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Polymer supported 5,10,15,20-tetrakis(phenoxy acetic acid)porphyrin derivative for separation and preconcentration of d- and f-electron metals

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Abstract.

5,10,15,20-tetrakis(phenoxy acetic acid) porphyrin (PAAP) was covalently linked to Merrifield chloromethylated resin. Characterization of PAAP and the modified polymeric matrix were performed by 1H NMR, FTIR and elemental analysis. The sorbent was used for the separation and enrichment of the d-electron metals (Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)) at pH 6–8 and of the f-electron metals U(VI) and Th(IV) at pH 4–5. The metals ions were preconcentrated with a concentration factor range of 115–215 and then determined by flame atomic absorption spectrometry or visible spectrophotometry using Arsenazo(III). The retained metals were eluted with 2.0 mol L−1 HNO3 in the case of the d-electron metals and 0.1/0.25 mol L−1 HCl in the case of the f-electron metals. The procedure was validated by analyzing the NIST standard reference material 2709 (San Joaquin Soil).

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Authors and Affiliations

  1. Chemistry Department, Faculty of Arts and Sciences, Dokuz Eylul University, Buca, Izmir, Turkey

    Serap Seyhan & Melek Merdivan

  2. Chemistry Department, Faculty of Arts and Sciences, Dicle University, Diyarbakir, Turkey

    Nadir Demirel & Halil Hosgoren

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  1. Serap Seyhan
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  2. Melek Merdivan
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  3. Nadir Demirel
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  4. Halil Hosgoren
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Correspondence to Melek Merdivan.

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Correspondence: Melek Merdivan, Chemistry Department, Faculty of Arts and Sciences, Dokuz Eylul University, 35160 Buca, Izmir, Turkey

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Seyhan, S., Merdivan, M., Demirel, N. et al. Polymer supported 5,10,15,20-tetrakis(phenoxy acetic acid)porphyrin derivative for separation and preconcentration of d- and f-electron metals. Microchim Acta 161, 87–93 (2008). https://doi.org/10.1007/s00604-007-0797-9

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  • DOI: https://doi.org/10.1007/s00604-007-0797-9

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