dahn JR (2009) Chem Mater 21:56–62

    Article  CAS  Google Scholar 

  20. Shaju KM, Subba Rao GV, Chowdari BVR (2002) Electrochim Acta 48:145–151

    Article  CAS  Google Scholar 

  21. Carley AF, Jackson SD, O’Shea JN, Roberts MW (1999) Surf Sci 440:L868–L874

    Article  CAS  Google Scholar 

  22. Amine K, Tukamoto H, Yasuda H, Fujita Y (1996) J Electrochem Soc 143:1607–1613

    Article  CAS  Google Scholar 

  23. Mansour AN (1996) Surf Sci Spectra 3:279–286

    Article  Google Scholar 

  24. Kang SH, Kim J, Stoll ME, Abraham D, Sun YK, Amine K (2002) J Power Sources 112:41–48

    Article  CAS  Google Scholar 

  25. Schougaard B, Breger J, Jiang M, Grey CP, Goodenough JB (2006) Adv Mater 18:905–909

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by a grand from Natural Science Foundation of Anhui Province (Grant No. 090414178).

Author information

Authors and Affiliations

  1. Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, 230026, People’s Republic of China

    Shumei Dou, Wen-lou Wang, Hongju Li & Xiaodong Xin

Authors
  1. Shumei Dou
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wen-lou Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hongju Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaodong Xin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Wen-lou Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dou, S., Wang, Wl., Li, H. et al. Synthesis and electrochemical performance of LiNi0.475Mn0.475Al0.05O2 as cathode material for lithium-ion battery from Ni–Mn–Al–O precursor. J Solid State Electrochem 15, 747–751 (2011). https://doi.org/10.1007/s10008-010-1151-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-010-1151-4

Keywords

Search

Navigation