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Electron Excited M X-Ray Spectra of the Elements 55≤Z≤58

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Abstract.

The M emission spectra of the elements 55 Cs, 56 Ba, 57 La, and 58 Ce were measured using wavelength dispersive X-ray spectrometry with a TAP crystal as the dispersing element. In total, 34 M lines were observed, of which only 13 are contained in the compilation of Bearden. Mα and Mβ of 56 Ba are among the new lines. They have their origin in a similar process to one that is known for 57 La. The interpretation of these spectra is complicated by the strong overlap of some emission lines with the MIV,V absorption structures, which may lead to anomalous self-absorption effects. Therefore, we have concentrated on spectra taken at a low energy of the exciting electrons, E0=2.5 keV. However, in order to illustrate the anomalous self-absorption effects parts of the 2.5 keV spectra, of Ba and La, are shown in comparison with the 10 keV spectra.

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Correspondence to Michael Wendt.

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Dellith, J., Wendt, M. Electron Excited M X-Ray Spectra of the Elements 55≤Z≤58. Microchim. Acta 145, 25–28 (2004). https://doi.org/10.1007/s00604-003-0122-1

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  • DOI: https://doi.org/10.1007/s00604-003-0122-1

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