Skip to main content
Log in

Recent advances in metal-organic frameworks for adsorption of common aromatic pollutants

  • Review Article
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

This review (with 85 refs.) summarizes the recent literature on the adsorption of common aromatic pollutants by using modified metal-organic frameworks (MOFs). Four kinds of aromatic pollutants are discussed, namely benzene homologues, polycyclic aromatic hydrocarbons (PAHs), organic dyes and their intermediates, and pharmaceuticals and personal care products (PPCPs). MOFs are shown to be excellent adsorbents that can be employed to both the elimination of pollutants and to their extraction and quantitation. Adsorption mechanisms and interactions between aromatic pollutants and MOFs are discussed. Finally, the actual challenges of existence and the perspective routes towards future improvements in the field are addressed.

Recent advance on adsorption of common aromatic pollutants including benzene series, polycyclic aromatic hydrocarbons, organic dyes and their intermediates, pharmaceuticals and personal care products by metal-organic frameworks.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Bao C, Fang CL (2012) Water resources flows related to urbanization in China: challenges and perspectives for water management and urban development. Water Resour Manag 26:531–552

    Article  Google Scholar 

  2. Zhao G, Jiang L, He Y, Li J, Dong H, Wang X, Hu W (2011) Sulfonated graphene for persistent aromatic pollutant management. Adv Mater 23(34):3959–3963

    Article  CAS  PubMed  Google Scholar 

  3. Qu Y, Pei X, Shen W, Zhang X, Wang J, Zhang Z, Li S, You S, Ma F, Zhou J (2017) Biosynthesis of gold nanoparticles by aspergillum sp. WL-au for degradation of aromatic pollutants. Phys E 88:133–141

    Article  CAS  Google Scholar 

  4. Carrizo D, Gustafsson O (2011) Distribution and inventory of polychlorinated biphenyls in the polar mixed layer of the seven pan-arctic shelf seas and interior basin. Environ Sci Technol 45:1420–1427

    Article  CAS  PubMed  Google Scholar 

  5. Carrizo D, Brennan SF, Chevallier OP, Woodside J, Cooper KM, Cantwell MM, Cuskelly G, Elliott CT (2017) Distribution of serum levels of persistent organic pollutants, heterocyclic aromatic amine theoretical intake and nutritional cofactors in a semi-rural island population. Environ Sci Pollut Res 24(28):22393–22401

    Article  CAS  Google Scholar 

  6. Deliyanni E, Seredych M, Bandosz TG (2009) Interactions of 4,6-dimethyldibenzothiophene with the surface of activated carbons. Langmuir 25:9302–9312

    Article  CAS  PubMed  Google Scholar 

  7. Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresour Technol 97:1061–1085

    Article  CAS  PubMed  Google Scholar 

  8. Haque E, Jun JW, Talapaneni SN, Vinu A, Jhung SH (2010) Superior adsorption capacity of mesoporous carbon nitride with basic CN framework for phenol. J Mater Chem 20:10801–10803

    Article  CAS  Google Scholar 

  9. Hasan Z, Jhung SH (2015) Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions. J Hazard Mater 283:329–339

    Article  CAS  PubMed  Google Scholar 

  10. Zhu M, Hu P, Tong Z, Zhao ZX, Zhao ZX (2016) Enhanced hydrophobic MIL(Cr) metal-organic framework with high capacity and selectivity for benzene VOCs capture from high humid air. Chem Eng J 313(7):1122–1131

    Google Scholar 

  11. Hashemi B, Zohrabi P, Raza N, Kim KH (2017) Metal-organic frameworks as advanced sorbents for the extraction and determination of pollutants from environmental, biological, and food media. Trac Trends Anal Chem 97:65–82

    Article  CAS  Google Scholar 

  12. Jhung SH, Lee JH, Yoon JW, Serre C, Férey G, Chang GC (2007) Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption ability. Adv Mater 19(1):121–124

    Article  CAS  Google Scholar 

  13. Xian S, Yu Y, Xiao J, Zhang Z, Xia Q, Wang h LZ (2015) Competitive adsorption of water vapor with VOCs dichloroethane, ethyl acetate and benzene on MIL-101(Cr) in humid atmosphere. RSC Adv 5(3):1827–1834

    Article  CAS  Google Scholar 

  14. Zhao Z, Sha W, Yan Y, Li XM, Li J, Li Z (2015) Competitive adsorption and selectivity of benzene and water vapor on the microporous metal organic frameworks (HKUST-1). Chem Eng J 259(1):79–89

    Article  CAS  Google Scholar 

  15. Nuzhdin AL, Bukhtiyarova GA (2015) Liquid-phase separation of benzene from saturated aliphatics by adsorption on a copper benzene-1,3,5-tricarboxylate metal-organic framework. Mendeleev Commun 25(2):153–154

    Article  CAS  Google Scholar 

  16. Yang K, Xue F, Sun Q, Yue RL, Li DH (2013) Adsorption of volatile organic compounds by metal-organic frameworks MOF-177. J Environ Chem Eng 1(4):713–718

    Article  CAS  Google Scholar 

  17. Wu Y, Chen H, Liu D, Xi HX (2015) Effective ligand functionalization of zirconium-based metal-organic frameworks for the adsorption and separation of benzene and toluene: a multi-scale computational study. Acs Appl Mater Interfaces 7(10):5775–5787

    Article  CAS  PubMed  Google Scholar 

  18. Leidinger M, Rieger M, Weishaupt D, Sauerwald T, Nägele M, Hürttlen J, Schütze A (2015) Trace gas VOC detection using metal-organic frameworks as pre-concentrators and semiconductor gas sensors. Procedia Eng 120:1042–1045

    Article  CAS  Google Scholar 

  19. Voort PVD, Leus K, Liu YY, Vandichel M, Speybroeck VV, Waroquierb M, Biswas S (2014) Vanadium metal–organic frameworks: structures and applications. New J Chem 38(5):1853–1867

    Article  Google Scholar 

  20. Duan L, Dong X, Wu Y, Li HL, Wang L, Song LJ (2013) Adsorption and diffusion properties of xylene isomers and ethylbenzene in metal–organic framework MIL-53(Al). J Porous Mater 20(2):431–440

    Article  CAS  Google Scholar 

  21. Mukherjee S, Joarder B, Desai AV, Manna B, Krishna R, Ghosh SK (2015) Exploiting framework flexibility of a metal-organic framework for selective adsorption of styrene over ethylbenzene. Inorg Chem 54(9):4403–4408

    Article  CAS  PubMed  Google Scholar 

  22. Cui X, Gu Z, Jiang D, Li Y, Wang H, Yan X (2009) In situ hydrothermal growth of metal-organic framework 199 films on stainless steel fibers for solid-phase microextraction of gaseous benzene homologues. Anal Chem 81(23):9771–9777

    Article  CAS  PubMed  Google Scholar 

  23. Chang N, Gu Z, Wang H, Yan X (2011) Metal-organic framework-based tandem molecular sievesasa dual platform for selective microextraction and high-resolution gas chromatographic separation of n-alkanes in complex matrixes. Anal Chem 83(18):7094–7101

    Article  CAS  PubMed  Google Scholar 

  24. Khan NA, Hasan Z, Jhung SH (2013) Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J Hazard Mater 244-245(2):444–456

    Article  CAS  PubMed  Google Scholar 

  25. Zhou HC, Kitagawa S (2014) Metal–organic frameworks (MOFs). Chem Soc Rev 43:5415–5418

    Article  CAS  PubMed  Google Scholar 

  26. Alexander S (2015) Adsorption on mesoporous metal-organic frameworks in solution: aromatic and heterocyclic compounds. Chem Eur J 21(47):16726–16742

    Article  CAS  Google Scholar 

  27. Wang C, Liu X, Keser DN, Chen J, Li K (2016) Applications of water stable metal-organic frameworks. Chem Soc Rev 45(18):5107–5134

    Article  CAS  PubMed  Google Scholar 

  28. Lei J, Qian R, Ling P, Cui L, Ju H (2014) Design and sensing applications of metal–organic framework composites. Trends Anal Chem 58:71–78

    Article  CAS  Google Scholar 

  29. Li B, Wen H, Cui Y, Zhou W, Qian G, Chen B (2016) Emerging multifunctional metal–organic framework materials. Adv Mater 28(40):8819–8860

    Article  CAS  PubMed  Google Scholar 

  30. Nandasiri MI, Jambovane SR, Mcgrail BP, Schaefc HT, Nuneb SK (2016) Adsorption, separation, and catalytic properties of densified metal-organic frameworks. Coord Chem Rev 311(6):38–52

    Article  CAS  Google Scholar 

  31. Dias EM, Petit C (2015) Towards the use of metal–organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and the next steps in the field. J Mater Chem A 3(45):22484–22506

    Article  CAS  Google Scholar 

  32. Xie L, Liu S, Han Z, Jiang R, Liu H, Zhu F, Zeng F, Su C, Ouyang G (2015) Preparation and characterization of metal-organic framework MIL-101(Cr)-coated solid-phase microextraction fiber. Anal Chim Acta 853:303–311

    Article  CAS  PubMed  Google Scholar 

  33. He C, Tian J, Liu S, Ouyang G, Zhang Z, Chen X (2013) A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds. Chem Sci 4(1):351–356

    Article  CAS  Google Scholar 

  34. Krugly E, Martuzevicius D, Sidaraviciute R, Ciuzas D, Prasauskas T, Kauneliene V, Stasiulaitiene I, Kliucininkas L (2014) Characterization of particulate and vapor phase polycyclic aromatic hydrocarbons in indoor and outdoor air of primary schools. Atmos Environ 82(1):298–306

    Article  CAS  Google Scholar 

  35. Mansab S, Rafique U, Haq NU (2015) Synthesis of Ni based metal organic frameworks and its applications for removal of polyaromatic hydrocarbons. IJISR 15(2):443–451

    Google Scholar 

  36. Du FY, Qin Q, Deng JC, Ruan GH, Yang XQ, Li LH, Li JP (2015) Magnetic metal-organic framework MIL-100(Fe) microspheres for the magnetic solid-phase extraction of trace polycyclic aromatic hydrocarbons from water samples. J Sep Sci 39(12):2356–2364

    Article  CAS  Google Scholar 

  37. Zhou Q, Lei M, Li J, Liu Y, Zhao K, Zhao D (2017) Magnetic solid phase extraction of N- and S-containing polycyclic aromatic hydrocarbons at ppb levels by using a zerovalent iron nanoscale material modified with a metal organic framework of type Fe@MOF-5, and their determination by HPLC. Microchim Acta 184(4):1029–1036

    Article  CAS  Google Scholar 

  38. Jia Y, Zhao Y, Zhao M, Wang Z, Chen X, Wang M (2018) Core–shell indium (III) sulfide @ metal-organic framework nanocomposite as an adsorbent for the dispersive solid-phase extraction of nitro-polycyclic aromatic hydrocarbons. J Chromatogr A 1551:21–28

    Article  CAS  PubMed  Google Scholar 

  39. Zhang X, Zang XH, Wang JT, Wang C, Wu QH, Wang Z (2015) Porous carbon derived from aluminum-based metal organic framework as a fiber coating for the solid-phase microextraction of polycyclic aromatic hydrocarbons from water and soil. Microchim Acta 182(13–14):2353–2359

    Article  CAS  Google Scholar 

  40. Wang GH, Lei YQ, Song HC (2015) Exploration of metal-organic framework MOF-177 coated fibers for headspace solid-phase microextraction of polychlorinated biphenyls and polycyclic aromatic hydrocarbons. Talanta 144:369–374

    Article  CAS  PubMed  Google Scholar 

  41. Gao J, Huang CH, Lin YF, Tong P, Zhang L (2016) In situ solvothermal synthesis of metal-organic framework coated fiber for highly sensitive solid-phase microextraction of polycyclic aromatic hydrocarbons. J Chromatogr A 1436:1–8

    Article  CAS  PubMed  Google Scholar 

  42. Zheng J, Li S, Wang Y, Li L, Su C, Liu H, Zhu F, Jiang R, Ouyang G (2014) In situ growth of IRMOF-3 combined with ionic liquids to prepare solid-phase microextraction fibers. Anal Chim Acta 829:22–27

    Article  CAS  PubMed  Google Scholar 

  43. Wei S, Wei L, Xu G, Wang Y, Liu S, Zhu F, Liu Y, Ouyang G (2017) Fabrication of a polymeric composite incorporating metal-organic framework nanosheets for solid-phase microextraction of polycyclic aromatic hydrocarbons from water samples. Anal Chim Acta 971:48–54

    Article  CAS  PubMed  Google Scholar 

  44. Yao S, Xu T, Zhao N, Zhang LR, Huo QS, Liu YL (2017) An anionic metal-organic framework with ternary building units for rapid and selective adsorption of dyes. Dalton Trans 46(10):3332–3337

    Article  CAS  PubMed  Google Scholar 

  45. Hu ML, Hashemi L, Morsali A (2016) Pore size and interactions effect on removal of dyes with two lead(II) metal-organic frameworks. Mater Lett 175:1–4

    Article  CAS  Google Scholar 

  46. Mohammadi AA, Alinejad A, Kamarehie B, Javan S, Ghaderpoury A, Ahmadpour M, Ghaderpoori M (2017) Metal-organic framework UiO-66 for adsorption of methylene blue dye from aqueous solutions. Int J Environ Sci Technol 14(9):1959–1969

    Article  CAS  Google Scholar 

  47. Zhao XL, Liu SL, Tang Z, Niu HY, Cai YQ, Meng W, Wu FC, Giesy JP (2015) Synthesis of magnetic metal-organic framework (MOF) for efficient removal of organic dyes from water. Sci Rep-UK 5:11849–11858

    Article  Google Scholar 

  48. Bibi R, Wei LF, Shen QH, Tian OO, Li NX, Zhou JH (2017) Effect ofamino functionality on the uptake of cationic dye by titanium-based metal organic frameworks. J Chem Eng Data 62(5):1615–1622

    Article  CAS  Google Scholar 

  49. Zhang ZH, Zhang JL, Liu JM, Xiong ZH, Chen X (2016) Selective and competitive adsorption of azo dyes on the metal–organic framework ZIF-67. Water Air Soil Pollut 227(12):471–482

    Article  CAS  Google Scholar 

  50. Masoomi MY, Bagheri M, Morsali A (2017) Porosity and dye adsorption enhancement by ultrasonic synthesized cd(II) based metal-organic framework. Ultrason Sonochem 37:244–250

    Article  CAS  PubMed  Google Scholar 

  51. Abdi J, Vossoughi M, Mahmoodi NM, Alemzadeh I (2017) Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal. Chem Eng J 326:1145–1158

    Article  CAS  Google Scholar 

  52. Wang KK, Li CF, Liang YX, Han TT, Huang HL, Yang QY, Liu DH, Zhong CL (2016) Rational construction of defects in a metal–organic framework for highly efficient adsorption and separation of dyes. Chem Eng J 289(7):486–493

    Article  CAS  Google Scholar 

  53. Xu J, Zhuo Q, Fu RZ, Cheng H, Tang X, Ma Y, Xie J (2016) A 2D metal–organic framework for selective adsorptions on organic dyes. Inorg Chim Acta 446(8):198–202

    Article  CAS  Google Scholar 

  54. Liu HC, Chen LG, Ding J (2016) Adsorption behavior of magnetic amino-functionalized metal–organic framework for cationic and anionic dyes from aqueous solution. RSC Adv 6(54):48884–48895

    Article  CAS  Google Scholar 

  55. Qi ZP, Yang JM, Kang YS, Guo F, Sun WY (2016) Facile water-stability evaluation of metal-organic frameworks and the property of selective removal of dyes from aqueous solution. Dalton Trans 45(21):8753–8359

    Article  CAS  PubMed  Google Scholar 

  56. Jia YY, Ren GJ, Li AL, Zhang LZ, Feng R, Zhang YH, Bu XH (2016) Temperature–related synthesis of two anionic metal–organic frameworks with distinct performance in organic dyes adsorption. Cryst Growth Des 16(10):5593–5597

    Article  CAS  Google Scholar 

  57. Hahm H, Kim S, Ha H, Jung S, Kim Y, Yoon M, Kim M (2015) Charged functional group effects on metal-organic framework for selective organic dye adsorptions. Crystengcomm 17(44):8418–8422

    Article  CAS  Google Scholar 

  58. Zhang XQ, Gao YF, Liu HT, Liu ZL (2015) Fabrication of porous metal–organic frameworks via a mixed-ligand strategy for highly selective and efficient dye adsorption in aqueous solution. Crystengcomm 17(31):6037–6043

    Article  CAS  Google Scholar 

  59. Han Y, Sheng S, Yang F, Xie Y, Zhao M, Li JR (2015) Size-exclusive and coordination-induced selective dye adsorption in a nanotubular metal–organic framework. J Mater Chem A 3(24):12804–12809

    Article  CAS  Google Scholar 

  60. Li PZ, Wang XJ, Tan SY, Ang CY, Chen H, Liu J, Zou R, Zhao Y (2015) Clicked isoreticular metal-organic frameworks and their high performance in the selective capture and separation of large organic molecules. Angew Chem Int Ed 54(43):12748–12752

    Article  CAS  Google Scholar 

  61. Lian X, Yan B (2016) A lanthanide metal–organic framework (MOF-76) for adsorbing dyes and fluorescence detecting aromatic pollutants. RSC Adv 6(14):11570–11576

    Article  CAS  Google Scholar 

  62. Sheng SN, Han Y, Wang B, Zhao C, Yang F, Zhao MJ, Xie YB, Li JR (2016) A novel porous anionic metal–organic framework with pillared double-layer structure for selective adsorption of dyes. J Solid State Chem 233(1):143–149

    Article  CAS  Google Scholar 

  63. Shen X, Yan B (2016) Anionic metal–organic framework hybrids: functionalization with lanthanide ions or cationic dyes and fluorescence sensing of small molecules. RSC Adv 6(34):28165–28170

    Article  CAS  Google Scholar 

  64. Roushani M, Saedi Z, Beygi TM (2016) Anionic dyes removal from aqueous solution using TMU-16 and TMU-16-NH2, as isoreticular nanoporous metal organic frameworks. J Taiwan Inst Chem Eng 66(9):164–171

    Article  CAS  Google Scholar 

  65. Qin L, Zeng SY, Zuo WJ, Liu QH, Li J, Ni G, Wang YQ, Zhang MD (2016) One neutral metal-organic framework with an unusual dmp, topology for adsorption of dyes. Polyhedron 121(1):231–235

    Google Scholar 

  66. Liu XX, Gong WP, Luo J, Zou C, Yang Y, Yang S (2016) Selective adsorption of cationic dyes from aqueous solution by polyoxometalate-based metal–organic framework composite. Appl Surf Sci 362(3):517–524

    Article  CAS  Google Scholar 

  67. Yang L, Li X, Sun CY, Wu H, Wang CG, Su ZM (2017) A stable pillared-layer cu(II) metal–organic framework with magnetic properties for dye adsorption and separation. New J Chem 41(9):3661–3666

    Article  CAS  Google Scholar 

  68. Li Z, Wu YN, Li J (2015) The metal–organic framework MIL-53(Al) constructed from multiple metal sources: alumina, aluminum hydroxide, and boehmite. Chem Eur J 21(18):6913–6920

    Article  CAS  PubMed  Google Scholar 

  69. Khan NA, Jung BK, Hasan Z, Jhung SH (2015) Adsorption and removal of phthalic acid and diethyl phthalate from water with zeolitic imidazolate and metal-organic frameworks. J Hazard Mater 282:194–200

    Article  CAS  PubMed  Google Scholar 

  70. Xu Y, Jin J, Li X, Han Y, Meng H, Song C, Zhang X (2015) Magnetization of a cu(II)-1,3,5-benzenetricarboxylate metal-organic framework for efficient solid-phase extraction of Congo red. Microchim Acta 182(13–14):2313–2320

    Article  CAS  Google Scholar 

  71. Wang T, Wang J, Zhang C, Yang Z, Dai X, Chengm HX (2015) Metal-organic framework MIL-101(Cr) as a sorbent of porous membrane-protected micro-solid-phase extraction for the analysis of six phthalate esters from drinking water: a combination of experimental and computational study. Analyst 140(15):5308–5316

    Article  CAS  PubMed  Google Scholar 

  72. Tahmasebi E, Masoomi MY, Yamini Y, Morsali A (2016) Application of a Zn based metal–organic framework as an efficient solid-phase extraction sorbent for preconcentration of plasticizer compounds. RSC Adv 6(46):40211–40218

    Article  CAS  Google Scholar 

  73. Seo YS, Khan NA, Jhung SH (2015) Adsorptive removal of methylchlorophenoxypropionic acid from water with a metal-organic framework. Chem Eng J 270:22–27

    Article  CAS  Google Scholar 

  74. Jung BK, Hasan Z, Jhung SH (2013) Adsorptive removal of 2,4-dichlorophenoxyacetic acid (2,4-D) from water with a metal–organic framework. Chem Eng J 234:99–105

    Article  CAS  Google Scholar 

  75. Liu XL, Wang C, Wang ZC, Wu Q, Wan Z (2015) Nanoporous carbon derived from a metal organic framework as a new kind of adsorbent for dispersive solid phase extraction of benzoylurea insecticides. Microchim Acta 182(11–12):1903–1910

    Article  CAS  Google Scholar 

  76. Wang X, Ma X, Wang H, Huang P, Du X, Lu X (2017) A zinc(II) benzenetricarboxylate metal organic framework with unusual adsorption properties, and its application to the preconcentration of pesticides. Microchim Acta 184(10):3681–3687

    Article  CAS  Google Scholar 

  77. Hasan Z, Choi E-J, Jhung SH (2013) Adsorption of naproxen and clofibric acid over ametal-organic framework MIL-101 functionalized with acidic and basic groups. Chem Eng J 219:537–544

    Article  CAS  Google Scholar 

  78. Seo PW, Bhadra BN, Ahmed I, Khan NA, Jhung SH (2016) Adsorptive removal of pharmaceuticals and personal care products from water with functionalized metal-organic frameworks: remarkable adsorbents with hydrogen-bonding abilities. Sci Rep 6:34462–34472

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  79. An HJ, Bhadra BN, Khan NA, Jhung SH (2018) Adsorptive removal of wide range of pharmaceutical and personal care products from water by using metal azolate framework-6-derived porous carbon. Chem Eng J 343:447–454

    Article  CAS  Google Scholar 

  80. Jun JW, Tong M, Jung BK, Hasan Z, Zhong C, Jhung SH (2015) Effect of central metal ions of analogous metal-organic frameworks on adsorption of organoarsenic compounds from water: plausible mechanism of adsorption and water purification. Chemistry 21(1):347–354

    Article  CAS  PubMed  Google Scholar 

  81. Jung BK, Jun JW, Hasan Z, Jhung SH (2015) Adsorptive removal of p-arsanilic acid from water using mesoporous zeolitic imidazolate framework-8. Chem Eng J 267:9–15

    Article  CAS  Google Scholar 

  82. Sarker M, Ji YS, Jhung SH (2017) Adsorption of organic arsenic acids from water over functionalized metal-organic frameworks. J Hazard Mater 335:162–169

    Article  CAS  PubMed  Google Scholar 

  83. Wang Q, Wang Y, Zhang Z, Tong Y, Zhang L (2017) Waxberry-like magnetic porous carbon composites prepared from a nickel-organic framework for solid-phase extraction of fluoroquinolones. Microchim Acta 184(10):4107–4115

    Article  CAS  Google Scholar 

  84. Wang T, Liu S, Gao G, Zhao P, Lu N, Lun X, Hou X (2017) Magnetic solid phase extraction of non-steroidal anti-inflammatory drugs from water samples using a metal organic framework of type Fe3O4/MIL-101 (Cr), and their quantitation by UPLC-MS/MS. Microchim Acta 184(8):2981–2990

    Article  CAS  Google Scholar 

  85. Liu H, Chen L, Ding J (2017) A core-shell magnetic metal organic framework of type Fe3O4@ZIF-8 for the extraction of tetracycline antibiotics from water samples followed by ultra-HPLC-MS analysis. Microchim Acta 184(10):4091–4098

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (21375032), the Natural Science Foundation of Hebei Province (B2016201213, B2016201210) and Post-graduate’s Innovation Fund Project of Hebei University (hbu2018ss19).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yun-Kai Lv.

Ethics declarations

The authors declare that they have no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, C., Yu, LQ., Zhao, YT. et al. Recent advances in metal-organic frameworks for adsorption of common aromatic pollutants. Microchim Acta 185, 342 (2018). https://doi.org/10.1007/s00604-018-2879-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00604-018-2879-2

Keywords

Navigation