Abstract
The bonding of hydrophobic, reconstructed (001) Si surfaces obtained with high temperature H2 processes has been studied with atomic force microscopy, low energy electron diffraction spectroscopy, X-ray reflectivity and bonding energy measurements. Surface reconstruction is shown to strongly affect bonding mechanisms. As a consequence, bonding energies of such surfaces are significantly higher, in the room temperature −500 °C range, than those of “HF-last” surfaces.
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References
Greenwood JA, Williamson JBP (1966) Contact of nominally flat surfaces. Proc R Soc Lond A 295:300
Hamaker HC (1937) The London—van der Waals attraction between spherical particles. Physica 4(10):1058–1072
Hertz H (1882) Ueber die Berührung fester elastischer Körper. J Reine Angew Math 92:156–171
Loup V, Hartmann JM, Rolland G, Holliger P, Laugier F, Lafond D, Séméria MN, Besson P, Gentile P (2003) Reduced pressure chemical vapour deposition of Si/Si1-x-yGexCy heterostructures using a chlorinated chemistry. Semicond Sci Technol 18(4):352–360
Maszara WP, Goetz G, Caviglia A, McKitterick JB (1988) Bonding of silicon wafers for silicon-on-insulator. J Appl Phys 64(10):4943–4950
Rieutord F, Eymery J, Fournel F, Buttard D, Oeser R, Plantevin O, Moriceau H, Aspar B (2001) High energy x-ray reflectivity of buried interfaces created by wafer bonding. Phys Rev B 63:125408
Rieutord F, Capello L, Beneyton R, Morales C, Charvet AM, Moriceau H (2006) Rough surface adhesion mechanisms for wafer bonding. ECS Trans 3(6):205–215
Tardif F, Lardin T, Abolafia Y, Danel A, Boelen P, Cowache C, Kashkoush I, Novak R (1999) New aspects of the diluted dynamic clean process. Diffus Defect Data Pt.B: Solid State Phenom 65–66:19–22
Tong QY, Gösele U (1999) Semiconductor wafer bonding; Science and technology. John Wiley and Sons, Hoboken
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This work has been partly funded by the “AtMol” European Union Project (Grant agreement no 270028).
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Rauer, C., Rieutord, F., Hartmann, J.M. et al. Hydrophobic direct bonding of silicon reconstructed surfaces. Microsyst Technol 19, 675–679 (2013). https://doi.org/10.1007/s00542-013-1735-x
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DOI: https://doi.org/10.1007/s00542-013-1735-x