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Titanium-Oxo Clusters, Versatile Nanobuilding Blocks for the Design of Advanced Hybrid Materials

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Summary.

This review describes the major advances made on titanium-oxo clusters chemistry and their derived hybrid materials. The main synthesis procedures, the cluster structures presented in literature, and the relation between the titanium-oxo clusters condensation degree and poisoning ratio are discussed. The tuned organo-functionalisation of the titanium-oxo based nanobuilding blocks allows to develop a LEGO-like chemistry, able to direct the assembling of a large variety of structurally well defined complex hybrid architectures.

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  1. Chimie de la Matière Condensée de Paris, University of Paris VI, UMR UPMC-CNRS 7574, 4 place Jussieu, T54 (5E C-54-55), 75252, Paris cedex 05, France

    Laurence Rozes, Nathalie Steunou, Giulia Fornasieri & Clément Sanchez

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  1. Laurence Rozes
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  2. Nathalie Steunou
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  3. Giulia Fornasieri
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  4. Clément Sanchez
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Correspondence to Clément Sanchez.

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Rozes, L., Steunou, N., Fornasieri, G. et al. Titanium-Oxo Clusters, Versatile Nanobuilding Blocks for the Design of Advanced Hybrid Materials. Monatsh. Chem. 137, 501–528 (2006). https://doi.org/10.1007/s00706-006-0464-6

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