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Preparation of silica-bonded N-propyltriethylenetetramine as a recyclable solid base catalyst for the synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols)

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Abstract

Silica-bonded N-propyltriethylenetetramine was prepared via the reaction between 3-silicapropyl chloride and triethylenetetramine. This heterogeneous solid base was used as a catalyst for the synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) by a one-pot condensation of aromatic aldehydes with 3-methyl-1-phenyl-5-pyrazolone in 72–93 % yields. The catalyst could be recycled several times without any additional treatment.

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Acknowledgments

We are thankful to the Persian Gulf University Research Council for the partial support of this work. Also, we are thankful to the School of Chemistry, Manchester University for running NMR, BET, CHN, TGA, and SEM.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Persian Gulf University, 75169, Bushehr, Iran

    Khodabakhsh Niknam, Maryam Sadeghi Habibabad, Abdollah Deris & Nasrin Aeinjamshid

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  1. Khodabakhsh Niknam
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  2. Maryam Sadeghi Habibabad
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  3. Abdollah Deris
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  4. Nasrin Aeinjamshid
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Correspondence to Khodabakhsh Niknam.

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Niknam, K., Habibabad, M.S., Deris, A. et al. Preparation of silica-bonded N-propyltriethylenetetramine as a recyclable solid base catalyst for the synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) . Monatsh Chem 144, 987–992 (2013). https://doi.org/10.1007/s00706-012-0910-6

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