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Ratiometric fluorescent test pen filled with a mixing ink of carbon dots and CdTe quantum dots for portable assay of silver ion on paper

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Abstract

A ratiometric fluorescent test pen filled with a mixing ink of blue carbon dots (CDs) and red CdTe quantum dots (CdTe QDs) is introduced for portable assay of silver ion (Ag(I)) on paper. The mixing ink was tuned with ratiometric fluorescent intensity of 1:5, and then filled into a vacant commercial fluorescent pen core. Writing/painting a random word/figure on a blank paper can make the most portable nanoprobe determining Ag(I) by visualization. Ag(I) can adsorb onto the surface of CdTe QDs, which leads to the formation of surficial Ag2Te layer by an ion-exchanging reaction. This enables the red fluorescence of CdTe QDs (with excitation/emission maxima at 360/628 nm) to be quenched. Due to the unchanged blue fluorescence of CDs (with excitation/emission maxima at 360/440 nm) as internal standard, the solution color evolves gradually from red to blue with the increase of Ag(I) concentration with a detection limit of 3.48 nM. This is at least 2 orders of magnitude lower than the limit defined by World Health Organization (WHO) in drinkable water. The fluorescent test pen has also been used for the determination of Ag(I) in wastewater.

Ag(I) can adsorb on the surface of CdTe QDs to quench their fluorescence, while the fluorescent intensity of CDs keep constant, accompanying color change with the increase of Ag(I) concentration. The method offers a visual assay of Ag(I) in water.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (Nos. 21775073 and 61605084).

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Authors and Affiliations

  1. School of Pharmacy, Nanjing Medical University, Nanjing, 211166, Jiangsu, China

    Junhui You, Jiangrong Ji, Jiafeng Wu, Siwan Wang, Panpan Chen, Rongchen Mao, Yang Jin, Liying Zhang & Shuhu Du

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  1. Junhui You
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  2. Jiangrong Ji
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  3. Jiafeng Wu
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  5. Panpan Chen
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  9. Shuhu Du
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Correspondence to Shuhu Du.

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You, J., Ji, J., Wu, J. et al. Ratiometric fluorescent test pen filled with a mixing ink of carbon dots and CdTe quantum dots for portable assay of silver ion on paper. Microchim Acta 187, 391 (2020). https://doi.org/10.1007/s00604-020-04369-6

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  • DOI: https://doi.org/10.1007/s00604-020-04369-6

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