Abstract
Mineral dust and other constituents of Devonian atmospheric aerosols together with certain amounts of aquatic suspensions of riverine detrital origin, colloidal particle dispersions and seawater solutes were embedded in ~95–98% (or purer) limestones on a consistently subsiding isolated carbonate platform where they formed very complex impurity systems. Very low Th/U values, relative abundance of Fe but a slight excess of K typically characterize these ultrafine impurities which are mineralogically dominated by smectite–illite and mica (sericite) together with goethite. In vertical section, these impurities are arranged like incremental series of light and dense bands. The combined method of natural gamma-ray spectrometric and magnetic susceptibility measurements (GRS–MS) together with background of major and trace element analyses provided first systematic insights into fine-scale variability of these impurities in a pile of pure carbonate platform beds, mostly in inner platform Amphipora limestone facies. These carbonates were deposited close to sea level but far from river mouths, and they represented a certain sort of a relatively “independent” medium that was primarily sensitive to climatically (and by rare events) controlled input of atmospheric dust. A remarkable similarity of MS stratigraphic patterns that reflect the quantity and quality of embedded impurities in very distant and paleogeographically separated Devonian basins might be seen as supporting this viewpoint. A long composite stratigraphic section of the Moravian Karst ranges from mid-Eifelian to end-Frasnian levels and yields a number of time characterizing GRS–MS variations that can potentially serve as templates for high-resolution stratigraphic correlations over long distances.
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Alibert C, Kinsley L, Fallon SJ, McCulloch MT, Birkelmans R, McAllister F (2003) Source of trace element variability in the Great Barrier Reef corals affected by the Burdekin flood plumes. Geochim Cosmochim Acta 67:231–246
Babek O (1996) Thinning and fining-upward megasequences in Middle Devonian carbonate slope deposits, Moravia, Czech Republic. Neues Jahrb Geol Palaeont Abh 202:409–432
Bond D, Zaton M (2003) Gamma-ray spectrometry across the Upper Devonian basin succession at Kowala in the Holy Cross Mountains (Poland). Acta Geol Polon 53:93–99
Bory A, Dulac F, Moulin C, Chiapello I, Newton PP, Guelle W, Lambert CE, Bergametti G (2002) Atmospheric and oceanic dust fluxes in the northeastern tropical Atlantic Ocean: how close a coupling? Ann Geophys 20:2067–2076
Bosak P, Mylroie JE, Hladil J, Carew JL, Slavik L (2002) Blow Hole Cave. An unroofed cave on San Salvador Island, the Bahamas, and its importance for detection of paleokarst caves on fossil carbonate platforms. Acta Carsol 31:51–74
Chamley H, Proust JN, Mansy JL, Boulvain F (1997) Diagenetic and palaeogeographic significance of clay, carbonate and other sedimentary components in the middle Devonian limestones of western Ardenne, France. Palaeogeogr Palaeoclimatol Palaeoecol 129:369–385
Collinson DW (1983) Methods in rock magnetism and palaeomagnetism: techniques and instrumentations. Chapman and Hall, London, p 503
Copper P (2001) Reef development at the Frasnian/Famennian mass extinction boundary. Palaeogeogr Palaeoclimatol Palaeoecol 181:27–65
Copper P, Scotese C (2003) Megareefs in mid-Devonian supergreenhouse climates. In: Chan MA, Archer AW (eds) Extreme depositional environments: mega end members in geologic time. Geol Soc Am Spec Pap 370:209–230
Cotter E (2000) Depositional setting and cyclic development of the lower part of the Witteberg Group (Mid- to Upper Devonian), Cape Supergroup, Western Cape, South Africa. South Afr J Geol 103:1–14
Crick RE, Ellwood BB, El Hassani A (1994) Integration of biostratigraphy, magnetic susceptibility and relative sea-level change: a new look at high resolution correlation. SDS Newslett 11:59–66
Crick RE, Ellwood BB, El Hassani A, Feist R, Hladil J (1997) Magnetosusceptibility event and cyclostratigraphy (MSEC) of the Eifelian-Givetian GSSP and associated boundary sequences in North Africa and Europe. Episodes 20:167–175
Crick RE, Ellwood BB, Hladil J, El Hassani A, Hrouda F, Chlupac I (2001) Magnetostratigraphy susceptibility of the Pridolian-Lochkovian (Silurian-Devonian) GSSP (Klonk, Czech Republic) and a coeval sequence in Anti-Atlas, Morocco. Palaeogeogr Palaeoclimatol Palaeoecol 167:73–100
Crick RE, Ellwood BB, Feist R, El Hassani A, Schindler E, Dreesen R, Over DJ, Girard C (2002) Magnetostratigraphy susceptibility of the Frasnian/Famennian boundary. Palaeogeogr Palaeoclimatol Palaeoecol 181:67–90
da Silva C, Boulvain F (2002) Sedimentology, magnetic susceptibility and isotopes of a Middle Frasnian carbonate platform: Tailfer section, Belgium. Facies 46:89–102
da Silva C, Boulvain F (2003) Sedimentology, magnetic susceptibility and correlations of Middle Frasnian platform limestone (Tailfer and Aywaille sections, Belgium). Geologica Belgica 6:81–96
da Silva C, Boulvain F (2005) Upper Devonian carbonate platform correlations and sea level variations recorded in magnetic susceptibility. Palaeogeogr Palaeoclimatol Palaeoecol, in press
Derbyshire E (2003) Loess, and the dust indicators and records of terrestrial and marine palaeoenvironments (DIRTMAP) database. Q Sci Rev 22:1813–1819
Doriguetto AC, Goulart AT, de Jesus Filho MF, Fabris JD, Santana GP (1998) Ilmenite in soil forming from Brazilian amphibolite. Eur J Soil Sci 49:541–545
Duce RA, Tindale NW (1991) Atmospheric transport of iron and its deposition in the ocean. Limnol Oceanogr 36:1715–1726
Dunlop DJ, Ozdemir O (1997) Rock magnetism. Cambridge University Press, London, p 573
Ellwood BB, Crick RE, El Hassani A, Benoist SL, Young RH (2000) Magnetosusceptibility event and cyclostratigraphy (MSEC) in marine rocks and the question of detrital input versus carbonate productivity. Geology 28:1135–1138
Ellwood BB, Benoist SL, El Hassani A, Wheeler C, Crick RE (2003) Impact ejecta layer from the mid-Devonian: possible connection to global mass extinctions. Science 300:1734–1737
Ellwood BB, Benoist SL, El Hassani A, Feist R (2004) High resolution correlation using graphic correlation of biostratigraphic and magneto-stratigraphic or chemostratigraphic data sets: illustrating the method by defining the Middle Devonian magnetostratigraphic susceptibility for sections from France and Morocco. Abstr SDS 2004 Meet Rabat, Morocco:P8
Fan D, Zhang T, Ye J (2004) The Xikuangshan Sb deposit hosted by the Upper Devonian black shale series, Hunan, China. Ore Geol Rev 24:121–133
Finger F, Tichomirowa M, Pin C, Hanzl P (2000) Relics of an early-Panafrican metabasite-metarhyolite formation in the Brno Massif, Moravia, Czech Republic. Int J Earth Sci 89:328–335
France-Lanord C, Derry LA (1997) Organic carbon burial forcing of the carbon cycle from Himalayan erosion. Nature 390:65–67
Galle A, Friakova O, Hladil J, Kalvoda J, Krejci Z, Zukalova V (1988) Biostratigraphy of Middle and Upper Devonian carbonates of Moravia, Czechoslovakia. Can Soc Petrol Geol Mem 14:633–645
Galle A, Hladil J (1991) Lower Paleozoic corals of Bohemia and Moravia. In: 6th international symposium on Fossil Cnidaria and Porifera. Fossil Cnidaria, Munster, Guidebook B3, pp 1–83
Gersl M, Hladil J (2004a) Gamma-ray and magnetic susceptibility correlation across Frasnian carbonate platform and search for the “punctata” equivalents in stromatoporoid-coral limestone facies of Moravia. Geol Q 48:283–292
Gersl M, Hladil J (2004b) Weathering products trapped in pure platform limestones: geochemical picture of magnetic susceptibility and gamma-ray variations. Geochim Cosmochim Acta 68(Suppl 11):A446 post 4.5.P25
Gilmore G, Hemingway JD (1995) Practical gamma-ray spectrometry. Wiley, p 322
Goulard AT, de Jesus Filho MF, Fabris JD, Coey JMD (1994) Characterization of soil ilmenite developed from basalt. Hyperfine Interact 91:771–775
Harrison SP, Kohfeld KE, Roelandt C, Claquin T (2001) The role of dust in climate changes today, at the last glacial maximum and in the future. Earth-Sci Rev 54:43–80
Hladil J (1983) The biofacies section of Devonian limestones in the central part of the Moravian Karst. Sbor Geol Ved Geol Prague 38:71–94
Hladil J (1994) Microfacies of the Devonian limestones in Moravia, Part II, Overview of microfacies. Zem Plyn Nafta Gbely 39:19–70
Hladil J (2002) Geophysical records of dispersed weathering products on the Frasnian carbonate platform and early Famennian ramps in Moravia, Czech Republic: proxies for eustasy and palaeoclimate. Palaeogeogr Palaeoclimatol Palaeoecol 181:213–250
Hladil J (2003) Devonian and Carboniferous of the Moravian Karst. In: 9th international symposium on Fossil Cnidaria and Porifera. Graz-Brno, Field Trip Guidebook B2, p 15 http://home.gli.cas.cz/hladil/www/B2-Guidebook-MK.pdf
Hladil J, Hladikova J (2000) Isotopic compositions of carbon and oxygen in platform/reef carbonates of the Moravian Karst. In: Oschmann W, Steininger F, Fursich FT (eds) Biomarkers and stable isotopes in palaeontology. Eur Palaeont Assoc Workshop Frankfurt 2000:51–53
Hladil J, Patocka F, Kachlik V, Melichar R, Hubacik M. (2003a) Metamorphosed carbonates of Krkonose Mountains and Paleozoic evolution of Sudetic tarranes (NE Bohemia, Czech Republic). Geol Carpath 54:281–297
Hladil J, Bosak P, Slavik L, Carew JL, Mylroie JE, Gersl M (2003b) Early diagenetic origin and persistence of gamma-ray and magnetosusceptibility patterns in platform carbonates: comparison of Devonian and Quaternary sections. Phys Chem Earth 28:719–727
Hladil J, Gersl M, Hladikova J, Frana J (2004) Environmental disturbances in early Middle Frasnian (punctata Zone)—Alamo Comet was likely accompanied by other bolides. Acad Sci CR Inst Geol Ann Rep 2003:46–47
Hladil J, Pruner P, Venhodova D, Hladilova T, Man O (2002) Toward an exact age of Middle Devonian Celechovice corals—past problems in biostratigraphy and present solutions complemented by new magnetosusceptibility measurements. Coral Res Bull 7:65–71
Honjo S (1982) Seasonality of biogenic and lithogenic fluxes in the Panama Basin. Science 218: 883–884
Horita J, Zimmermann H, Holland HD (2002) Chemical evolution of seawater during the Phanerozoic: Implications from the record of marine evaporites. Geochim Cosmochim Acta 66:3733–3756
Kao SJ, Horng CS, Roberts AP, Liu KK (2004) Carbon-sulfur-iron relationships in sedimentary rocks from southwestern Taiwan: influence of geochemical environment on greigite and pyrrhotite formation. Chemical Geology 203:153–168
Krs M, Pruner P, Man O (2001) Tectonic and paleogeographic interpretation of the paleomagnetism of Variscan and pre-Variscan formations of the Bohemian Massif, with special reference to the Barrandian terrane. Tectonophysics 332:93–114
Leleyter L, Probst JL, Depetris P, Haida S, Mortatti J, Rouault R, Samuel J (1999) REE distribution pattern in river sediments: partitioning into residual and labile fractions. Compt Rend Acad Sci Ser IIA 329:45–52
Lennie AR, Redfern SAT, Champness PE, Stoddart CP, Schofield PF, Vaughan DJ (1997): Transformation of mackinawite to greigite: and in situ X-ray powder diffraction and transmission electron microscope study. Am Mineral 82:302–309
Liegeois JP, Latouche L, Boughrara M, Navez J, Guiraud M (2003) The LATEA metacraton (Central Hoggar, Tuareg shield, Algeria): behaviour of an old passive margin during the Pan-African orogeny. J Afr Earth Sci 37:161–190
Lo Monaco S, Lopez L, Rojas H, Garcia D, Premovic P, Briceno H (2002) Distribution of major and trace elements in La Luna Formation, Southwestern Venezuelan Basin. Organic Geochem 33:1593–1608
Luening S, Wendt J, Belka Z, Kaufmann B (2004) Temporal–spatial reconstruction of the early Frasnian (Late Devonian) anoxia in NW Africa: new field data from the Ahnet Basin (Algeria). Sedim Geol 163: 237–264
Mahowald N, Kohfeld K, Hansson M, Balkanski Y, Harrison SP, Prentice IC, Schulz M, Rodhe H (1999) Dust sources and deposition during the last glacial maximum and current climate: a comparison of model results with paleodata from ice cores and marine sediments. J Geophys Res 104:15895–15916
Mani RC, Sunkara MK (2003) Kinetic faceting of multiply twinned diamond crystals during vapor phase synthesis. Diam Rel Mater 12:324–329
Marx SK, Kamber BS, McGowan HA (2005) Provenance of long travelled dust determined with ultra trace element composition: a pilot study with samples from New Zealand glaciers. Earth Surf Processes Landforms, (in press)
McCulloch M, Fallon SR, Wyndham T, Hendy E, Lough J, Barnes D (2003) Coral record of increased sediment flux to the inner Great Barrier Reef since European settlement. Nature 421(6924):727–730
Michalopoulos P, Aller RC (2004) Early diagenesis of biogenic silica in the Amazon delta: Alteration, authigenic clay formation, and storage. Geochim Cosmochim Acta 68:1061–1085
Nozaki Y (2001) Rare earth elements and their isotopes. In: Steele JS, Turekian KK, Thorpe SA (eds) Encyclopedia of Ocean sciences. Academic, London, pp 2354–2366
Olsen H (1990) Astronomical forcing of meandering river behaviour: Milankovitch cycles in Devonian of East Greenland. Paleogeogr Paleoclimatol Paleoecol 79:99–115
Pawellek T, Aigner T (2003) Stratigraphic architecture and gamma ray logs of deeper ramp carbonates (Upper Jurassic, SW Germany). Sed Geol 159:203–240
Plank T, Langmuir CH (1998) The geochemical composition of subducting sediment and its consequences for the crust and mantle. Chem Geol 145:325–394
Prokoph A, Barthelmes F (1996) Detection of non-stationarities in geological time-series. Wavelet-analysis of chaotic and cyclic sequences. Comput Geosci 22:1097–1108
Purkynova E, Gilikova H, Jachowitz M, Filipiak P (2004) Paleobotanical records from basal Devonian clastics in Menin and Kozlovice boreholes, Moravia, Czech Republic. Cas Slez Muz Opava A 53:193–204
Racki G (1998) Frasnian-Famennian biotic crisis: undervalued tectonic control? Palaeogeogr Palaeoclimatol Palaeoecol 141:177–198
Racki G, Piechota A, Bond D, Wignall PB (2004) Geochemical and ecological aspects of lower Frasnian pyrite-goniatite level at Kostomloty (Holy Cross Mountains, Central Poland). Geol Quart 48:267–282
Richter C, Valet JP, Solheid PA (1997) Rock-magnetic properties of sediments from Ceara Rise (Site 929), and implications for the origin of their magnetic susceptibility. In: Shackleton NJ, Curry WB, Richter C, Bralower TJ (eds) Proceedings of ODP, Scientific Results, vol 154, pp 169–179
Royer DL, Berner BA, Montanez IP, Tabor NJ, Beerling DJ (2004) CO2 as a primary driver of Phanerozoic climate. GSA Today 14(3):4–10
Ruffell A, Worden R (2000) Palaeoclimate analysis using spectral γ-ray data from the Aptian (Cretaceous) of southern England and southern France. Palaeogeogr Palaeoclimatol Palaeoecol 155:265–283
Sayles FL, Mangelsdorf PC (1977) The equilibrium of clay minerals with seawater: exchange reactions. Geochim Cosmochim Acta 41:951–960
Schindler E (1990) Die Kellwasser-Krise (hohe Frasne-Stufe, Ober-Devon). Gott Arb Geol Palaont 46:1–115
Schwarzacher W (2000) Repetitions and cycles in stratigraphy. Earth Sci Rev 50:51–75
Scotese CR (2005) Paleomap project, climate history. http://www.scotese.com/paleocli.htm
Sholkovitz ER, Price NB (1980) The major-element chemistry of suspended matter in the Amazon Estuary. Geochim Cosmochim Acta 44:163–171
Slavik L, Hladil J, Blazek R, Kruta T (2000) Anatomy of the Pragian stratigraphic column; gamma-ray spectrometric record throughout a complete 170-m thick Pragian section in calciturbidite/hemipelagite facies. Subcomm Devon Stratigr Newsl 17:46–47
Smalley IJ, Kumar R, O’Hara Dhand K, Jefferson IF (2004) The formation of quartz silt for terrestrial sediments: particularly loess deposits. Int. Workshop Particle Size Sed. Dynamics. Hanse-Wissenschaftskol Delmenhorst 2004:129–130
Streel M, Caputo MV, Loboziak S, Melo JHG (2000) Late Frasnian-Famennian climates based on palynomorph analyses and the question of the Late Devonian glaciations. Earth Sci Rev 52:121–173
Tegen I, Fung I (1995) Contribution to the atmospheric mineral aerosol load from land surface modification. J Geophys Res 100:18707–18726
Tribovillard N, Averbuch O, Devleeschouwer X, Racki G, Riboulleau A (2004) Deep-water anoxia over the Frasnian–Famennian boundary (La Serre, France): a tectonically induced oceanic anoxic event? Terra Nova 16:288–295
Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am Bull 72:175–192
Ures M, LeMenn J, Hladil J (1999) Middle Devonian crinoid columnals from Celechovice in Moravia, Czech Republic. Bull Geosci Czech Geol Surv 74:323–333
Vavrdova M, Mikulas R, Nehyba S (2003) Lower Cambrian siliciclastic sediments in Southern Moravia (Czech Republic) and their paleogeographical constraints. Geol Carpath 52:67–79
Walliser OH, Lottmann J, Schindler E (1988) Global events in the Devonian of Kellerwald and Harz Mountains. Cour Forsch-Inst Senckenberg 102:190–193
Wehausen R, Brumsack HJ (1999) Cyclic variations in the chemical composition of eastern Mediterranean Pliocene sediments: a key for understanding sapropel formation. Mar Geol 153:161–176
Wehausen R, Tian J, Brumsack HJ, Cheng X, Wang P (2003) Geochemistry of Pliocene sediments from ODP Site 1143 (southern South China Sea). In: Prell WL, Wang P, Blum P, Rea DK, Clemens SC (eds). Proceedings of ODP, scientific results vol 184, pp 1–25
Westphal H, Boehm F (2004) Orbital frequencies in the carbonate sedimentary record: distorted by diagenesis? Facies 50:3–11
Williams CA, Krause FF (1998) Pedogenic-phreatic carbonates on a Middle Devonian (Givetian) terrigenous alluvial-deltaic plain, Gilwood Member (Watt Mountain Formation), northcentral Alberta, Canada. Sedimentology 45:1105–1124
Woodrow DL (1985) Paleogeography, paleoclimate, and sedimentary processes of the Late Devonian Catskill Delta. Geol Soc Amer Spec Pap 201:51–63
Zukalova V (1971) Stromatoporoidea from the Middle and Upper Devonian of the Moravian Karst. Rozpr Ustr Ust Geol Prague 37:3–143
Zukalova V, Chlupac I (1982) Stratigraphic classification of non-metamorphosed Devonian of the Moravian-Silesian area. Cas Mineral Geol 27:225–241
Acknowledgments
Project: AVOZ30130516 “Earth Systems”. Consulting and support: X-ray diffractometry—K. Melka (Inst. Geol. ASCR); PIXE probing—J. Voltr (Phys. Electronics, Czech Tech. Univ.); magnetism—M. Krs, P. Pruner and M. Chadima (Paleomag. Lab. Pruhonice), B.B. Ellwood (Dept. Geol. Geophys., Louisiana State Univ.), F. Hrouda (Agico Ltd.); gamma-ray—I. Kasparec (Exploranium CZ). Particular indebtedness is due to helpful comments and corrections by journal referees.
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Hladil, J., Gersl, M., Strnad, L. et al. Stratigraphic variation of complex impurities in platform limestones and possible significance of atmospheric dust: a study with emphasis on gamma-ray spectrometry and magnetic susceptibility outcrop logging (Eifelian-Frasnian, Moravia, Czech Republic). Int J Earth Sci (Geol Rundsch) 95, 703–723 (2006). https://doi.org/10.1007/s00531-005-0052-8
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DOI: https://doi.org/10.1007/s00531-005-0052-8