Abstract
We describe an experimental method to measure the cluster deformation of metal clusters deposited on a substrate. It is based upon the sensitivity of the cluster plasmon resonance on the geometric shape of the clusters; it uses optical spectroscopy with polarized light in oblique incidence. The proposed method was applied to silver clusters (mean diameter 2R = 2nm) produced in a supersonic beam and deposited on a quartz glass substrate. Cluster deposition and optical measurements were performed in situ in vacuum. At an estimated particle velocity of 1.5 · 103 ms -1, we evaluated an axial ratio of c/a = 0.86 for the deposition induced deformation. This result is compared to data from molecular dynamical simulations. By varying the substrate coverage, the critical cluster coverage for the onset of electromagnetic cluster-cluster coupling and coalescence was determined to amount to 0.1 cluster-monolayers.
Similar content being viewed by others
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hövel, H., Hilger, A., Nusch, I. et al. Experimental determination of deposition induced cluster deformation. Z Phys D - Atoms, Molecules and Clusters 42, 203–208 (1997). https://doi.org/10.1007/s004600050355
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s004600050355