Abstract
A simple electrodepositing method was proposed for fabricating a uniform, tight, and close-packed TiO2 nanocrystalline film on the ITO substrate. The electrode and dye-sensitized solar cell (DSSC) with electrodeposited TiO2 layer were characterized by scanning electron microscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The phthalocyanin dye, zinc tetra-carboxyl phthalocyanin complex, was used as a model dye to evaluate the influence of close-packed TiO2 blocking layer on the photocurrent–voltage property. On the electrodeposition, the close-packed TiO2 layer could effectively inhibit the recombination of charges, and therefore improve the performances of the corresponding cells. The effects of film thickness on light transmittance and photocurrent density of the corresponding cell were also demonstrated. The optimum film thickness was found to be approximately 400 nm. At the optimum thickness, the photocurrent density greatly increased comparing with that of the screen printing TiO2 film. These results imply that our proposition was a potential and feasible method for the fabrication of DSSC practically.
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O’Regan B, Grätzel M (1991) Nat 353:737. doi:10.1038/353737a0
Grätzel M (2003) J Photochem Photobiol Chem 4:145. doi:10.1016/S1389-5567(03)00026-1
Wang ZS, Kawauchi H, Kashima T, Arakawa H (2004) Coord Chem Rev 248:1381. doi:10.1016/j.ccr.2004.03.006
He JJ, Benkö G, Korodi F, Polívka T, Lomoth R, Åkermark B, Sun LC, Hagfeld A, Sundström V (2002) J Am Chem Soc 124:4922. doi:10.1021/ja0178012
Cameron PJ, Peter LM (2003) J Phys Chem B 107:14394. doi:10.1021/jp030790+
Yum J-H, Kim S-S, Kim D-Y, Sung Y-E (2005) J Photochem Photobiol A 173:1. doi:10.1016/j.jphotochem.2004.12.023
Ito S, Liska P, Comte P, Charvet R, Péchy P, Bach U, Schmidt-Mende L, Zakeeruddin SM, Kay A, Nazeeruddin MK, Grätzel M (2005) Chem Commun (Camb) 5:4351. doi:10.1039/b505718c
Peng B, Jungmanna G, Jäger C, Haarer D, Schmidt HW, Thelakkat M (2004) Coord Chem Rev 248:1479. doi:10.1016/j.ccr.2004.02.008
Hart JN, Menzies D, Cheng YB, Simon GP, Spiccia L (2006) C R Chim 9:622
Zhu K, Schiff EA, Park NG, van de Lagemaat J, Frank AJ (2002) Appl Phys Lett 80:685. doi:10.1063/1.1436533
Acher BN, Fohlen GM, Parker JA, Keshavayya J (1988) Indian J Chem Sect A 27:411
Bisquert J (2002) J Phys Chem B 106:325. doi:10.1021/jp011941g
Kern R, Sastrawan R, Ferber J, Stangl R, Luther J (2002) Electrochim Acta 47:4213. doi:10.1016/S0013-4686(02)00444-9
Adachi M, Sakamoto M, Jiu J, Ogata Y, Isoda S (2006) J Phys Chem B 110:13872. doi:10.1021/jp061693u
Zhang JJ, Wu M, Qin YT, Chen R, Jiang YH, Sun YM, Yang ZH (2008) Acta Phys Chim Sin 24:79
Bard AJ, Faulkner LR (1980) Electrochemical methods: fundamentals and applications. Wiley, New York
Stoynov ZB, Grafov BM, Savova-Stoynova BS, Elkin VV (1991) Electrochemical impedance. Nauka, Moscow
Chen A, La Russa DJ, Miller B (2004) Langmuir 20:9695. doi:10.1021/la0484873
Cameron PJ, Peter LM, Hore S (2005) J Phys Chem B 109:930. doi:10.1021/jp0405759
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This research was sponsored by the National Basic Research Program of China (2007CB936300).
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Wu, M., Yang, Z.H., Jiang, Y.H. et al. Improvement of dye-sensitized solar cell performance through electrodepositing a close-packed TiO2 film. J Solid State Electrochem 14, 857–863 (2010). https://doi.org/10.1007/s10008-009-0866-6
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DOI: https://doi.org/10.1007/s10008-009-0866-6