Parental melts of melilitolite and origin of alkaline carbonatite: evidence from crystallised melt inclusions, Gardiner complex

Abstract

Perovskite and melilite crystals from melilitolites of the ultramafic alkaline Gardiner complex (East Greenland) contain crystallised melt inclusions derived from: (1) melilitite; (2) low-alkali carbonatite; (3) natrocarbonatite. The melilitite inclusion (1) homogenisation temperature of 1060 °C is similar to liquidus temperatures of experimentally investigated natural melilitites. The compositions are peralkaline, low in MgO (ca.␣5 wt%), Ni and Cr, and they are low-pressure fractionates of more magnesian larnite-normative ultramafic lamprophyre-type melts of primary mantle origin. Low-alkali carbonatite compositions (2) homogenise at 1060–1030 °C and are compositionally similar to immiscible calcite carbonatite dykes derived from the melilitolite magma. Natrocarbonatite inclusions (3) homogenise between 1030 and 900 °C and are compositionally similar to natrocarbonatite lava from Oldoinyo Lengai. Nephelinitic to phonolitic dykes which are related to the calcite carbonatite dykes, are very Zr-rich and agpaitic (molecular Na₂O + K₂O/Al₂O₃ > 1.2) and resemble nephelinites of Oldoinyo Lengai. The petrographic, geochemical and temporal relationships indicate unmixing of carbonatite compositions (ca. 10% alkalies) from evolving melilitite melt and continued fractionation of melilitite to nephelinite. It is suggested that the natrocarbonatite compositions represent degassed supercritical high temperature fluid formed in a cooling body of strongly larnite-normative nephelinite or evolved melilitite. The Gardiner complex and similar melilitolite and carbonatite-bearing ultramafic alkaline complexes are believed to represent subvolcanic complexes formed beneath volcanoes comparable to Oldoinyo Lengai and that the suggested origin of natrocarbonatite may be applied to natrocarbonatites of Oldoinyo Lengai.