Skip to main content
Log in

Dating high-grade metamorphism—constraints from rare-earth elements in zircon and garnet

  • Original Paper
  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

We integrate petrography and SIMS REE analyses of garnet and polyphase zircon from a pelitic granulite adjacent to the Ronda peridotite, Betic Cordillera, southern Spain to constrain the significance of zircon U–Pb geochronology. Sillimanite inclusions in garnet rims suggest that they grew during decompression, and Ca enrichment in their rims records initiation of partial melting. Chondrite-normalised REE profiles of zircon cores are typically magmatic (positive La to Lu slope and Ce anomaly), whereas overgrowths have flat or negatively sloping heavy-REE profiles (Gd–Lu). The presence of rimmed zircon grains only in the garnet rims and the matrix suggests that this zircon phase grew after garnet had already sequestered heavy REEs, a process documented here by progressive depletion of heavy REE in the garnets from centre to rim. Combined with the textural evidence, we suggest that the U–Pb age of 21.3±0.3 Ma obtained from the zircon rims dates a point on this decompression path rather than the peak metamorphic pressure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4a, b.
Fig. 5.
Fig. 6a, b.
Fig. 7.
Fig. 8a, b.
Fig. 9a–c.
Fig. 10.

Similar content being viewed by others

References

  • Anders E, Grevesse N (1989) Abundances of the elements: meteoritic and solar. Geochim Cosmochim Acta 53:197–214

    CAS  Google Scholar 

  • Argles TW, Platt JP, Waters DJ (1999) Attenuation and excision of a crustal section during extensional exhumation: the Carratraca Massif, Betic Cordillera, Southern Spain. J Geol Soc Lond 156:149–162

    CAS  Google Scholar 

  • Balanyá JC, Azañon JM, Sánchez-Gómez M, García-Dueñas V (1993) Pervasive ductile extension, isothermal decompression, and thinning of the Jubrique unit in the Palaeogene (Alpujarride Complex, western Betics Spain). CR Acad Sci Paris 316:1595–1601

    Google Scholar 

  • Barbey P, Allé P, Brouand M, Albarède F (1995) Rare-earth patterns in zircons from the Manaslu granite and Tibetan Slab migmatites (Himalaya): insights in the origin and evolution of a crustally-derived granite magma. Chem Geol 125:1–17

    CAS  Google Scholar 

  • Bau M (1996) Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems; evidence from Y/ Ho, Zr/ Hf, and lanthanide tetrad effect. Contrib Mineral Petrol 123:323–333

    Article  CAS  Google Scholar 

  • Bea F, Montero P (1999) Behavior of accessory phases and redistribution of Zr, REE, Y, Th, and U during metamorphism and partial melting of metapelites in the lower crust: an example from the Kinzigite Formation of Ivrea-Verbano, NW Italy. Geochim Cosmochim Acta 63:1133–1153

    Article  CAS  Google Scholar 

  • Bea F, Montero P, Garuti G, Zacharini F (1997) Pressure-dependence of rare earth element distribution in amphibolite- and granulite-grade garnets. A LA-ICP-MS study. Geostand Newslett 21:253–270

    CAS  Google Scholar 

  • Bingen B, Austhreim H, Whitehouse M (2001) Ilmenite as a source for zirconium during high-grade metamorphism? textural evidence from the Caledonides of W. Norway and implications for zircon geochronology. J Petrol 42:355–375

    Article  CAS  Google Scholar 

  • Bouybaouène M, Michard A, Goffé B (1998) High-pressure granulites on top of the Beni Bousera peridotites, Rif belt, Morocco: a record of an ancient thickened crust in the Alboran domain. Bull Soc Géol Fr 169:153–162

    Google Scholar 

  • Fraser G, Ellis D, Eggins S (1997) Zirconium abundance in granulite-facies minerals, with implications for zircon geochronology in high-grade rocks. Geology 25:607–610

    CAS  Google Scholar 

  • Garbe-Schönberg CD, Arpe T (1997) High resolution-ICPMS in fast scanning mode: application for laser ablation analysis of zircon. Fresenius J Anal Chem 359:462–464

    Article  Google Scholar 

  • Hinton RW (1990) Ion microprobe trace-element analysis of silicates: measurement of multi-element glasses. Chem Geol 83:11–25

    CAS  Google Scholar 

  • Hinton RW, Upton BGJ (1991) The chemistry of zircon; variations within and between large crystals from syenite and alkali basalt xenoliths. Geochim Cosmochim Acta 55:3287–3302

    CAS  Google Scholar 

  • Hoskin PWO (1998) Minor and trace element analysis of natural zircon (ZrSiO4) by SIMS and laser ablation ICPMS: a consideration and comparison of two broadly competitive techniques. J Trace Microprobe Tech 16:301–326

    CAS  Google Scholar 

  • Kornprobst J (1969) Le massif ultrabasique des Beni Bouchera (Rif Interne, Maroc): étude des péridotites de haute température et de haute pression, et des pyroxénolites, grenat ou sans grenat, qui leur sont associées. Contrib Mineral Petrol 23:283–322

    CAS  Google Scholar 

  • Loomis TP (1972a) Contact metamorphism of pelitic rock by the Ronda ultramafic intrusion, southern Spain. Geol Soc Am Bull 83:2449–2474

    CAS  Google Scholar 

  • Loomis TP (1972b) Diapiric emplacement of the Ronda high-temperature ultramafic intrusion, southern Spain. Geol Soc Am Bull 83:2475–2496

    Google Scholar 

  • Monié P, Torres-Roldán R-L, García-Casco A (1994) Cooling and exhumation of the western Betic Cordilleras, 40Ar/ 39Ar thermochronological constraints on a collapsed terrane. Tectonophysics 238:353–379

    Google Scholar 

  • Montel JM, Kornprobst J, Vielzeuf D, Veschambre M (1995) Shielding effect of garnet for the U-Th-Pb system in monazite: an e-probe study at Beni Bousera (Morocco). Terra Abstr 8:348

    Google Scholar 

  • Nesbitt RW, Hirata T, Butler IB, Milton JA (1997) UV laser ablation ICP-MS; some applications in the earth sciences. Geostand Newslett 21:231–243

    CAS  Google Scholar 

  • Pearce NJG, Perkins WT, Westgate JA, Gorton MP, Jackson SE, Neal CR, Chenery SP (1996) A compilation of new and published major and trace element data for NIST SRM 610 and NIST SRM 612 glass reference materials. Geostand Newslett 21:115–144

    Google Scholar 

  • Platt JP, Vissers RLM (1989) Extensional collapse of thickened continental lithosphere: a working hypothesis for the Alboran Sea and the Gibraltar arc. Geology 17:540–543

    Article  Google Scholar 

  • Platt JP, Whitehouse MJ (1999) Early Miocene high-temperature metamorphism and rapid exhumation in the Betic Cordillera (Spain): evidence from U-Pb zircon ages. Earth Planet Sci Lett 171:591–605

    Article  CAS  Google Scholar 

  • Roberts MP, Finger F (1997) Do U-Pb zircon ages from granulites reflect peak metamorphic conditions? Geology 25:319–322

    CAS  Google Scholar 

  • Rubatto D (2002) Zircon trace element geochemistry: partitioning with garnet and the link between U-Pb ages and metamorphism. Chem Geol 184:123–138

    Article  CAS  Google Scholar 

  • Sánchez-Rodriguez L (1998) Pre-Alpine and alpine evolution of the Ronda ultramafic complex and its country-rocks (Betic chain, southern Spain): U-Pb SHRIMP zircon and fission-track dating. PhD Thesis, Swiss Federal Institute of Technology, Zürich

    Google Scholar 

  • Sánchez-Rodriguez L, Gebauer D (2000) Mesozoic formation of pyroxenites and gabbros in the Ronda area (southern Spain), followed by Early Miocene subduction metamorphism and emplacement into the middle crust: U-Pb sensitive high-resolution ion microprobe dating of zircon. Tectonophysics 316:19–44

    Article  Google Scholar 

  • Schaltegger U, Fanning CM, Guenther D, Maurin JC, Schulmann K, Gebauer D (1999) Growth, annealing and recrystallization of zircon and preservation of monazite in high-grade metamorphism; conventional and in-situ U-Pb isotope, cathodoluminescence and microchemical evidence. Contrib Mineral Petrol 134:186–201

    CAS  Google Scholar 

  • Schreiber HD, Lauer HV, Thanyasiri T (1980) The redox state of cerium in basaltic magmas: an experimental study of iron-cerium interactions in silicate melts. Geochim Cosmochim Acta 44:1599–1612

    CAS  Google Scholar 

  • Sosson M, Morillon AC, Bourgois J, Feraud G, Poupeau G, Saint-Marc P (1998) Late exhumation stages of the Alpujarride Complex (western Betic Cordilleras, Spain); new thermochronological and structural data on Los Reales and Ojen nappes. Tectonophysics 285:253–273

    Article  CAS  Google Scholar 

  • Spear FS, Kohn MJ (1996) Trace element zoning in garnet as a monitor of crustal melting. Geology 24:1099–1102

    Article  CAS  Google Scholar 

  • Stacey JS, Kramers JD (1975) Approximation of terrestrial lead isotope evolution by a two-stage model. Earth Planet Sci Lett 26:207–221

    CAS  Google Scholar 

  • Steiger RH, Jäger E (1977) Subcommission on geochronology; convention on the use of decay constants in geo- and cosmochronology. Earth Planet Sci Lett 36:359–362

    CAS  Google Scholar 

  • Torres-Roldán RL (1981) Plurifacial metamorphic evolution of the Sierra Bermeja peridotite aureole (Southern Spain). Estudios Geol 37:115–133

    Google Scholar 

  • Tubía JM, Navarro-Vila F, Cuevas J (1993) The Maláguide–Los Reales Nappe: an example of crustal thinning related to the emplacement of the Ronda peridotites (Betic Cordillera). Phys Earth Planet Interiors 78:343–354

    Article  Google Scholar 

  • Vavra G, Schmid R, Gebauer D (1999) Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea Zone (Southern Alps). Contrib Mineral Petrol 134:380–404

    Article  CAS  Google Scholar 

  • Vissers RLM, Platt JP, van der Wal D (1995) Late orogenic extension of the Betic Cordillera and the Alboran Domain: a lithospheric view. Tectonics 14:786–803

    Google Scholar 

  • Whitehouse MJ, Claesson S, Sunde T, Vestin J (1997) Ion-microprobe U–Pb zircon geochronology and correlation of Archaean gneisses from the Lewisian Complex of Gruinard Bay, north-west Scotland. Geochim Cosmochim Acta 61:4429–4438

    Article  CAS  Google Scholar 

  • Whitehouse MJ, Kamber B, Moorbath S (1999) Age significance of U-Th-Pb zircon data from early Archaean rocks of west Greenland—a reassessment based on combined ion-microprobe and imaging studies. Chem Geol 160:201–224

    Article  CAS  Google Scholar 

  • Wiedenbeck M, Allé P, Corfu F, Griffin WL, Meier M, Oberli F, von Quadt A, Roddick JC, Spiegel W (1995) Three natural zircon standards for U-Th-Pb, Lu-Hf, trace element and REE analysis. Geostand Newslett 19:1–23

    CAS  Google Scholar 

  • Zeck HP, Whitehouse MJ (1999) Hercynian, Pan-African, Proterozoic and Archean ion-microprobe zircon ages for a Betic-Rif core complex, Alpine Belt, W. Mediterranean—consequences for its P-T-t path. Contrib Mineral Petrol 134:134–149

    Article  CAS  Google Scholar 

  • Zeck HP, Monié P, Villa IM, Hansen BT (1992) Very high rates of cooling and uplift in the Alpine belt of the Betic Cordilleras, southern Spain. Geology 20:79–82

    Article  Google Scholar 

Download references

Acknowledgements

We thank John Hanchar and Nigel Kelly for thorough and constructive reviews. The Nordsim ion-microprobe facility in Stockholm is funded by the natural science funding agencies of Denmark, Finland, Norway and Sweden, and the Swedish Museum of Natural History. M.J.W. acknowledges the support of a senior research fellowship from Vetenskapsrådet, Sweden. Work by J.P.P. was funded by grant number GR3/13160 from the Natural Environmental Research Council of Great Britain. This is Nordsim laboratory contribution number 65.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Martin J. Whitehouse.

Additional information

Editorial responsibility: I. Parsons

Rights and permissions

Reprints and permissions

About this article

Cite this article

Whitehouse, M.J., Platt, J.P. Dating high-grade metamorphism—constraints from rare-earth elements in zircon and garnet. Contrib Mineral Petrol 145, 61–74 (2003). https://doi.org/10.1007/s00410-002-0432-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00410-002-0432-z

Keywords

Navigation