Abstract
The anorthite content of plagioclase grains (XAn) in 12 rocks from the layered series of the Skaergaard intrusion has been studied by electron microprobe (typically ∼30 core and ∼70 rim analyses per thin section). Mean core compositions vary continuously from An66 at the base of the layered series (LZa) to An32–30 at the top. On the other hand, crystal rims are of approximately constant composition (An50 ± 1) from the LZa to the lower Middle Zone (MZ). Above the MZ, core and rim compositions generally overlap. Profiles across individual plagioclase grains from the lower zone show that most crystals have an external zone buffered at XAn ∼50 ± 1. The simplest explanation for these features is that during postcumulus crystallization in the lower zone, interstitial liquids passed through a density maximum. This interpretation is consistent with proposed liquid lines of descent that predict silica enrichment of the liquid associated with the appearance of cumulus magnetite.
Similar content being viewed by others
References
Andersen JCØ, Rasmussen H, Nielsen TFD, Røngsbo JG (1998) The Triple Group and the Platinova gold and palladium reefs in the Skaergaard intrusion: stratigraphic and petrographic relations. Econ Geol 93:488–509
Brooks CK, Nielsen TFD (1990) The differentiation of the Skaergaard intrusion. A discussion of Hunter and Sparks (Contrib Mineral Petrol 95: 451–461). Contrib Mineral Petrol 104:244–247
Gibb FGF, Henderson CMB (1996) The Shiant Isles Main Sill: structure and mineral fractionation ranges. Mineral Mag 60:67–97
Grant NK, Chalokwu CI (1998) The cumulate paradigm affirmed. J Geol 106:641–644
Henderson P (1970) The significance of the mesostasis of basic layered igneous rocks. J Petrol 11:463–473
Henderson CMB, Gibb FGF (1983) Felsic mineral crystallization trends in differentiating alkaline basic magmas. Contrib Mineral Petrol 84:355–364
Holness MB (2006) Melt-solid dihedral angles of common minerals in natural rocks. J Petrol 47:791–800
Hoover JD (1989) Petrology of the Marginal Border Series of the Skaergaard intrusion. J Petrol 30:399–439
Hunter RH (1996) Texture development in cumulate rocks. In: Cawthorn RG (ed) Layered intrusions. Elsevier, Amsterdam, pp 77–101
Hunter RH, Sparks RSJ (1987) The differentiation of the Skaergaard intrusion. Contrib Mineral Petrol 95:451–461
Hunter RH, Sparks RSJ (1990) The differentiation of the Skaergaard intrusion. Reply to McBirney and Naslund. Contrib Mineral Petrol 104:248–254
Irvine TN, Andersen JCØ, Brooks CK (1998) Included blocks (and blocks within blocks) in the Skaergaard intrusion: geologic relations and the origins of rhythmic modally graded layers. Geol Soc Am Bull 110:1398–1447
Jang YD, Naslund HR (2001) Major and trace element composition of Skaergaard plagioclase; geochemical evidence for changes in magma dynamics during the final stage of crystallization of the Skaergaard intrusion. Contrib Mineral Petrol 140:441–457
Jang YD, Naslund HR, McBirney AR (2001) The differentiation trend of the Skaergaard intrusion and the timing of magnetite crystallization: iron enrichment revisited. Earth Planet Sci Lett 189:189–196
Jerram DA, Cheadle MJ, Philpotts AR (2003) Quantifying the building blocks of igneous rocks: are clustered crystal frameworks the foundation? J Petrol 44:2033–2051
Lange RL, Carmichael ISE (1990) Thermodynamic properties of silicate liquids with emphasis on density, thermal expansion and compressibility. In: Nicholls J, Russell JK (eds) Modern methods of igneous petrology: understanding magmatic processes. Reviews in Mineralogy, vol 24, Chap 2, pp 25–64
Maaløe S (1976) Zoned plagioclase of the Skaergaard intrusion, East Greenland. J Petrol 17:398–419
McBirney AR (1989) The Skaergaard Layered Series: I. Structure and average compositions. J Petrol 30:363–397
McBirney AR (1996a) The Skaergaard intrusion. In: Cawthorn RG (ed) Layered intrusions. Elsevier, Amsterdam, pp 147–180
McBirney AR (1996b) Geological map of the Skaergaard intrusion, East Greenland, 1: 20,000. Department of Geology, University of Oregon, USA
McBirney AR, Hunter RH (1995) The cumulate paradigm reconsidered. J Geol 103:114–122
McBirney AR, Naslund HR (1990) The differentiation of the Skaergaard intrusion. A discussion of Hunter and Sparks (Contrib Mineral Petrol 95:451–461). Contrib Mineral Petrol 104:235–240
McBirney AR, Noyes RM (1979) Crystallization and layering of the Skaergaard intrusion. J Petrol 20:487–544
McBirney AR, Sonnenthal EL (1990) Metasomatic replacement in the Skaergaard intrusion, East Greenland: preliminary observations. Chem Geol 88:245–260
Meurer WP, Boudreau AE (1998) Compaction of igneous cumulates Part I: geochemical consequences for cumulates and liquid fractionation trends. J Geol 106:281–292
Meurer WP, Meurer MES (2006) Using apatite to dispel the “trapped liquid” concept and to understand the loss of interstitial liquid by compaction in mafic cumulates: an example from the Stillwater Complex, Montana. Contrib Mineral Petrol 151:187–201
Morse SA (1969) The Kiglapait layered intrusion, Labrador. Mem Geol Soc Am 112
Morse SA (1984) Cation diffusion in plagioclase feldspar. Science 225:504–505
Morse SA (1986) Convection in aid of adcumulus growth. J Petrol 27:1183–1214
Morse SA (1990) The differentiation of the Skaergaard intrusion. A discussion of Hunter and Sparks (Contrib Mineral Petrol 95:451–461). Contrib Mineral Petrol 104:240–244
Morse SA (1998) Is the cumulate paradigm at risk? An extended discussion of the cumulate paradigm reconsidered. J Geol 106:367–370
Naslund HR (1984) Petrology of the Upper Border Series of the Skaergaard intrusion. J Petrol 25:185–212
Nielsen TFD (2004) The shape and volume of the Skaergaard intrusion, East Greenland: imlpications for mass balance and bulk composition. J Petrol 45:507–530
Paster TP, Schauwecker DS, Haskin LA (1974) The behavior of some trace elements during solidification of the Skaergaard layered series. Geochim Cosmochim Acta 38:1459–1477
Philpotts AR, Brustman CM, Shi JY, Carlson WD, Denison C (1999) Plagioclase-chain networks in slowly cooled basaltic magma. Am Mineral 84:1819–1829
Shimizu N (1978) Analysis of the zoned plagioclase of different magmatic environments: a preliminary ion-microprobe study. Earth Planet Sci Lett 39:398–406
Smith JV, Brown WL (1988) Feldspar minerals. Springer, Berlin, p 828
Stewart BW, DePaolo DJ (1990) Isotopic studies of processes in mafic magma chambers: 2. The Skaergaard intrusion, East Greenland. Contrib Mineral Petrol 104:125–141
Tait SR, Jaupart C (1996) The production of chemically stratified and adcumulate plutonic igneous rocks. Miner Mag 60:99–114
Tait SR, Huppert HE, Sparks RSJ (1984) The role of compositional convection in the formation of adcumulate rocks. Lithos 17:139–146
Tegner C (1997) Iron in plagioclase as a monitor of the differentiation of the Skaergaard intrusion. Contrib Mineral Petrol 128:45–51
Toplis MJ, Carroll MR (1995) An experimental study of the influence of oxygen fugacity on Fe–Ti oxide stability, phase relations, and mineral-melt equilibria in ferro-basaltic systems. J Petrol 36:1137–1170
Toplis MJ, Carroll MR (1996) Differentiation of ferro-basaltic magmas under conditions open and closed to oxygen: implications for the Skaergaard Intrusion and other natural systems. J Petrol 37:837–858
Wager LR (1960) The major element variation of the layered series in the Skaergaard intrusion and a re-estimation of the average composition of the hidden layered series and of the successive residual magmas. J Petrol 1:364–398
Wager LR (1963) The mechanism of adcumulus growth in the layered series of the Skaergaard intrusion. Mineral Soc Am Spec Pap 1:1–9
Wager LR, Deer WA (1939) Geological investigations in East Greenland, Part III. The petrology of the Skaergaard intrusion, Kangerdlugssuaq, East Greenland. Meddr Grønland, vol 105, p 352
Wager LR, Brown GM (1968) Layered igneous rocks. Oliver and Boyd, Edinburgh, p 588
Wager LR, Brown GM, Wadsworth WJ (1960) Types of igneous cumulates. J Petrol 1:73–85
Acknowledgments
We are particularly indebted to our friends and colleagues who generously donated rock samples, before our memorable visit to the intrusion in 2001. Those people include Graham Chinner (University of Cambridge), Alex McBirney (University of Oregon), Ian Parsons, Brian Upton and Peder Aspen (University of Edinburgh) and Kevin Walsh (University of Oxford Museum). Thanks also to S. Barda, F. Diot and A. Kohler of the Service Commun d’analyse of the Université Henri Poincaré in Nancy for help with the electron microprobe and SEM. S.A. Morse and an anonymous reviewer are thanked for their comments which were greatly appreciated. Financial support from the CNRS-INSU (“Intérieur de la Terre” and “Dyeti” programmes) is also acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Communicated by T.L. Grove.
Rights and permissions
About this article
Cite this article
Toplis, M.J., Brown, W.L. & Pupier, E. Plagioclase in the Skaergaard intrusion. Part 1: Core and rim compositions in the layered series. Contrib Mineral Petrol 155, 329–340 (2008). https://doi.org/10.1007/s00410-007-0245-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00410-007-0245-1