Skip to main content

Advertisement

SpringerLink
Log in

Electrochemical characterization of cobalt cordierites attached to paraffin-impregnated graphite electrodes

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

The electrochemistry of α, β and μ cobalt-containing cordierites (Co2Al4Si5O18) attached to paraffin-impregnated graphite electrodes has been studied by linear scan and cyclic voltammetries in HCl+NaCl and NaOH electrolytes. This electrochemistry is compared with that of vitreous cobalt cordierite, cobalt(II) oxide and cobalt spinel aluminate (CoAl2O4), the two last taken as reference materials. Electrochemical processes involve the site-characteristic reduction of Co(II) species to cobalt metal near to −0.5 V vs. SCE and their oxidative dissolution near +0.3 V, accompanied by solid state interconversion between Co(II) and Co(III) at potentials above +0.45 V. Cordierite-modified electrodes display a significant site-dependent catalytic effect on the electrochemical oxidation of mannitol in 0.10 M NaOH.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Watanabe K, Giess EA (1985) J Am Ceram Soc 68:C102

    CAS  Google Scholar 

  2. Watanabe K, Giess EA, Shafer MW (1985) J Mater Sci 20:508

    CAS  Google Scholar 

  3. Karkhanavala MD, Hummel FA (1953) J Am Ceram Soc 36:389

    CAS  Google Scholar 

  4. Gibbs GV (1966) Am Mineral 51:1068

    CAS  Google Scholar 

  5. Meagher EP, Gibbs GV (1977) Can Mineral 15:43

    Google Scholar 

  6. Putnis A (1980) Contrib Mineral Petrol 74:135

    CAS  Google Scholar 

  7. Goldman DS, Rossman GR, Dollase WA (1977) Am Mineral 62:1144

    CAS  Google Scholar 

  8. Selkregg KR, Bloss FD (1980) Am Mineral 65:522

    CAS  Google Scholar 

  9. Ikawa H, Otagiri T, Imal O, Suzuki M, Urabe K, Udagawa S (1986) J Am Ceram Soc 69:492

    CAS  Google Scholar 

  10. Sundar S, Vepa VSS, Umarji AM (1993) J Am Ceram Soc 76:1873

    Google Scholar 

  11. Chen YF, Rabu P, Pourroy G, Vilminot S (1995) Eur J Solid State Inorg Chem 32:1065

    CAS  Google Scholar 

  12. Wandscheneider P, Seifert F (1984) J Am Ceram Soc 67:C163

    Google Scholar 

  13. Sales M, Alarcón J (1995) J Mater Sci 30:2341

    CAS  Google Scholar 

  14. Villegas MA, Alarcón J (2002) J Eur Ceram Soc 22:487

    Article  CAS  Google Scholar 

  15. Torres FJ, Alarcón J (2003) J Eur Ceram Soc (in press)

  16. Scholz F, Meyer B (1998) In: Bard AJ. Rubinstein I (eds) Electroanalytical chemistry, a series of advances, vol. 20. Dekker, New York, pp 1–87

  17. Lamache M, Bauer D (1979) Anal Chem 51:1320

    CAS  Google Scholar 

  18. Brainina KhZ, Vidrevich MB (1981) J Electroanal Chem 121:1

    Article  CAS  Google Scholar 

  19. Scholz F, Nitschke L, Henrion G (1989) Naturwissenschaften 76:71

    Google Scholar 

  20. Scholz F, Nitschke L, Henrion G, Damaschun F (1989) Naturwissenschaften 76:167

    Google Scholar 

  21. Scholz F, Lange B (1992) Trends Anal Chem 11:359

    CAS  Google Scholar 

  22. Scholz F Meyer B (1994) Chem Soc Rev 23:341

    CAS  Google Scholar 

  23. Grygar T, Marken F, Schröder U, Scholz F (2002) Collect Czech Chem Commun 67:163

    CAS  Google Scholar 

  24. Rao MM, Liebenow C, Jayalakshami M, Wulff H, Guth U, Scholz F (2001) J Solid State Electrochem 5:348

    Article  CAS  Google Scholar 

  25. Frangini S, Carewska M, Passerini S, Scaccia S (2001) J New Mater Electrochem Syst 4:83

    CAS  Google Scholar 

  26. Rao MM, Jayalakshmi M, Schäf O, Wulff H, Scholz F (2001) J Solid State Electrochem 5:50

    Article  CAS  Google Scholar 

  27. Cox JA, Jaworski RK, Kulesza PJ (1991) Electroanalysis 3:969

    Google Scholar 

  28. Ghosh PK, Bard AJ (1983) J Am Chem Soc 105:5691

    CAS  Google Scholar 

  29. Rolison DR, Nowak RJ, Welsh TA, Murray CG (1991) Talanta 38:27

    Article  CAS  Google Scholar 

  30. Casella IG, Cataldi TRI, Salvi AM, Desimoni E (1993) Anal Chem 65:3143

    CAS  Google Scholar 

  31. Doménech A, Alarcón J (2002) Anal Chim Acta 452:11

    Article  Google Scholar 

  32. Luo P, Prabhu SV, Baldwin RP (1990) Anal Chem 62:752

    CAS  Google Scholar 

  33. Wang J, Taha Z (1990) Anal Chem 62:1413

    CAS  PubMed  Google Scholar 

  34. Jadeii JM, Marioli J, Kuwana T (1991) Anal Chem 63:649

    Google Scholar 

  35. Xie Y, Huber CO (1991) Anal Chem 63:1714

    CAS  Google Scholar 

  36. Cataldi TRI, Guerrieri A, Casella IG, Desimoni E (1995) Electroanalysis 7:305

    CAS  Google Scholar 

  37. Grygar T (1996) J Electroanal Chem 405:117

    CAS  Google Scholar 

  38. Lovric M, Komorsky-Lovric S, Bond AM (1991) J Electroanal Chem 319:1

    Article  CAS  Google Scholar 

  39. Schultze JW, Lohrengel MM (1983) Electrochim Acta 28:973

    Article  CAS  Google Scholar 

  40. Gunawardena G, Hills G, Montenegro I (1985) J Electroanal Chem 184:357

    Article  CAS  Google Scholar 

  41. de Levie R (1988) Chem Rev 88:599

    Google Scholar 

  42. Crousier J, Bimaghra I (1989) Electrochim Acta 34:1205

    Article  Google Scholar 

  43. Nicholson RS (1965) Anal Chem 37:667

    CAS  Google Scholar 

  44. Polcyn DS, Shain I (1966) Anal Chem 38:370

    CAS  Google Scholar 

  45. Bontempelli G, Magno, F, Daniele S (1985) Anal Chem 57:1503

    CAS  Google Scholar 

  46. Andrieux CP, Dumas-Bouchiat JM, Saveant JM (1982) J Electroanal Chem 131:1

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We thank the Valencian Regional Government, project CTIDIB/2002/216, for financial support.

Author information

Authors and Affiliations

  1. Departament de Química Analítica, Universitat de València, Dr. Moliner 50, 46100 , Burjassot (València), Spain

    Antonio Doménech-Carbó

  2. Departament de Química Inorgànica, Universitat de València, Dr. Moliner 50, 46100 , Burjassot (València), Spain

    Francisco José Torres & Javier Alarcón

Authors
  1. Antonio Doménech-Carbó
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Francisco José Torres
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Javier Alarcón
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Antonio Doménech-Carbó.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Doménech-Carbó, A., Torres, F.J. & Alarcón, J. Electrochemical characterization of cobalt cordierites attached to paraffin-impregnated graphite electrodes. J Solid State Electrochem 8, 127–137 (2004). https://doi.org/10.1007/s10008-003-0443-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-003-0443-3

Keywords

Search

Navigation