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Thiazolylazo dyes and their application in analytical methods

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Abstract.

An overview is presented on thiazolylazo dyes and their analytical applications in the determination, preconcentration or separation of trace metal ions. The article summarizes conventional analytical methods based on spectrophotometry, solid phase extraction, liquid chromatography and liquid–liquid and cloud point extraction. Both in-batch and on-line procedures are considered. General properties about these ligands are also commented on. Finally, the use of thiazolylazo dyes in procedures involving electroanalytical and other methods is presented.

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References

  • L Ahlström C S Eskilsson E Björklund (2005) ArticleTitleDetermination of banned azo dyes in consumer goods Trends Anal Chem 24 49

    Google Scholar 

  • V Chromy L Sommer (1967) ArticleTitle2-(2-Thiazolylazo)-4-methoxyphenol and 2-(2-thiazolylazo)-5-methoxyphenol as metal-ion indicators Talanta 14 393 Occurrence Handle1:CAS:528:DyaF2sXhtFWhsr0%3D

    CAS  Google Scholar 

  • F Kai H Izumi (1970) ArticleTitleOrtho-(2-thiazolylazo)-4-chlorophenol complexes and their utility as metallochromic indicators for nickel(II) ion Anal Lett 3 307 Occurrence Handle1:CAS:528:DyaE3cXkvVemtL0%3D

    CAS  Google Scholar 

  • V Camel (2003) ArticleTitleSolid phase extraction of trace elements, Spectrochim Acta Part B 58 1177

    Google Scholar 

  • H Wang H S Zhang J K Cheng (1999) ArticleTitleStudies on 2-(2-thiazolylazo)-5-diethylaminophenol as a precolumn derivatizing reagent in the separation of platinum group metals by high performance liquid chromatography Talanta 48 1 Occurrence Handle1:CAS:528:DyaK1MXjvVOntA%3D%3D

    CAS  Google Scholar 

  • M A Bezerra M A Z Arruda S L C Ferreira (2005) ArticleTitleCloud point extraction as a procedure of separation and pre-concentration for metal determination using spectroanalytical techniques: a review Appl Spectrosc Rev 40 1

    Google Scholar 

  • B Subrahmanyam M C Eshwar (1976) ArticleTitleSpectrophotometric determination of chromium(III) with 4-(2-thiazolylazo)-resorcinol Microchim Acta 66 579

    Google Scholar 

  • O Navratil R W Frei (1970) ArticleTitleThe extraction-photometric determination of cadmium and cobalt with 4-(2-thiazolylazo)-resorcinol and 1-(2-thiazolylazo)-naphthol Anal Chim Acta 52 221

    Google Scholar 

  • S L C Ferreira M G M Andrade I P Lobo A C S Costa (1991) ArticleTitle2-(2-thiazolyazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of lead (II) Anal Lett 24 1675 Occurrence Handle1:CAS:528:DyaK3MXlvFOhsb4%3D

    CAS  Google Scholar 

  • M Langová-Hniličková L Sommer (1969) ArticleTitleReaction of galium and indium with 4-(2-thiazolylazo) resorcinol Talanta 16 681

    Google Scholar 

  • H R Hovind (1975) ArticleTitleThiazolylazo dyes and their applications in analytical chemistry Analyst 100 769 Occurrence Handle1975plsc.conf.....H Occurrence Handle1:CAS:528:DyaE28Xjt1Gmuw%3D%3D

    ADS  CAS  Google Scholar 

  • Lemos V A (2001) On-line system for preconcentration and determination of cadmium and lead by flame atomic absorption spectrometry using 2-(2-benzothiazolylazo)-p-cresol loaded polyurethane foam), DSc Thesis (In Portuguese), Universidade Federal da Bahia, Brazil

  • R A Chalmers (1967) ArticleTitleStability constants of TAR and PAR complexes Talanta 14 527 Occurrence Handle1:CAS:528:DyaF2sXktFGnt74%3D Occurrence Handle228663

    CAS  MathSciNet  Google Scholar 

  • I Takase A S Luna R C de Campos (2003) ArticleTitleThe use of 2-2-thiazolylazo-p-cresol to minimize the interference of Ni and Cu for the bismuth determination in alloys by hydride generation atomic absorption spectrometry Talanta 61 597 Occurrence Handle1:CAS:528:DC%2BD3sXos12ru7g%3D

    CAS  Google Scholar 

  • K Ueno T Imamura K L Cheng (1992) Handbook of organic analytical reagents EditionNumber2 CRC Press Boca Raton, Florida, USA

    Google Scholar 

  • H Onishi (1986) Photometric determination of traces of metals, part IIA Wiley New York, US

    Google Scholar 

  • H Onishi (1989) Photometric determination of traces of metals, part IIB Wiley New York, US

    Google Scholar 

  • R G Anderson G Nickless (1967) ArticleTitleHeterocyclic azo dyestuffs in analytical chemistry Analyst 92 207 Occurrence Handle4859975 Occurrence Handle1:CAS:528:DyaF2sXktFOnurg%3D

    PubMed  CAS  Google Scholar 

  • A S Amin E H El-Mossalamy (2003) ArticleTitleSimple spectrophotometric method for the quantitative determination of uranium J Trace Microprobe T 21 637 Occurrence Handle1:CAS:528:DC%2BD3sXoslSgsLo%3D

    CAS  Google Scholar 

  • A S Amin (2001) ArticleTitleSynthesis of some thiazolylazo compounds and their application to the spectrophotometric determination of nickel Quim Anal 20 145 Occurrence Handle1:CAS:528:DC%2BD3MXpt1Sis7k%3D

    CAS  Google Scholar 

  • A S Amin (2001) ArticleTitleDetermination of nickel in biological samples spectrophotometrically involving complexation reaction with some thiazolylazo compounds Ann Chim-Rome 91 103 Occurrence Handle1:CAS:528:DC%2BD3MXisFamsbw%3D

    CAS  Google Scholar 

  • A S Amin (2000) ArticleTitleThe surfactant-sensitized analytical reaction of niobium with some thiazolylazo compounds Microchem J 65 261 Occurrence Handle1:CAS:528:DC%2BD3cXot1Giurs%3D

    CAS  Google Scholar 

  • A S Amin (1999) ArticleTitleDetermination of molybdenum in human urine by spectrophotometric method using thiazolylazo compounds as chromogenic reagents Anal Lett 32 1575 Occurrence Handle1:CAS:528:DyaK1MXjvVGqurs%3D

    CAS  Google Scholar 

  • I S Ahmed (2005) ArticleTitleSelective spectrophotometric investigation and determination with some thiazolylazo compounds, of palladium(II), or of tartaric acid in the presence of niobium(V) Instrum Sci Technol 33 33 Occurrence Handle1:CAS:528:DC%2BD2MXptFSgsQ%3D%3D

    CAS  Google Scholar 

  • S L Zhao X Q Xia X W Kong T S Liu (1997) ArticleTitleHighly sensitive colour-reaction of nickel with a new chromogenic reagent benzothiaxolyldiazoaminoazobenzene and its application Talanta 45 13 Occurrence Handle1:CAS:528:DyaK2sXnsF2ltLk%3D

    CAS  Google Scholar 

  • S T Li S L Zhao (2004) ArticleTitleSpectrophotometric determination of cationic surfactants with benzothiaxolyldiazoaminoazobenzene Anal Chim Acta 501 99 Occurrence Handle1:CAS:528:DC%2BD3sXpvVWjt7s%3D

    CAS  Google Scholar 

  • E Y Hashem M S Abu-Bakr S M Hussain (2003) ArticleTitleInteraction of nickel with (BTAS) and simultaneous first-derivative spectrophotometric determination of nickel(II) and iron(III) Spectrochim Acta Part A 59 761 Occurrence Handle1:STN:280:DC%2BD3s7ntF2mtw%3D%3D

    CAS  Google Scholar 

  • Y M Hao H X Shen (2000) ArticleTitleSimple and sensitive determination of nucleic acids using palladium(II) complex with 2-(2-thiazolylazo)-5-dimethylaminobenzoic acid Anal Chim Acta 422 159 Occurrence Handle1:CAS:528:DC%2BD3cXmslKksLs%3D

    CAS  Google Scholar 

  • A Bhalotra B K Puri (2000) ArticleTitleSimultaneous first derivative spectrophotometric determination of palladium and nickel using 2-(2-thiazolylazo)-5-dimethylaminobenzoic acid as an analytical reagent Microchim Acta 134 139 Occurrence Handle1:CAS:528:DC%2BD3cXms1Cksbs%3D

    CAS  Google Scholar 

  • A Bhalotra B K Puri (2000) ArticleTitleThird derivative spectrophotometric determination of rhodium using 2-(2-thiazolylazo)-5-dimethylaminobenzoic acid as analytical reagent in the presence of triton X-100 Quim Anal 19 25 Occurrence Handle1:CAS:528:DC%2BD3cXjtlKrtLk%3D

    CAS  Google Scholar 

  • X Z Fan G F Zhang C H Zhu (1998) ArticleTitleSynthesis of 2-[2-(5-methylbenzothiazolyl)azo]-5-dimethylaminobenzoic acid and its application to the spectrophotometric determination of nickel Analyst 123 109 Occurrence Handle1:CAS:528:DyaK1cXmsVarsw%3D%3D

    CAS  Google Scholar 

  • X Z Fan C H Zhu (1998) ArticleTitleSyntheses of three new benzoic acid-type thiazolylazo reagents and their application to spectrophotometric determination of microamounts of nickel Microchem J 59 284 Occurrence Handle1:CAS:528:DyaK1cXksVWis74%3D

    CAS  Google Scholar 

  • M I Toral P Richter N Lara M T Escudero C Soto (2000) ArticleTitleSimultaneous determination of platinum and palladium by second derivative spectrophotometry using 3-(2′-thiazolylazo)-2,6-diaminopyridine as chromophore ligand Anal Lett 33 93 Occurrence Handle1:CAS:528:DC%2BD3cXhtVSqsL0%3D

    CAS  Google Scholar 

  • L S G Teixeira A C S Costa S L C Ferreira M D Freitas (1999) ArticleTitleSpectrophotometric determination of uranium using in the presence of surfactants J Brazil Chem Soc 10 519 Occurrence Handle1:CAS:528:DC%2BD3cXhslOktw%3D%3D

    CAS  Google Scholar 

  • L S G Teixeira A C S Costa A S Queiroz A M M Amorim O N Bomfim S L C Ferreira (1998) ArticleTitle2-(2-Thiazolylazo)-p-cresol as a spectrophotometric reagent for vanadium determination in the presence of ascorbic acid Microchim Acta 129 103 Occurrence Handle1:CAS:528:DyaK1cXisVymu7k%3D Occurrence Handle10.1007/BF01246856

    Article  CAS  Google Scholar 

  • G H Rounaghi M S Hosseini E Ghiamati (1998) ArticleTitleCompetitive spectrophotometric study of copper, zinc and cadmium with 18C6 using TAR as a colorimetric complexing agent in methanol Iran J Chem Chem Eng 17 4 Occurrence Handle1:CAS:528:DyaK1cXntFWqtbs%3D

    CAS  Google Scholar 

  • P Pohl Z Bogdal B Prusisz (2005) ArticleTitlePreconcentration and fractionation of Cd, Co, Cu, Ni, Pb and Zn in natural water samples prior to analysis by inductively coupled plasma atomic emission spectrometry Microchim Acta 150 253 Occurrence Handle1:CAS:528:DC%2BD2MXmtVaisrY%3D

    CAS  Google Scholar 

  • A O Martins E L da Silva M C M Laranjeira V T de Favere (2005) ArticleTitleApplication of chitosan functionalized with 8-hydroxyquinoline: determination of lead by flow injection flame atomic absorption spectrometry Microchim Acta 150 27 Occurrence Handle1:CAS:528:DC%2BD2MXktlCitLw%3D

    CAS  Google Scholar 

  • V A Lemos J S Santos L S Nunes (2005) ArticleTitleSynthesis and application of a new functionalized resin in on-line preconcentration of lead Separ Sci Technol 40 1401 Occurrence Handle1:CAS:528:DC%2BD2MXltFaisb4%3D

    CAS  Google Scholar 

  • M Soylak L Elçi I Narin M Dogan (2001) ArticleTitleApplication of solid-phase extraction for the preconcentration and separation of trace amounts of cobalt from urine Trace Elem Electroly 18 26 Occurrence Handle1:CAS:528:DC%2BD3MXhtF2ntbw%3D

    CAS  Google Scholar 

  • W Lee S E Lee M K Kim C H Lee Y S Kim (2002) ArticleTitleA chelating resin containing 2-(2-thiazolylazo)-5-dimethylaminophenol as the functional group: synthesis and sorption behavior for some trace metal ions B Kor Chem Soc 23 1067 Occurrence Handle1:CAS:528:DC%2BD38XmslSisLo%3D Occurrence Handle10.5012/bkcs.2002.23.8.1067

    Article  CAS  Google Scholar 

  • W Lee S E Lee C H Lee Y S Kim Y Lee (2001) ArticleTitleA chelating resin containing 1-(2-thiazolylazo)-2-naphthol as the functional group; synthesis and sorption behavior for trace metal ions Microchem J 70 195 Occurrence Handle1:CAS:528:DC%2BD3MXovFKgsbs%3D

    CAS  Google Scholar 

  • M M Saeed S Z Bajwa M S Ansari R Ahmed (2005) ArticleTitleSolid phase sorption of microamount of Hg(II) onto 1-(2-thiazolylazo)-2-naphthol (TAN) loaded polyurethane foam Radiochim Acta 93 177 Occurrence Handle1:CAS:528:DC%2BD2MXksFGku74%3D

    CAS  Google Scholar 

  • C R Preetha V M Biju T P Rao (2003) ArticleTitleOn-line solid phase extraction preconcentration of ultratrace amounts of zinc in fractionated soil samples for determination by flow injection flame AAS Atom Spectrosc 24 118 Occurrence Handle1:CAS:528:DC%2BD3sXntlSjsb0%3D

    CAS  Google Scholar 

  • A Bhalotra B K Puri (2000) ArticleTitleColumn preconcentration and second derivative spectrophotometric trace determination of scandium in standard biological and synthetic samples using 1-(2-thiazolylazo)-2-naphthol Anal Sci 16 507 Occurrence Handle1:CAS:528:DC%2BD3cXjslCnsLw%3D

    CAS  Google Scholar 

  • Y W Liu Y Gou X J Chang S M Meng D Yang B J Din (2005) ArticleTitleColumn solid-phase extraction with 2-acetylmercaptophenyldiazoaminoazobenzene (AMPDAA) impregnated amberlite XAD-4 and determination of trace heavy metals in natural waters by flame atomic absorption spectrometry Microchim Acta 149 95 Occurrence Handle1:CAS:528:DC%2BD2MXksFymtw%3D%3D

    CAS  Google Scholar 

  • G Venkatesh A K Jain A K Singh (2005) ArticleTitle2,3-Dihydroxypyridine loaded amberlite XAD-2 (AXAD-2-DHP): preparation, sorption-desorption equilibria with metal ions, and applications in quantitative metal ion enrichment from water, milk and vitamin samples Microchim Acta 149 213 Occurrence Handle1:CAS:528:DC%2BD2MXjt1Gqsro%3D

    CAS  Google Scholar 

  • Y S Kim G In C W Han J M Choi (2005) ArticleTitleStudies on synthesis and application of XAD-4-salen chelate resin for separation and determination of trace elements by solid phase extraction Microchem J 80 151 Occurrence Handle1:CAS:528:DC%2BD2MXjs1SksL4%3D

    CAS  Google Scholar 

  • V A Lemos E M Gama A S Lima (2006) ArticleTitleOn-line preconcentration and determination of cadmium, cobalt and nickel in food samples by flame atomic absorption spectrometry using a new functionalized resin Microchim Acta 153 179 Occurrence Handle1:CAS:528:DC%2BD28Xht1Wkt78%3D

    CAS  Google Scholar 

  • S L C Ferreira W N L dos Santos V A Lemos (2001) ArticleTitleOn-line preconcentration system for nickel determination in food samples by flame atomic absorption spectrometry Anal Chim Acta 445 145 Occurrence Handle1:CAS:528:DC%2BD3MXnslCks7s%3D

    CAS  Google Scholar 

  • S L C Ferreira V A Lemos R E Santelli E Ganzarolli (2001) ArticleTitleAn automated on-line flow system for the pre-concentration and determination of lead by flame atomic absorption spectrometry Microchem J 68 41 Occurrence Handle1:CAS:528:DC%2BD3MXivVagsLw%3D

    CAS  Google Scholar 

  • G M Wuilloud R G Wuilloud J C A Wuilloud R A Olsina L D Martinez (2003) ArticleTitleOn-line preconcentration and determination of chromium in by flow injection – flame atomic absorption spectrometry J Pharmaceut Biomed 31 117 Occurrence Handle1:CAS:528:DC%2BD3sXmsFWqsw%3D%3D

    CAS  Google Scholar 

  • R G Wuilloud G M Wuilloud J C A Wuilloud R A Olsina L D Martinez (2002) ArticleTitlePreconcentration and speciation of Cr(III) and Cr(VI) in water samples using amberlite XAD-16 resin and determination by flow injection-flame AAS Atom Spectrosc 23 44 Occurrence Handle1:CAS:528:DC%2BD38Xkt1emsrY%3D

    CAS  Google Scholar 

  • C H Lee M Y Suh J S Kim D Y Kim W H Kim T Y Eom (1999) ArticleTitleSeparation and preconcentration of uranium from geological materials with chelating resin containing 4-(2-thiazolylazo)resorcinol functional groups Anal Chim Acta 382 199 Occurrence Handle1:CAS:528:DyaK1MXps1GlsQ%3D%3D

    CAS  Google Scholar 

  • W N L dos Santos C M dos Santos S L C Ferreira (2005) ArticleTitleField sampling system for determination of cadmium and nickel in fresh water by flame atomic absorption spectrometry J Brazil Chem Soc 16 727 Occurrence Handle1:CAS:528:DC%2BD2MXosVals7s%3D

    CAS  Google Scholar 

  • S L C Ferreira M A Bezerra W N L dos Santos B B Neto (2003) ArticleTitleApplication of Doehlert designs for optimisation of an on-line preconcentration system for copper determination by flame atomic absorption spectrometry Talanta 61 295 Occurrence Handle1:CAS:528:DC%2BD3sXotVCms7g%3D

    CAS  Google Scholar 

  • S L C Ferreira H C dos Santos J R Ferreira N M L de Araújo A C S Costa D S de Jesus (1998) ArticleTitlePreconcentration and determination of copper and zinc in natural water samples by ICP-AES after complexation and sorption on amberlite XAD-2 J Brazil Chem Soc 9 525 Occurrence Handle1:CAS:528:DyaK1MXhvVWgtL0%3D

    CAS  Google Scholar 

  • J Vacha L Sommer (1993) ArticleTitlePreconcentration of uranium(VI) on modified and unmodified amberlite XAD-4 sorbent Collect Czech Chem C 58 1813 Occurrence Handle1:CAS:528:DyaK3sXmsFKitb8%3D

    CAS  Google Scholar 

  • S L Ferreira C F de Brito (1999) ArticleTitleSeparation and preconcentration of cobalt after sorption onto amberlite XAD-2 loaded with 2-(2-thiazolylazo)-p-cresol Anal Sci 15 189 Occurrence Handle1:CAS:528:DyaK1MXhslansb0%3D

    CAS  Google Scholar 

  • U Divrikli M Soylak L Elçi (2003) ArticleTitleSeparation and enrichment of gallium(III) as complex by solid phase extraction on amberlite XAD-4 adsorption resin Anal Lett 36 839 Occurrence Handle1:CAS:528:DC%2BD3sXjtl2hsbc%3D

    CAS  Google Scholar 

  • M Soylak U Divrikli L Elçi M Dogan (1998) ArticleTitleColumn chromatographic preconcentration and enrichment of copper, nickel and iron in by graphite furnace atomic absorption spectrometry Kuwait J Sci Eng 25 389 Occurrence Handle1:CAS:528:DyaK1MXmsVansA%3D%3D

    CAS  Google Scholar 

  • T Braun J D Navratil A B Farag (1985) Polyurethane foam sorbents in separation science CRC Press Boca Raton

    Google Scholar 

  • O D Sant’Ana L S Jesuino R J Cassella M S de Carvalho R E Santelli (2004) ArticleTitleDetermination of lead by employing a novel sampling strategy of polyurethane foam impregnated with thiazolylazo-p-cresol (TAC) J Brazil Chem Soc 15 96 Occurrence Handle1:CAS:528:DC%2BD2cXjsFeqsrw%3D

    CAS  Google Scholar 

  • D S de Jesus M S de Carvalho A C S Costa S L C Ferreira (1998) ArticleTitleQuantitative separation of zinc traces from cadmium matrices by solid-phase extraction with polyurethane foam Talanta 46 1525 Occurrence Handle1:CAS:528:DyaK1cXkvVKnt7g%3D

    CAS  Google Scholar 

  • R J Cassella R E Santelli A G Branco V A Lemos S L C Ferreira M S de Carvalho (1999) ArticleTitleSelectivity enhancement in spectrophotometry: on-line interference suppression using polyurethane foam minicolumn for aluminum determination with Methyl Thymol Blue Analyst 124 805 Occurrence Handle1:CAS:528:DyaK1MXivVSmu7s%3D

    CAS  Google Scholar 

  • V A Lemos D R Vieira C G Novaes M E Rocha M S Santos R T Yamaki (2006) ArticleTitlePreconcentration systems using polyurethane foam/Me-BDBD for determination of copper in food samples Microchim Acta 153 193 Occurrence Handle1:CAS:528:DC%2BD28Xht1Wktrw%3D

    CAS  Google Scholar 

  • E M Gama A S Lima V A Lemos (2006) ArticleTitlePreconcentration system for cadmium and lead determination in environmental samples using polyurethane foam/Me-BTANC J Hazard Mater 136 757 Occurrence Handle16530947 Occurrence Handle1:CAS:528:DC%2BD28XotVeisro%3D

    PubMed  CAS  Google Scholar 

  • V A Lemos A A de Jesus E M Gama G T Davis R T Yamaki (2005) ArticleTitleOn-line solid phase extraction and determination of copper in food samples using polyurethane foam loaded with Me-BTANC Anal Lett 38 683 Occurrence Handle1:CAS:528:DC%2BD2MXjsVaqtbs%3D

    CAS  Google Scholar 

  • S L C Ferreira W N L dos Santos M A Bezerra V A Lemos J M Bosque-Sendra (2003) ArticleTitleUse of factorial design and Doehlert matrix for multivariate optimisation of an on-line preconcentration system for lead determination by flame atomic absorption spectrometry Anal Bioanal Chem 375 443 Occurrence Handle12589511 Occurrence Handle1:CAS:528:DC%2BD3sXhtFCrt7c%3D

    PubMed  CAS  Google Scholar 

  • V A Lemos W N L dos Santos J S Santos M B de Carvalho (2003) ArticleTitleOn-line preconcentration system using a minicolumn of polyurethane foam loaded with Me-BTABr for zinc determination by flame atomic absorption spectrometry Anal Chim Acta 481 283 Occurrence Handle1:CAS:528:DC%2BD3sXitFKju78%3D

    CAS  Google Scholar 

  • V A Lemos R E Santelli M S de Carvalho S L C Ferreira (2000) ArticleTitleApplication of polyurethane foam loaded with BTAC in an on-line preconcentration system: cadmium determination by FAAS Spectrochim Acta Part B 55 1497

    Google Scholar 

  • V A Lemos M de la Guardia S L C Ferreira (2002) ArticleTitleAn on-line system for preconcentration and determination of lead in wine samples by FAAS Talanta 58 475 Occurrence Handle1:CAS:528:DC%2BD38XntVGktr0%3D

    CAS  Google Scholar 

  • V A Lemos S L C Ferreira (2001) ArticleTitleOn-line preconcentration system for lead determination in seafood samples by flame atomic absorption spectrometry using polyurethane foam loaded with 2-(2-benzothiazolylazo)-2-p-cresol Anal Chim Acta 441 281 Occurrence Handle1:CAS:528:DC%2BD3MXlslCit7Y%3D

    CAS  Google Scholar 

  • A Bhalotra B K Puri (1999) ArticleTitleTrace determination of zinc in standard alloys, environmental and pharmaceutical samples by fourth derivative spectrophotometry using 1-2-(thiazolylazo)-2-naphthol as reagent and ammonium tetraphenylborate supported on naphthalene as adsorbent Talanta 49 485 Occurrence Handle1:CAS:528:DyaK1MXktFKmsL4%3D

    CAS  Google Scholar 

  • A Bhalotra B K Puri (2001) ArticleTitlePreconcentration of bismuth(III) and copper(II) by solid-phase extraction and subsequent determination by differential pulse polarography J AOAC Int 84 47 Occurrence Handle11234851 Occurrence Handle1:CAS:528:DC%2BD3MXis1altrw%3D

    PubMed  CAS  Google Scholar 

  • A Bhalotra Atamiyot B K Puri (2002) ArticleTitleSimultaneous determination of cadmium and lead in a standard alloy, various biological and environmental samples by differential pulse polarography after pre-concentration by solid-phase extraction of their 1-(2-thiazolylazo)-2-naphthol-tetraphenylborate complexes on microcrystalline naphthalene Quim Anal 20 229 Occurrence Handle1:CAS:528:DC%2BD38XktFCitrk%3D

    CAS  Google Scholar 

  • D Kara N Tekin (2005) ArticleTitleSolid-phase extraction and spectrophotometric determination of trace amounts of mercury in natural samples Microchim Acta 149 193 Occurrence Handle1:CAS:528:DC%2BD2MXjt1Gqsr8%3D

    CAS  Google Scholar 

  • P Liang W J Fa (2005) ArticleTitleDetermination of La, Eu and Yb in water samples by inductively coupled plasma atomic emission spectrometry after solid phase extraction of their 1-phenyl-3-methyl-4-benzoylpyrazol-5-one complexes on silica gel column Microchim Acta 150 15 Occurrence Handle1:CAS:528:DC%2BD2MXktlCitL8%3D

    CAS  Google Scholar 

  • L S G Teixeira A C S Costa S Garrigues M de la Guardia (2002) ArticleTitleFlow-injection solid phase partial least-squares spectrophotometric simultaneous determination of iron, nickel and zinc J Brazil Chem Soc 13 54 Occurrence Handle1:CAS:528:DC%2BD38XosFCisA%3D%3D

    CAS  Google Scholar 

  • L S G Teixeira F R P Rocha M Korn B F Reis S L C Ferreira A C S Costa (1999) ArticleTitleFlow-injection solid-phase spectrophotometry for the determination of zinc in pharmaceutical preparations Anal Chim Acta 383 309 Occurrence Handle1:CAS:528:DyaK1MXht1Gjs78%3D

    CAS  Google Scholar 

  • M Arndt I Zadrozna A Dybko W Wroblewski K Kasiura (2003) ArticleTitlePalladium determination using flow-through spectrophotometric sensing phase Sensor Actuat B-Chem 90 332

    Google Scholar 

  • Z Chen B Li M Miao G Yang J Yin Q Su (2005) ArticleTitleSimultaneous determination of palladium, platinum and rhodium by on-line column enrichment and HPLC with 4-hydroxy-1-naphthalthiorhodanine as pre-column derivatization reagents Microchim Acta 152 93 Occurrence Handle1:CAS:528:DC%2BD2MXht1SmtLbL

    CAS  Google Scholar 

  • L Qiping Z Huashan C Jieke (1991) ArticleTitleReversed-phase HPLC determination of some noble metals as their thiazolylazoresorcinol chelates Talanta 38 669 Occurrence Handle1:STN:280:DC%2BD1cjgtVCnsA%3D%3D

    CAS  Google Scholar 

  • N Uehara K Fukuda Y Shijo (1998) ArticleTitleDetermination of cobalt in natural water as a 2-(5-bromo-2-pyridylazo)-5-[n-propyl-n-(3-sulphopropyl)amino]phenol chelate by on-line preconcentration HPLC with column-switching technique Anal Sci 14 343 Occurrence Handle1:CAS:528:DyaK1cXislKmt7k%3D

    CAS  Google Scholar 

  • C S Lin X S Zhang X Z Liu (1991) ArticleTitleDetermination of iron, cobalt and nickel as chelates with 4-(2-thiazolylazo) resorcinol by reversed-phase high-performance liquid chromatography Analyst 116 277 Occurrence Handle1:CAS:528:DyaK3MXhsFKht70%3D

    CAS  Google Scholar 

  • Y Chung W Chung (2003) ArticleTitleDetermination of Co(II) ion as a 4-(2-thiazolylazo) resorcinol or 5-methyl-4-(2-thiazolylazo) resorcinol chelate by reversed-phase capillary high-performance liquid chromatography B Kor Chem Soc 24 1781 Occurrence Handle2003sath.conf.....C Occurrence Handle1:CAS:528:DC%2BD2cXhsFeisg%3D%3D Occurrence Handle10.5012/bkcs.2003.24.12.1781

    Article  ADS  CAS  Google Scholar 

  • W Lee M K Kim E K Kim K S Park Y S Kim (2001) ArticleTitleStudies on the retention behaviour of some thiazolylazo derivatives in reversed phase liquid chromatography Microchem J 70 187 Occurrence Handle1:CAS:528:DC%2BD3MXovFKgsbo%3D

    CAS  Google Scholar 

  • I V Mishenina E N Shaovalova T A Bolshova P V Smirnov O A Shipgun (1996) ArticleTitleEffect of the nature of the stationary phase on the retention of metal chelates with 2-(2-thiazolylazo)-5-diethylaminophenol in high-performance liquid chromatography J Anal Chem 51 270 Occurrence Handle1:CAS:528:DyaK28Xit1Ogsbw%3D

    CAS  Google Scholar 

  • H Wang H S Zhang J K Cheng P H Oiu (1997) ArticleTitleDetermination of V(V), Nb(V), and Ta(V) with 2-(2-thiazolylazo)-5-diethylaminophenol by reversed-phase high performance liquid chromatography Microchem J 55 332 Occurrence Handle1:CAS:528:DyaK2sXhvVymu7o%3D

    CAS  Google Scholar 

  • Q P Liu T Zhao J C Liu J K Cheng (1996) ArticleTitleDetermination of platinum metals complexes with by reversed-phase high performance liquid chromatography Microchim Acta 122 27 Occurrence Handle1:CAS:528:DyaK28Xhs1amsrg%3D

    CAS  Google Scholar 

  • Z L Ma Y P Wang C X Wang F Z Miao W X Ma (1997) ArticleTitleReversed-phase ion-pair high performance liquid chromatographic determination of Co(III), Ni(II), V(V) and Fe(III)-2-(2-benzothiazolylazo)-5-(3-sulforpropyl)aminophenol chelates Talanta 44 743 Occurrence Handle1:CAS:528:DyaK2sXjtl2ltbg%3D

    CAS  Google Scholar 

  • L L Ying M D Gui Y Q Zhao (1995) ArticleTitleRevised-phase HPLC determination of Co(II), Ni(II) and Fe(III) as their 2-(2-thiazolylazo)-5-dimethylaminophenol chelates Talanta 42 89

    Google Scholar 

  • Q P Liu Y C Wang J C Liu C Jieke (1995) ArticleTitleSeparation mechanism exploration on metal-MBTAE-salicylic acid mixed-ligand complexes by reversed-phase high-performance liquid-chromatography Talanta 42 901

    Google Scholar 

  • Q P Liu J C Liu Y Tong J Cheng (1992) ArticleTitleSeparation and determination of Pt(II), Rh(III), Pd(II), Os(IV), Ni(II) and Co(II) complexes by reversed-phase liquid-chromatography Anal Chim Acta 269 223 Occurrence Handle1:CAS:528:DyaK3sXhsFGquw%3D%3D

    CAS  Google Scholar 

  • J Dolezal L Sommer (1994) ArticleTitleReverse-phase high-performance liquid-chromatography of metal-chelates of 4-(2-pyridylazo)resorcinol and 4-(2-thiazolylazo)resorcinol – simultaneous determination of low concentrations of Co, Ni and Fe Collect Czech Chem C 59 2209 Occurrence Handle1:CAS:528:DyaK2MXisVGntLw%3D

    CAS  Google Scholar 

  • C S Lin X S Zhang G C Li S Q Liang (1991) ArticleTitleOn separation and determination of vanadium, cobalt and chromium as chelates with 4-(2-thiazolylazo) resorcinol by reversed-phase HPLC Acta Chim Sinica 49 249 Occurrence Handle1:CAS:528:DyaK3MXisFykt74%3D

    CAS  Google Scholar 

  • Z Marczenko (1976) Spectrophotometric determination of elements Wiley & Sons New York, USA

    Google Scholar 

  • S L C Ferreira A S Queiroz M D A Korn A C S Costa (1997) ArticleTitleDetermination of nickel in alkaline salts by inductively coupled plasma atomic emission spectroscopy using 1-(2-thiazolylazo)-p-cresol for preconcentration and separation Anal Lett 30 2251 Occurrence Handle1:CAS:528:DyaK2sXmt1Gntro%3D

    CAS  Google Scholar 

  • S L C Ferreira A S Queiroz J C R Assis M D A Korn A C S Costa (1997) ArticleTitleDetermination of iron in alkaline salts by ICP-AES using 1-(2-thiazolylazo)-p-cresol (TAC) for preconcentration and separation J Brazil Chem Soc 8 621 Occurrence Handle1:CAS:528:DyaK1cXhvV2ju7g%3D

    CAS  Google Scholar 

  • E Makrilik P Vanura (2000) ArticleTitleContribution to the termodynamics of 1-(2-thiazolylazo)-2-naphthol in the water nitrobenzene extraction system J Serb Chem Soc 65 581

    Google Scholar 

  • A E Visser S T Griffin D H Hartman R D Rogers (2000) ArticleTitleNaphthol- and resorcinol-based azo dyes as metal ion complexants in aqueous biphasic systems J Chromatogr B 743 107 Occurrence Handle1:CAS:528:DC%2BD3cXktlKmsLY%3D

    CAS  Google Scholar 

  • P Liang J Li X Yang (2005) ArticleTitleCloud point extraction preconcentration of trace cadmium as 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone complex and determination by flame atomic absorption spectrometry Microchim Acta 152 47 Occurrence Handle1:CAS:528:DC%2BD2MXht1SmtLfO

    CAS  Google Scholar 

  • M J Rosen (1987) Surfactants and interfacial phenomena John Wiley New York, USA

    Google Scholar 

  • Z F Fan (2005) ArticleTitleSpeciation analysis of antimony(III) and antimony(V) by flame atomic absorption spectrometry after separation/preconcentration with cloud point extraction Microchim Acta 152 29 Occurrence Handle1:CAS:528:DC%2BD2MXht1Smtb7P

    CAS  Google Scholar 

  • H S Ferreira M A Bezerra S L C Ferreira (2006) ArticleTitleA pre-concentration procedure using cloud point extraction for the determination of manganese in saline effluents of a petroleum refinery by flame atomic absorption spectrometry Microchim Acta 154 163 Occurrence Handle1:CAS:528:DC%2BD28XjslCrsrw%3D

    CAS  Google Scholar 

  • J R Chen K C Teo (2001) ArticleTitleDetermination of cobalt and nickel in water samples by flame atomic absorption spectrometry after cloud point extraction Anal Chim Acta 434 325 Occurrence Handle1:CAS:528:DC%2BD3MXjtFOrtbY%3D

    CAS  Google Scholar 

  • K C Teo J R Chen (2001) ArticleTitleDetermination of manganese in water samples by flame atomic absorption spectrometry after cloud point extraction Analyst 126 534 Occurrence Handle11340994 Occurrence Handle1:CAS:528:DC%2BD3MXit1yisLg%3D

    PubMed  CAS  Google Scholar 

  • J R Chen K C Teo (2001) ArticleTitleDetermination of cadmium, copper, lead and zinc in water samples by flame atomic absorption spectrometry after cloud point extraction Anal Chim Acta 450 215 Occurrence Handle1:CAS:528:DC%2BD3MXovFKhtbo%3D

    CAS  Google Scholar 

  • M A Bezerra A L B Conceição S L C Ferreira (2006) ArticleTitleA pre-concentration procedure using cloud point extraction for the determination of uranium in natural water Microchim Acta 154 149 Occurrence Handle1:CAS:528:DC%2BD28XjslCku7Y%3D

    CAS  Google Scholar 

  • V A Lemos J S Santos P X Baliza (2006) ArticleTitleMe-BTABr reagent in cloud point extraction for spectrometric determination of copper in water samples J Brazil Chem Soc 17 30 Occurrence Handle1:CAS:528:DC%2BD28XisFaitb8%3D

    CAS  Google Scholar 

  • P L Croot M Johansson (2000) ArticleTitleDetermination of iron speciation by cathodic stripping voltammetry in seawater using the competing ligand 2-(2-thiazolylazo)-p-cresol (TAC) Electroanal 12 565 Occurrence Handle1:CAS:528:DC%2BD3cXjs12hurw%3D

    CAS  Google Scholar 

  • I C S Fraga P A M Farias A K Ohara (2000) ArticleTitleDetermination of molybdenum in the presence of by catalytic-adsorptive stripping voltammetry Fresen J Anal Chem 366 307 Occurrence Handle1:CAS:528:DC%2BD3cXntl2rsQ%3D%3D

    CAS  Google Scholar 

  • N Menek S Topcu (2003) ArticleTitleElectrochemical behaviour of 5-methyl-(2-thiazolylazo)-resorcinol B Electrochem 19 133 Occurrence Handle1:CAS:528:DC%2BD3sXjvFKjsb0%3D

    CAS  Google Scholar 

  • E M Basova V M Ivanov O A Shpigun (1999) ArticleTitleInfluence of ligand nature on the retention of heterocyclic azonaphthols and their chelates in thin-layer chromatography J Anal Chem 54 349 Occurrence Handle1:CAS:528:DyaK1MXis1Gns7s%3D

    CAS  Google Scholar 

  • S Cerutti S L C Ferreira J A Gásquez R A Olsina L D Martinez (2004) ArticleTitleOptimization of the preconcentration system of cadmium with 1(2-thiazolylazo)-p-cresol using a knotted reactor and flame atomic absorption spectrometric detection J Hazard Mater 112 279 Occurrence Handle15302449 Occurrence Handle1:CAS:528:DC%2BD2cXmtlOrsL0%3D

    PubMed  CAS  Google Scholar 

  • R J Cassella V A Salim L S Jesuíno R E Santelli S L C Ferreira M S de Carvalho (2001) ArticleTitleFlow injection determination of cobalt after its sorption onto polyurethane foam loaded with 2-(2-thiazolylazo)-p-cresol (TAC) Talanta 54 61 Occurrence Handle1:CAS:528:DC%2BD3MXhslCqtb8%3D

    CAS  Google Scholar 

  • V A Lemos C F de Brito A C Ferreira M D A Korn (2002) ArticleTitleFlame atomic absorption spectrometric determination of cobalt after on-line preconcentration Can J Anal Sci Spect 47 49 Occurrence Handle1:CAS:528:DC%2BD38XotFKmt7s%3D

    CAS  Google Scholar 

  • M H A Melo S L C Ferreira R E Santelli (2000) ArticleTitleDetermination of cadmium by FAAS after on-line enrichment using a mini column packed with amberlite XAD-2 loaded with TAM Microchem J 65 59 Occurrence Handle1:CAS:528:DC%2BD3cXlt1Wrtro%3D

    CAS  Google Scholar 

  • A M Starving T P Rao (2004) ArticleTitleRemoval and recovery of mercury(II) from hazardous wastes using 1-(2-thiazolylazo)-2-naphthol functionalized activated carbon as solid phase extractant J Hazard Mat 113 77

    Google Scholar 

  • F S Oliveira L S G Teixeira M Korn (2000) ArticleTitleApplication of partial least squares calibration for multicomponents determination by flow injection-solid phase spectrophotometry Lab Robotics Automat 12 305 Occurrence Handle1:CAS:528:DC%2BD3MXhtlOisw%3D%3D

    CAS  Google Scholar 

  • L S G Teixeira J O N Reis A C S Costa S L C Ferreira M D A Korn J B de Andrade (1998) ArticleTitleICP-AES determination of small amounts of zinc in copper-base alloys after separation by adsorption of the zinc-TAN complex on Sep Pak C18 cartridges Talanta 46 1279 Occurrence Handle1:CAS:528:DyaK1cXkvVKhtr0%3D

    CAS  Google Scholar 

  • A Bhalotra B K Puri (2000) ArticleTitleFirst derivative spectrophotometric determination of iridium with 2-(2-thiazolylazo)-5-dimethylaminophenol in various synthetic samples using ammonium tetraphenylborate – naphthalene as adsorbent Ann Chim-Rome 90 265 Occurrence Handle1:CAS:528:DC%2BD3cXivFKitbg%3D

    CAS  Google Scholar 

  • I Narin M Soylak (1999) ArticleTitleDetermination of cadmium, copper, lead and nickel contents of water samples from Tabakhane River and Akkaya Dam, Nigde-Turkey after preconcentration on activated carbon Fresen Environ Bull 8 24 Occurrence Handle1:CAS:528:DyaK1MXotFyhsQ%3D%3D

    CAS  Google Scholar 

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Lemos, V., Santos, E., Santos, M. et al. Thiazolylazo dyes and their application in analytical methods. Microchim Acta 158, 189–204 (2007). https://doi.org/10.1007/s00604-006-0704-9

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