Abstract
Nanostructured MnO2/carbon nanotubes composite electrode material was prepared using the liquid-phase deposition reaction starting with potassium permanganate (KMnO4) and manganese acetate (Mn(Ac)2·4H2O) as the reactants and carbon nanotubes (CNTs) as the substrates. The structure and morphology of the material was characterized by X-ray diffraction, infrared spectroscopy, and transmission electron microscope techniques. The electrochemical properties of the nano-MnO2/CNTs composite electrode in 1 M LiAc and 1 M MgSO4 solutions and in 1 M RAc (R = Li, Na, and K)–1 M MgSO4 mixed solutions, respectively, were studied. Experimental results demonstrated that the specific capacitance and rate discharge ability of the nano-MnO2/CNTs composite electrode in 1 M LiAc–1 M MgSO4 mixed solution is superior to that in 1 M LiAc or 1 M MgSO4 solution. For the 1 M RAc (R = Li, Na, and K)–1 M MgSO4 mixed electrolytes, the specific capacitance of the composite electrode was found to be in the following order: LiAc > NaAc > KAc.
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References
Conway BE (1991) J Electrochem Soc 138:1539
Zheng JP, Cygan PJ, Jow TR (1995) J Electrochem Soc 142:2699
Nam KW, Yoon WS, Kim KB (2002) Electrochim Acta 47:3201
Srinivasan V, Weidner JW (2002) J Power Sources 108:15
Lee HY, Goodenough JB (1999) J Solid State Chem 144:220
Pang SC, Anderson MA, Chapman TW (2000) J Electrochem Soc 147:444
Toupin M, Brousse T, Bélanger D (2002) Chem Mater 14:3946
Reddy RN, Reddy RG (2003) J Power Sources 124:330
Prasad KR, Miura N (2004) J Power Sources 135:354
Chen YS, Hu CC, Wu YT (2004) J Solid State Electrochem 8:467
Subramanian V, Zhu HW, Vajtai R, Ajayan PM, Wei BQ (2005) J Phys Chem B 109:20207
Broughton JN, Brett MJ (2005) Electrochim Acta 50:4814
Nam KW, Kim KB (2006) J Electrochem Soc 153:A81
Kuo SL, Wu NL (2006) J Electrochem Soc 153:A1317
Brousse T, Toupin M, Dugas R, Athouël L, Crosnier O, Bélanger D (2006) J Electrochem Soc 153:A2171
Chun SE, Pyun SI, Lee GJ (2006) Electrochim Acta 51:6479
Hong MS, Lee SH, Kim SW (2002) Electrochem Solid-State Lett 5:A227
Brousse T, Toupin M, Bélanger D (2004) J Electrochem Soc 151:A614
Khomenko V, Raymundo-Piñero E, Béguin F (2006) J Power Sources 153:183
Wu YT, Hu CC (2004) J Electrochem Soc 151:A2060
Zhou YK, He BL, Zhang FB, Li HL (2004) J Solid State Electrochem 8:482
Raymundo-Piñero E, Khomenko V, Frackowiak E, Béguin F (2005) J Electrochem Soc 152:A229
Lee CY, Tsai HM, Chuang HJ, Li SY, Lin P, Tseng TY (2005) J Electrochem Soc 152:A716
Wang GX, Zhang BL, Yu ZL, Qu MZ (2005) Solid State Ionics 176:1169
Subramanian V, Zhu HW, Wei BQ (2006) Electrochem Commun 8:827
Fan Z, Chen JH, Wang MY, Cui KZ, Zhou HH, Kuang YF (2006) Diam Relat Mater 15:1478
Ma SB, Ahn KY, Lee ES, Oh KH, Kim KB (2007) Carbon 45:375
Zhang ML, Yang C, Chen Y, Xue Y (2004) Chin J Power Sources 28:626
Ananth M V, Pethkar S, Dakshinamurthi K (1998) J Power Sources 75:278
Toupin M, Brousse T, Bélanger D (2004) Chem Mater 16:3184
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Wang, Y., Yuan, A. & Wang, X. Pseudocapacitive behaviors of nanostructured manganese dioxide/carbon nanotubes composite electrodes in mild aqueous electrolytes: effects of electrolytes and current collectors. J Solid State Electrochem 12, 1101–1107 (2008). https://doi.org/10.1007/s10008-007-0445-7
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DOI: https://doi.org/10.1007/s10008-007-0445-7