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Recent advancements in metal-organic frameworks composites based electrochemical (bio)sensors

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Abstract

Metal-organic frameworks (MOFs) are a novel class of crystalline materials which find widespread applications in the field of microporous conductors, catalysis, separation, biomedical engineering, and electrochemical sensing. With a specific emphasis on the MOF composites for electrochemical sensor applications, this review summarizes the recent construction strategies on the development of conductive MOF composites (post-synthetic modification of MOFs, in situ synthesis of functional materials@MOFs composites, and incorporating electroactive ligands). The developed composites are revealed to have excellent electrochemical sensing activity better than their pristine forms. Notably, the applicable functionalized MOFs to electrochemical sensing/biosensing of various target species are discussed. Finally, we highlight the perspectives and challenges in the field of electrochemical sensors and biosensors for potential directions of future development.

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Abbreviations

AChE:

Acetylcholinesterase

Amp:

Amperometry

ASV:

Anodic stripping voltammetry

AuE:

Gold electrode

AuNF:

Gold nanoflower

AuNP:

Gold nanoparticle

AuNR:

Au nanorod

BCL:

Burkholderia cepacia lipase

BDC2− :

1,4-Benzenedicarboxylate

BET:

Brunauer–Emmett–Teller

BIB:

1,4-Bisimidazolebenzene

bipy:

Bipyridine

BSA:

Bovine serum albumin

BTB:

4,4′,4″-Benzene-1,3,5-triyl-tribenzoic acid

BTC:

1,3,5-Benzene-tricarboxylate

BTCA-P-Cu-CP:

(Benzene-1,2,4,5 tetracarboxylic acid)-piperazine-Cu-coordination polymer

Ce:

Cerium

Chronoamp:

Chronoamperometry

CNF:

Carbon nanofiber

CNH:

Carbon nanohorn

CNT:

Carbon nanotube

COF:

Covalent organic framework

CPE:

Carbon paste electrode

CuNP:

Copper nanoparticle

DNA:

Deoxyribonucleic acid

DPASV:

Differential pulse anodic stripping voltammetry

DPSV:

Differential pulse stripping voltammetry

DPV:

Differential pulse voltammetry

DQ:

N,N′-Ethylene 2,2′-bipyridinium

EDTA:

Ethylenediaminetetraacetic acid

EG:

Expanded graphite

ERGO:

Electrochemically reduced graphene oxide

Exo III:

Exonuclease III

FTO:

Fluorine-doped tin oxide

GaOOH:

Gallium oxide hydroxide

GCE:

Glassy carbon electrode

GN:

Graphene nanocomposite

GNR:

Graphene nanoribbon

GO:

Graphene oxide

GONR:

Graphene oxide nanoribbon

Gr:

Graphene

H2adp:

Adipic acid

H2O2 :

Hydrogen peroxide

H2TZB:

4-(1H-Tetrazol-5-yl)benzoic acid

H4DSBDC:

2,5-Disulfhydrylbenzene-1,4-dicarboxylic acid

H6dpa:

3,4-Di(3,5-dicarboxyphenyl)phthalic acid

HHTP:

2,3,6,7,10,11-Hexahydroxytriphenylene

HITP:

2,3,6,7,10,11-Hexaiminotriphenylene

HMIM:

2-Methylimidazole

IL:

Ionic liquid

ITO:

Indium tin oxide

JPBC:

Jasmine petal derived biocarbon

LSV:

Linear sweep voltammetry

MIP:

Molecularly imprinted polymer

MoS2 :

Molybdenum disulfide

MPC:

Macroporous carbon

MQ:

N,N′-Dimethyl-2,2′-bipyridinium

MWCNT:

Multi-walled carbon nanotube

NiCoNS:

Nickel cobalt nanosheet

NPC:

Nanoporous carbon

NP:

Nanoparticle

P(ANI-co-ANA):

Polyaniline and poly(anthranilic acid) copolymer

PA:

Phytic acid

PAA:

Poly(acrylic acid)

PCE:

Porous carbon electrode

PDMS:

Polydimethylsiloxane

PEDOT:

Poly(3,4-ethylenedioxythiophene)

PO:

Polyoxometalate

PPy:

Polypyrrole

RGO:

Reduced graphene oxide

SA:

Streptavidin

SPCE:

Screen-printed carbon electrode

SPE:

Screen-printed electrode

SPE:

Screen-printed electrode

SWASV:

Square wave anodic stripping voltammetry

SWV:

Square wave voltammetry

TCPP:

Tetra-(4-carboxyphenyl)-substituted porphyrin

TDPAT:

2,4,6-Tris(3,5-dicarboxylphenylamino)-1,3,5-triazine

TPA:

Terephthalic acid

TPN:

Terephthalonitrile

TPT:

2,4,6-Tri(4-pyridyl)-1,3,5-triazine

tyr:

l-Tyrosine

ZIF:

Zeolitic imidazolate framework

β-CD:

β-Cyclodextrin

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Acknowledgements

Financial supports from National Natural Science Foundation of China (21905180 and 51778369) are gratefully acknowledged. We appreciate the Instrument Analysis Centre of Shenzhen University (Lihu campus) for providing equipment for material characterizations.

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  1. Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, People’s Republic of China

    Venkata Narayana Palakollu, Dazhu Chen, Jiao-Ning Tang, Lei Wang & Chen Liu

  2. Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, 3688 Nanhai Ave, Shenzhen, 518060, People’s Republic of China

    Venkata Narayana Palakollu

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  1. Venkata Narayana Palakollu
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  2. Dazhu Chen
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  3. Jiao-Ning Tang
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  4. Lei Wang
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  5. Chen Liu
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Correspondence to Chen Liu.

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Palakollu, V.N., Chen, D., Tang, JN. et al. Recent advancements in metal-organic frameworks composites based electrochemical (bio)sensors. Microchim Acta 189, 161 (2022). https://doi.org/10.1007/s00604-022-05238-0

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