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Thermodynamic Properties and Melting Behavior of Bi–Sn–Zn Alloys

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Summary.

The partial and integral enthalpies of mixing of liquid Bi–Sn–Zn alloys were determined at 500°C by a drop calorimetric technique using a Calvet-type microcalorimeter. The ternary interaction parameters in the Bi–Sn–Zn system were fitted using the Redlich-Kister-Muggianu model for substitutional solutions, and isoenthalpy curves of the integral molar enthalpy of mixing at 500°C were constructed. Furthermore, a DSC technique was used to determine the liquidus temperatures in three sections (3, 5, and 7 at.% Zn) as well as the invariant reaction temperature of the ternary eutectic L ⇄ (Bi) + (Sn) + (Zn). The ternary eutectic reaction was found at 135°C.

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Authors and Affiliations

  1. Institut für Anorganische Chemie – Materialchemie, Universität Wien, 1090, Wien, Austria

    Christoph Luef & Herbert Ipser

  2. Department of Chemical Engineering and Chemistry, Laboratory of Materials and Interface Chemistry, Eindhoven University of Technology, 5600, MB Eindhoven, The Netherlands

    Aloke Paul & Alexander Kodentsov

  3. Metallurgy Department, Indian Institute of Science, 560012, Bangalore, India

    Aloke Paul

  4. Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 61662, Brno, Czech Republic

    Jiri Vizdal & Ales Kroupa

Authors
  1. Christoph Luef
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  2. Aloke Paul
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  3. Jiri Vizdal
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  4. Ales Kroupa
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  5. Alexander Kodentsov
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  6. Herbert Ipser
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Correspondence to Christoph Luef.

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Luef, C., Paul, A., Vizdal, J. et al. Thermodynamic Properties and Melting Behavior of Bi–Sn–Zn Alloys. Monatsh. Chem. 137, 381–395 (2006). https://doi.org/10.1007/s00706-005-0457-x

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  • DOI: https://doi.org/10.1007/s00706-005-0457-x

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