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EPR Study of TiO2 (Rutile) Doped with Vanadium

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Abstract

Samples of titanium dioxide, TiO2, doped with vanadium ions (0.1 ≤ [Vn+]0 ≤ 5.0 at. %) at high temperature, were prepared in a polycrystalline state and investigated using X-, Q-, and W-band electron paramagnetic resonance, EPR, spectroscopy. Substitutional and interstitial V4+ centers in TiO2 lattice have been both observed in EPR spectra, and their spin-Hamiltonian parameters were calculated. Portions of paramagnetic and diamagnetic species of Vn+ ions were estimated. The effect of additional high temperature annealing on the valence state of vanadium centers is discussed.

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Acknowledgments

This work is supported in part by the Russian Foundation for Basic Research (project no. 14-03-90020_Bel-a). We are grateful to Prof. A. Kh. Vorob’ev (Department of Chemistry, M. V. Lomonosov Moscow State University) for kindly providing us with his program package.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

    A. I. Kokorin & O. I. Gromov

  2. Zavoisky Kazan Physical-Technical Institute, Russian Academy of Sciences, Kazan, Russian Federation

    A. A. Sukhanov & V. K. Voronkova

  3. Chemistry Department, M. V. Lomonosov Moscow State University, Moscow, Russian Federation

    O. I. Gromov

  4. Department of Physics of Semiconductors and Microelectronics, Yerevan State University, Yerevan, Republic of Armenia

    V. M. Arakelyan & V. M. Aroutiounian

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  1. A. I. Kokorin
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  2. A. A. Sukhanov
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  3. O. I. Gromov
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  4. V. M. Arakelyan
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  5. V. M. Aroutiounian
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  6. V. K. Voronkova
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Correspondence to A. I. Kokorin.

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Kokorin, A.I., Sukhanov, A.A., Gromov, O.I. et al. EPR Study of TiO2 (Rutile) Doped with Vanadium. Appl Magn Reson 47, 479–485 (2016). https://doi.org/10.1007/s00723-016-0762-z

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  • DOI: https://doi.org/10.1007/s00723-016-0762-z

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