Abstract
Although the electrochemical reduction of carbon dioxide (CO2) with a copper electrode produces hydrocarbons, the activity toward the conversion of CO2 is lost for several 10 min by the deposition of poisoning species on the electrode. To solve the poisoning species problem, the electrochemical reduction of CO2 was carried out using a copper electrode with a pulse electrolysis mode with anodic as well as cathodic polarization. The anodic polarization intervals suppressed the deposition of poisoning species on the electrode, and the amount of two hydrocarbons, CH4 and C2H4, barely decreased even after an hour. By choosing appropriate anodic potential and time duration, the selectivity for the C2H4 formation was greatly enhanced. The enhancement was found to be due to the copper oxide formed on the copper electrode. The selectivity was further improved when the electrochemical reduction was made with the copper-oxide electrode. The highest efficiency of about 28% is obtained at −3.15 V.
References
Oman H (1998) Chemtech 116
Orr JC, Fabry VJ, Aumont O, Bopp L, Doney SC, Feely RA, Gnanadesikan A, Gruber N, Ishida A, Joos F, Key RM, Lindsay K, Maier-Reimer E, Matear R, Monfray P, Mouchet A, Najjar RG, Plattner G, Rodgers KB, Sabine CL, Sarmiento JL, Schlitzer R, Slater RD, Totterdell IJ, Weirig M, Yamanaka Y, Yool A (2005) Nature 437:681
Fischer F, Priziza O (1914) Ber Deut Chem Ges 47:256
Hori Y, Kikuchi K, Suzuki S (1985) Chem Lett 1695
Hori Y, Kikuchi K, Murata A, Suzuki S (1986) Chem Lett 897
Hori Y, Murata A, Takahashi R, Suzuki S (1988) J Chem Soc Chem Commun 17
Hori Y, Murata A, Yoshinami Y (1991) J Chem Soc Faraday Trans 87:125
Hori Y, Wakebe H, Tsukamoto T, Koga O (1994) Electrochim Acta 39:1833
Smith BD, Irish DE, Kedzierzawski P, Aaugustynski J (1997) J Electrochem Soc 144:4288
Kyriacou G, Anagnostopoulos A (1992) J Electroanal Chem 328:233
DeWuff DW, Jim T, Bard AJ (1989) J Electrochem Soc 136:1686
Wasmus S, Cattaneo E, Vielstish W (1990) Electrochim Acta 35:771
Friebe P, Bogdanoff P, Alonso-Vante N, Tributsch H (1997) J Catal 168:374
Lee J, Tak Y (2001) Electrochim Acta 46:3015
Hori Y, Konishi H, Futamura T, Murata A, Koga O, Sakurai H, Oguma K (2005) Electrochim Acta 50:5354
Ogura K, Sugihara H, Yano J, Higasa M (1994) J Electrochem Soc 141:419
Kita H, Kurisu T (1973) J Res Inst Catal Hokkaido Univ 21:200
Hori Y (1996) Electrochemistry 64:1048
Ogura K (2003) Electrochemistry 71:676
Acknowledgements
Helpful discussion with Professor Akira Kitani of Hiroshima University is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yano, J., Morita, T., Shimano, K. et al. Selective ethylene formation by pulse-mode electrochemical reduction of carbon dioxide using copper and copper-oxide electrodes. J Solid State Electrochem 11, 554–557 (2007). https://doi.org/10.1007/s10008-006-0181-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-006-0181-4