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A novel chemically modified carbon paste electrode based on a new mercury(II) complex for selective potentiometric determination of bromide ion

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Abstract

A new modified carbon paste electrode based on a recently synthesized mercury (II) complex of a pyridine containing proton transfer compound as a suitable carrier for Br− ion is described. The electrode has a linear dynamic range between 3.00×10−2 and 1.0×10−5 M with a near-Nernastian slope of 61.0±0.9 mV per decade and a detection limit of 4.0×10−6 M (0.32 ppm). The potentiometric response is independent of the pH of the solution in the pH range 4.0–8.3. The electrode possesses the advantages of low resistance, fast response and good over a variety of other anions. It was applied as an indicator electrode in potentiometric titration of bromide ions and for the recovery of Br− from tap water.

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Authors and Affiliations

  1. Department of Chemistry, Razi University, Kermanshah, Iran

    Mojtaba Shamsipur, Sohrab Ershad & Naser Samadi

  2. Department of Chemistry, Imam Hossein University, Tehran, Iran

    Abloghasem Moghimi

  3. Department of Chemistry, Teacher Training University, Tehran, Iran

    Hossein Aghabozorg

Authors
  1. Mojtaba Shamsipur
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  2. Sohrab Ershad
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  3. Naser Samadi
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  4. Abloghasem Moghimi
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  5. Hossein Aghabozorg
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Correspondence to Mojtaba Shamsipur.

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Shamsipur, M., Ershad, S., Samadi, N. et al. A novel chemically modified carbon paste electrode based on a new mercury(II) complex for selective potentiometric determination of bromide ion. J Solid State Electrochem 9, 788–793 (2005). https://doi.org/10.1007/s10008-005-0692-4

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  • DOI: https://doi.org/10.1007/s10008-005-0692-4

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