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Effect of some nitrogen-heterocyclic compounds on corrosion of tin, indium, and their alloys in HClO4

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Abstract

The effect of adenine, adenosine, and 2,4,6-tris(2-pyridyl)-1,3,5-triazine (TPTZ) on the electrochemical and corrosion behavior of tin, indium, and tin-indium alloys in 0.5 M HClO4 solution at different temperatures was studied. The inhibition efficiency increases with an increase in the concentration of adenine and adenosine in the case of tin and indium. However, the effect of two mentioned compounds on the corrosion rate of the studied alloys gives an opposite effect. In the presence of TPTZ, the inhibition efficiency increases as the concentration of the inhibitor is increased in the case of tin. In the case of both indium and its investigated alloys, the maximum inhibition efficiency is obtained at the lowest concentration of TPTZ (10−6 M). The adsorption of the studied compounds is found to obey the Frumkin adsorption isotherm. The standard enthalpy \( \Updelta H_{\rm ads}^{^\circ } , \) entropy \( \Updelta S_{\rm ads}^{^\circ } , \) and free energy changes of adsorption \( \Updelta G_{\rm ads}^{^\circ } \) are calculated and discussed.

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References

  1. Mohran HS, El-Sayed A, Abd El-Lateef HM (2009) J Solid State Electrochem 13:1279

    Article  CAS  Google Scholar 

  2. El-Sayed A (1998) Denki Kagaku 66:176

    CAS  Google Scholar 

  3. Abd El-Rehim SS, Hassan HH, Amin MA (2004) Corros Sci 46:5

    Article  CAS  Google Scholar 

  4. Foad El Sherbini E (1999) Mat Chem Phys 60:286

    Article  CAS  Google Scholar 

  5. Migahed MA, Azzam EMS, Al-Sabagh AM (2004) Mater Chem Phys 85:273

    Article  CAS  Google Scholar 

  6. Hackerman N, Cook EL (1950) J Electrochem Soc 97:1

    Article  Google Scholar 

  7. Ahlberg E, Friel M (1989) Electrochim Acta 34:190

    Google Scholar 

  8. Ajmal M, Mideen AS, Quaraishi MA (1994) Corros Sci 36:79

    Article  CAS  Google Scholar 

  9. Fang J, Li J (2002) J Mol Struct (Theochem) 593:179

    Article  CAS  Google Scholar 

  10. Quraishi MA, Sharma HK (2002) Mater Chem Phys 78:18

    Article  CAS  Google Scholar 

  11. Bockris JOM, Reddy AKN (2000) Modern electrochemistry 2B, electrodics in chemistry, engineering, biology, and environmental science, 2nd edn. Kluwer Academic/Plenum Publishers, New York, p 1703

    Google Scholar 

  12. Ashassi-Sorkhabi H, Asghari E (2008) Electrochim Acta 54:162

    Article  CAS  Google Scholar 

  13. Ali SA, Saeed MT (2001) Polymer 42:2785

    Article  CAS  Google Scholar 

  14. Al-Kharafi FM, Al-Hajjar FH, Katrib A (1990) Corros Sci 30:869

    Article  CAS  Google Scholar 

  15. Hosseini SMA, Azimi A (2009) Corros Sci 51:728

    Article  CAS  Google Scholar 

  16. Aksüt A, Bilgiç S (1992) Corros Sci 33:379

    Article  Google Scholar 

  17. Baba H, Kodama T (1999) Corros Sci 41:1987

    Article  CAS  Google Scholar 

  18. Moretti G, Guidi F (2002) Corros Sci 44:1995

    Article  CAS  Google Scholar 

  19. Matos JB, Pereira LP, Agostinho SML, Barcia OE, Cordeiro GGO, D’Elia E (2004) J Electroanal Chem 570:91

    Article  CAS  Google Scholar 

  20. Katritzky AR (1984) Comprehensive heterocyclic chemistry, structure, reaction, synthesis, and uses of heterocyclic compounds, vol 5, Pergamon Press Ltd, London

  21. Scendo M (2007) Corros Sci 49:3953

    Article  CAS  Google Scholar 

  22. Scendo M (2008) Corros Sci 50:2070

    Article  CAS  Google Scholar 

  23. Mohran HS, El-Sayed A, Abd El-Lateef HM (2009) J Solid State Electrochem 13:1147

    Article  CAS  Google Scholar 

  24. Tremont R, De Jesus-Cardona H, Garcia-Orozco J, Castro RJ, Cabrera CR (2000) J Appl Electrochem 30:737

    Article  CAS  Google Scholar 

  25. Schultze JW, Wippermann K (1987) Electrochim Acta 32:23

    Article  Google Scholar 

  26. El-Sayed A (1997) J Appl Electrochem 27:193

    Article  CAS  Google Scholar 

  27. Antropov LI (1972) Theoretical electrochemistry. Mir Publications, Moscow, p 276

    Google Scholar 

  28. Antropov LI (1967) Corros Sci 7:607

    Article  CAS  Google Scholar 

  29. El-Sayed A, Shaker AM, Abd El-Lateef HM (2010) Corros Sci 52:72

    Article  CAS  Google Scholar 

  30. Lorenz WJ (1970) Z Phys Chem 65:244

    Google Scholar 

  31. El-Sherbini FEF (2006) Corros Sci 48:1093

    Article  Google Scholar 

  32. Takati JD, Gandhi DK (1983) Corros Sci 23:1315

    Article  Google Scholar 

  33. Abdel Aal MS, Abdel Wahab AA, El-Sayed A (1981) Corrosion 37:557

    Article  CAS  Google Scholar 

  34. Agrawal R, Namloodhiri TKG (1997) J Appl Electrochem 27:1265

    Article  CAS  Google Scholar 

  35. Omanovic S, Metikos-Hukovic M (1995) Solid State Ionics 78:69

    Article  CAS  Google Scholar 

  36. El-Shafei AM, Mohamed LA, Ali N (2007) J Appl Sci Res 3:1010

    CAS  Google Scholar 

  37. Abd El-Maksoud SS, Hassan HH (2007) Mater Corros 58:369

    Article  CAS  Google Scholar 

  38. Branzoi V, Golgovici F, Branzoi F (2002) Mater Chem Phys 78:122

    Article  CAS  Google Scholar 

  39. Dehri I, Ozcan M (2006) Mater Chem Phys 98:316

    Article  CAS  Google Scholar 

  40. Frumkin AN (1925) Z Phys Chem 116:166

    Google Scholar 

  41. Abd El-Rehim SS, Hassan HH, Amin MA (2001) Mater Chem Phys 70:64

    Article  CAS  Google Scholar 

  42. Ateya BG, El-Anadouli BE, El-Nizamy FM (1984) Corros Sci 24:509

    Article  CAS  Google Scholar 

  43. Abdel Nabey BA, Khamis E, Ramadan MS, El-Gindy A (1995) In: 8th European Symp Corros Inhibitors, Ann Univi Ferrara NS Sez 10299

  44. El-Sayed A, Shaker AM, Gad El-Kareem H (2003) Bull Chem Soc Jpn 76:1527

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Faculty of Science, Chemistry Department, Sohag University, Sohag, 82524, Egypt

    Abdel-Rahman El-Sayed, Hossnia S. Mohran & Hany M. Abd El-Lateef

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  1. Abdel-Rahman El-Sayed
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  2. Hossnia S. Mohran
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  3. Hany M. Abd El-Lateef
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Correspondence to Abdel-Rahman El-Sayed.

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El-Sayed, AR., Mohran, H.S. & Abd El-Lateef, H.M. Effect of some nitrogen-heterocyclic compounds on corrosion of tin, indium, and their alloys in HClO4 . Monatsh Chem 143, 51–64 (2012). https://doi.org/10.1007/s00706-011-0558-7

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  • DOI: https://doi.org/10.1007/s00706-011-0558-7

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