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Dimeric and polymeric mercury(II) complexes containing 4-methyl-1,2,4-triazole-3-thiol ligand: X-ray studies, spectroscopic characterization, and thermal analyses

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Abstract

The polymer complex [Hg(μ-mptrz)2] n and two binuclear complexes of {[H2en][Hg2(mptrz)4(μ-Br)2]} and {[H2en][Hg2(mptrz)4(μ-I)2]} were prepared from the reaction of 4-methyl-1,2,4-triazole-3-thiol (Hmptrz) and ethylene diamine (en) with HgCl2, HgBr2, and HgI2 in CH3OH, respectively. Complex [Hg(μ-mptrz)2] n was also prepared from the reaction of 4-methyl-1,2,4-triazole-3-thiol and ethylene diamine with Hg(OAc)2 and Hg(SCN)2 in CH3OH and Hg(NO3)2·H2O in a mixture of CH3OH/H2O. Analysis of these complexes was done by CHN elemental analysis, IR, UV–Vis, 1H and 13C NMR, and luminescence spectroscopy, as well as single-crystal X-ray diffraction. Thermal stabilities of these complexes were also studied by TGA/DTA analyses.

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Acknowledgments

We would like to thank the University of Kurdistan and Islamic Azad University, Yadegar-e-Imam Khomeini (RAH) Branch, for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Mohammad Taheriha & Mohammad Ghadermazi

  2. Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran

    Vahid Amani

Authors
  1. Mohammad Taheriha
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  2. Mohammad Ghadermazi
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  3. Vahid Amani
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Correspondence to Mohammad Ghadermazi or Vahid Amani.

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Taheriha, M., Ghadermazi, M. & Amani, V. Dimeric and polymeric mercury(II) complexes containing 4-methyl-1,2,4-triazole-3-thiol ligand: X-ray studies, spectroscopic characterization, and thermal analyses. Monatsh Chem 146, 559–569 (2015). https://doi.org/10.1007/s00706-014-1333-3

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  • DOI: https://doi.org/10.1007/s00706-014-1333-3

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