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Rapid SnCl2 catalyzed phenylselenoetherification of (Z)- and (E)-hex-4-en-1-ols

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Abstract

A fast and efficient method for intramolecular heterocyclization of (Z)- and (E)-hex-4-en-1-ols was developed. The method does not cause side reactions of the substrates and provides the cyclic phenylselenoethers in high yields after only few minutes. A catalytic amount of SnCl2 increased the yield, but in the presence of an equimolar amount of SnCl2, formation of corresponding cyclic ethers were almost quantitative and reaction occurred instantaneously under extremely mild experimental conditions.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kragujevac, Kragujevac, Serbia

    Vera M. Divac, Marina D. Rvović & Zorica M. Bugarčić

Authors
  1. Vera M. Divac
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  2. Marina D. Rvović
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  3. Zorica M. Bugarčić
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Corresponding author

Correspondence to Zorica M. Bugarčić.

Additional information

Correspondence: Zorica M. Bugarčić, Department of Chemistry, Faculty of Science, University of Kragujevac, Radoja Domanovića 12, P.O.Box 60, YU-34000 Kragujevac, Serbia.

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Divac, V., Rvović, M. & Bugarčić, Z. Rapid SnCl2 catalyzed phenylselenoetherification of (Z)- and (E)-hex-4-en-1-ols. Monatsh Chem 139, 1373–1376 (2008). https://doi.org/10.1007/s00706-008-0936-y

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  • DOI: https://doi.org/10.1007/s00706-008-0936-y

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