Abstract
We have studied the chemical zoning of plagioclase phenocrysts from the slow-spreading Mid-Atlantic Ridge and the intermediate-spreading rate Costa Rica Rift to obtain the time scales of magmatic processes beneath these ridges. The anorthite content, Mg, and Sr in plagioclase phenocrysts from the Mid-Atlantic Ridge can be interpreted as recording initial crystallisation from a primitive magma (~11 wt% MgO) in an open system. This was followed by crystal accumulation in a mush zone and later entrainment of crystals into the erupted magma. The initial magma crystallised plagioclase more anorthitic than those in equilibrium with any erupted basalt. Evidence that the crystals accumulated in a mush zone comes from both: (1) plagioclase rims that were in equilibrium with a Sr-poor melt requiring extreme differentiation; and (2) different crystals found in the same thin section having different histories. Diffusion modelling shows that crystal residence times in the mush were <140 years, whereas the interval between mush disaggregation and eruption was ≤1.5 years. Zoning of anorthite content and Mg in plagioclase phenocrysts from the Costa Rica Rift show that they partially or completely equilibrated with a MgO-rich melt (>11 wt%). Partial equilibration in some crystals can be modelled as starting <1 year prior to eruption but for others longer times are required for complete equilibration. This variety of times is most readily explained if the mixing occurred in a mush zone. None of the plagioclase phenocrysts from the Costa Rica Rift that we studied have Mg contents in equilibrium with their host basalt even at their rims, requiring mixing into a much more evolved magma within days of eruption. In combination these observations suggest that at both intermediate- and slow-spreading ridges: (1) the chemical environment to which crystals are exposed changes on annual to decadal time scales; (2) plagioclase crystals record the existence of melts unlike those erupted; and (3) disaggregation of crystal mush zones appears to precede eruption, providing an efficient mechanism by which evolved interstitial melt can be mixed into erupted basalts.
Similar content being viewed by others
References
Albarede F, Bottinga Y (1972) Kinetic disequilibrium in trace element partitioning between phenocryst and host lava. Geochim Cosmochim Acta 35:141–256
Alt JC, Kinoshita H, Stokking LB et al (1993) Proceedings of ODP, initial reports, vol 148. College Station, TX (Ocean Drilling Program)
Bindeman IN, Davis AM, Drake MJ (1998) Ion microprobe study of plagioclase-basalt partition experiments at natural concentration levels of trace elements. Geochim Cosmochim Acta 62:1175–1193
Blundy JD, Wood BJ (1991) Crystal-chemical controls on the partitioning of Sr and Ba between plagioclase feldspar, silicate melts, and hydrothermal solutions. Geochim Cosmochim Acta 55:193–209
Brewer TS, Bach W, Furnes H (1996) Geochemistry of lavas from Hole 896A. In: Alt JC, Kinoshita H, Stokking LB, Michael PJ (eds) Proceedings ocean drilling program scientific results, vol 148, pp 9–17
Cashman K (1990) Textural constraints on the kinetics of crystallization of igneous rocks. Rev Mineral 24:259–314
Cashman K (1993) Relationship between plagioclase crystallization and cooling rate in basaltic melts. Contrib Mineral Petrol 113:126–142
Cherniak DJ, Watson EB (1994) A study of strontium diffusion in plagioclase using Rutherford backscattering spectroscopy. Geochim Cosmochim Acta 58:5179–5190
Coogan LA, Saunders AD, Kempton PD, Norry MJ (2000) Evidence from oceanic gabbros for porous melt migration within a crystal mush beneath the Mid-Atlantic Ridge. Geophys Geochem Geosys 1: Paper No 2000GC000072
Costa F, Chakraborty S, Dohmen R (2003) Diffusion coupling between major and trace elements and a model for the calculation of magma chamber residence times using plagioclase. Geochim Cosmochim Acta 67:2189–2200
Costa F, Dohmen R, Chakraborty S (2008) Time scales of magmatic processes from modeling the zoning patterns of crystals. Rev Mineral Geochem 69:545–594
Crank J (1975) The mathematics of diffusion. Oxford Science Publications
Danyushevsky LV, Sokolov S, Falloon TJ (2002) Melt inclusions in olivine phenocrysts: using diffusive re-equilibration to determine the cooling history of a crystal, with implications for the origin of olivine-phyric volcanic rocks. J Petrol 43:1651–1671
Dick HJ, Meyer SH, Bloomer S, Kirby D, Stakes, Mawer C (1991) Lithostratigraphic evolution of an in situ section of oceanic layer 3. In: Von Herzen PR et al (ed) Proceedings of the ocean drilling program Leg 118, Scientific Results. U.S. Government Printing Office, Washington, pp 439–540
Dohmen R, Chakraborty S (2007) Fe–Mg diffusion in olivine II: point defect chemistry, change of diffusion mechanisms and a model for calculation of diffusion coefficients in natural olivine. Phys Chem Min 34:409–430
Donaldson CH, Brown RW (1977) Refractory megacrysts and magnesium-rich melt inclusions within spinel in oceanic tholeiites: indicators of magma mixing and parental magma composition. Earth Planet Sci Lett 37:81–89
Dungan MA, Rhodes JM (1978) Residual glasses and melt inclusions in basalts from DSDP Leg 45 and 46: evidence for magma mixing. Contrib Mineral Petrol 67:417–431
Dungan M, Long PE, Rhodes JM (1978) The petrography, mineral chemistry, and one-atmosphere phase relations of basalts from Site 395. In: Melson WG, Rabinowitz PD et al (eds) Initial reports of the deep sea drilling project. US Government Printing Office, Washington, pp 461–477
Fisk M, McNeill AW, Teagle DAH, Furnes H, Bach W (1996) Data report: major-element chemistry of Hole 896A glass. In: Alt JC, Kinoshita H, Stokking LB, Michael PJ (eds) Proceedings of ocean drilling program scientific results, vol 148, pp 483–487
Flower MJF, Robinson PT, Schmicnke H-U, Ohnmacht W (1977) Petrology and geochemistry of igneous rocks, DSDP Leg 37. DSDP Init Rep 37:653–679
Ghiorso MS, Sack RO (1995) Chemical mass transfer in magmatic processes. IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid–solid equilibria in magmatic systems at elevated temperatures and pressures. Contrib Mineral Petrol 119:197–212
Giletti BJ, Casserly JED (1994) Strontium diffusion kinetics in plagioclase feldspars. Geochim Cosmochim Acta 58:3785–3797
Goldstein SJ, Perfit MR, Batiza R, Fornari DJ, Murrell MT (1994) 226Ra and 231Pa systematics of axial morb, crustal residence ages, and magma chamber characteristics at 9–10°N East Pacific Rise. Min Mag 58:335–336
Grove TL, Baker MB, Kinzler RJ (1984) Coupled CaAl–NaSi diffusion in plagioclase feldspar: experiments and applications to cooling rate speedometry. Geochim Cosmochim Acta 48:2113–2121
Grove TL, Kinzler RJ, Bryan WB (1990) Natural and experimental phase relations of lavas from Serocki volcano. In: Detrick R, Honnorez J, Bryan WB, Juteau T et al (eds) Proceedings of ocean drilling program scientific results, vol 106/109, pp 9–17
Grove TL, Kinzler RJ, Bryan WB (1992) Fractionation of Mid-Ocean Ridge Basalt (MORB), In: Morgan JP, Blackman DK, Sinton JM (eds) Mantle flow and melt generation at Mid-Ocean Ridges. AGU Geophysical Monograph, vol 71, pp 281–310
Hammer J (2008) Experimental studies of the kinetics and energetics of magma crystallization. Rev Min Geochem 69:9–59
Horn I, Hinton RW, Jackson SE, Longerich HP (1997) Ultra-trace element analysis of NIST SRM 616 and 614 using laser ablation microprobe inductively coupled plasma mass spectrometry (LAM-ICP-MS): a comparison with secondary ion mass spectrometry (SIMS). Geostand Newsl 21(2):191–203
Humler E, Whitechurch H (1988) Petrology of basalts from the Central Indian Ridge (lat. 25 23′S, long. 70 04′E): estimates of frequencies and fractional volumes of magma injections in a two layered reservoir. Earth Planet Sci Lett 88:169–181
Klein EM, Langmuir CH (1987) Global correlation of ocean ridge basalt chemistry with axial depth and crustal thickness. J Geophys Res 92:8089–8115
Kuo L-C, Kirkpatrick RJ (1982) Pre-eruption history of phyric basalts from DSDP Legs 45 and 46: evidence from morphology and zoning patterns in plagioclase. Contrib Mineral Petrol 79:13–27
Langmuir CH (1989) Geochemical consequences of in situ differentiation. Nature 340:199–205
Langmuir CH, Klein EM, Plank T (1992) Petrological systematics of Mid-Ocean ridge basalts: constraints on melt generation beneath ocean ridges. In: Morgan JP, Blackman DK, Sinton JM (eds) Mantle flow and melt generation at Mid-Ocean Ridges. AGU Geophysical Monograph, vol 71, pp 183–280
LaTourrette T, Wasserburg GJ (1998) Mg diffusion in anorthite: implications for the formation of early solar system planetesimals. Earth Planet Sci Lett 158:91–108
Lesher CE (1994) Kinetics of Sr and Nd exchange in silicate liquids: theory, experiments, and applications to uphill diffusion, isotopic equilibration, and irreversible mixing of magmas. J Geophys Res 99:9585–9604
McNeill AW, Danyushevsky LV (1996) Composition and crystallization temperatures of primary melts from hole 896A basalts: evidence from melt inclusion studies. In: Alt JC, Kinoshita H, Stokking LB, Michael PJ (eds) Proceedings of ocean drilling program scientific results, vol 148, pp 21–35
Meyer PS, Shibata T (1990) Complex zoning in plagioclase feldspars from ODP site 648. In: Detrick R, Honnorez J, Bryan WB, Juteau T et al (eds) Proceedings of ocean drilling program scientific results, vol 106/109, pp 123–142
Nabeleck PI, Langmuir CH (1986) The significance of unusual zoning in olivines from FAMOUS area basalt 527-1-1. Contrib Mineral Petrol 93:1–8
Pan Y, Batiza R (2002) Mid-ocean ridge magma chamber processes: constraints from olivine zonation in lavas from the East Pacific Rise at 9°30′N and 10°30′N. J Geophys Res 107. doi10.1029/2001JB000435
Pearce NJG, Perkins WT, Westgate JA, Gorton MP, Jackson SE, Neal CR, Chenery SP (1997) A compilation of new and published major and trace element data for NIST SRM 610 and NIST SRM 612 glass reference materials. Geostand Newsl 21:115–144
Perk N, Coogan LA, Karson JA, Klein EM, Hanna H (2007) Primitive cumulates from the upper crust formed at the East Pacific Rise. Contrib Mineral Petrol 154:575–590
Presnall DC, Hoover JD (1987) High pressure phase equilibrium constraints on the origin of mid-ocean ridge basalts. Geochem Soc (Spec paper no. 1):75–89
Qin Z, Lu F, Anderson AT (1992) Diffusive reequilibration of melt and fluid inclusions. Am Min 77:565–576
Ridley WI, Perfit M, Smith MC, Fornari DJ (2006) Magmatic processes in developing oceanic crust revealed in a cumulate xenoliths collected at the East Pacific Rise, 9°50′N. Geochem Geophys Geosys 7. doi:10.1029/2006GC001316
Rubin KH, van der Zandler I, Smith MC, Bergmanis EC (2005) Minimum speed limit for ocean ridge magmatism from 210Pb–226Ra–230Th disequilibria. Nature 437:534–538
Saal AE, Van Orman JA (2004) The 226Ra enrichment in oceanic basalts: evidence for melt-cumulate diffusive interaction processes within the oceanic lithosphere. Geochem Geophys Geosys 5. doi:10.1029/2003GC000620
Sato H, Aoki K-I, Okamoto K, Fujita B-Y (1979) Petrology and chemistry of Basaltic rocks from Hole 396B, IPOD/DSDP Leg 46. DSDP Init Rep 46:115–141
Shipboard Scientific Party (1988) Site 648. In: Detrick R, Honnorez J, Bryan WB, Juteau T et al (eds). Proceedings of ODP, initial reports, vol 106/109. College Station, TX (Ocean Drilling Program)
Sinton JM, Detrick RS (1992) Mid-Ocean Ridge magma chambers. J Geophys Res 97:197–216
Sinton CW, Christie DM, Coombs VL, Nielsen RL, Fisk MR (1993) Near-primary melt inclusions in anorthite phenocrysts from the Galapagos Platform. Earth Planet Sci Lett 119:527–537
Smith VG, Tiller WA, Rutter JW (1955) A mathematical analysis of solute redistribution during solidification. Can J Phys 33:723–745
Van Orman JA, Saal AE (2007) Reconciling Pb-210 deficits with the physics of melt extraction. Geochim Cosmochim Acta 71:A1058
Van Orman JA, Saal AE, Bourdon B, Hauri EH (2006) Diffusive fractionation of U-series radionuclides during mantle melting and shallow level melt-cumulate interaction. Geochim Cosmochim Acta 70:4797–4812
Acknowledgments
Reviews by J. Sinton and P. Wallace are greatly appreciated and helped to clarify various parts of the manuscript. FC acknowledges contracts under project 526 of the German Science Foundation and a Ramon y Cajal Fellowship Spanish Ministry of Education. The ocean drilling program is acknowledged for providing access to the samples studied here. NSERC funded the LA-ICP-MS analyses at the University of Victoria.
Author information
Authors and Affiliations
Corresponding author
Additional information
Communicated by T.L. Grove.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Costa, F., Coogan, L.A. & Chakraborty, S. The time scales of magma mixing and mingling involving primitive melts and melt–mush interaction at mid-ocean ridges. Contrib Mineral Petrol 159, 371–387 (2010). https://doi.org/10.1007/s00410-009-0432-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00410-009-0432-3