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Catalytic potentials of homodioxo-bimetallic dihydrazone complexes of uranium and molybdenum in a homogeneous oxidation of alkenes

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Abstract

The catalytic potentials of dioxomolybdenum(VI) and dioxouranium(VI) homobimetallic bis-ONO tridentate (2-hydroxy-1-benzylidene)malonyl-, succinyl-, and terephthalo-dihydrazone complexes were studied in homogeneous oxidation processes of various aliphatic and cyclic alkenes using aqueous H2O2 or TBHP (tert-butyl hydroperoxide) as a terminal oxidant. The catalytic potentiality is quantitative and highly selective to afford the corresponding oxide product with MoVIO2 complexes which is 5 times more than that with UVIO2 complexes using aqueous H2O2 or TBHP. Effect of various solvents and temperatures was investigated in the oxidation of 1,2-cyclooctene catalyzed by MoVIO2 complexes using aqueous H2O2 results that the most favored solvent is acetonitrile at an optimal temperature is 70 °C. The mechanistic pathway was tentatively described and discussed.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, King Faisal University, P.O. Box 380, Al Hufuf, 31982, Al Hassa, Saudi Arabia

    Mohamed Shaker S. Adam

  2. Department of Chemistry, Faculty of Science, Sohag University, Sohag, 82534, Egypt

    Mohamed Shaker S. Adam

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  1. Mohamed Shaker S. Adam
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Correspondence to Mohamed Shaker S. Adam.

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Adam, M.S.S. Catalytic potentials of homodioxo-bimetallic dihydrazone complexes of uranium and molybdenum in a homogeneous oxidation of alkenes. Monatsh Chem 146, 1823–1836 (2015). https://doi.org/10.1007/s00706-015-1477-9

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  • DOI: https://doi.org/10.1007/s00706-015-1477-9

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