In-situ UV-laser ⁴⁰Ar/³⁹Ar geochronology of a micaceous mylonite : an example of defect-enhanced argon loss

Abstract.

Muscovite and biotite from a crustal-scale mylonite zone (Pogallo Shear Zone, southern Alps) were investigated using furnace step-heating and in-situ UV-laser ablation ⁴⁰Ar/³⁹Ar geochronology. Undeformed muscovite porphyroclasts yield ⁴⁰Ar/³⁹Ar plateau ages of 182.0±1.6 Ma, whereas in-situ UV-laser ablation ⁴⁰Ar/³⁹Ar dating and furnace step-heating of strongly deformed muscovite and biotite grains display a range of apparent ages that are systematically younger. The range of ⁴⁰Ar/³⁹Ar ages measured in the deformed muscovite and biotite is consistent with protracted cooling through argon closure in minerals that exhibit variably developed segmentation on the intra-grain scale. These microstructurally controlled segments are bound by either first-order lattice discontinuities, sub-microscopic structural defects and/or zones of high defect density, which create variable length-scales for intragranular argon diffusion. The observed deformational microstructures within muscovite and biotite acted as intra-grain fast diffusion pathways in the slowly cooled mylonitic rocks. Therefore, the high-spatial resolution ⁴⁰Ar/³⁹Ar data record the initial and final closure to argon diffusion over a time span of about 60 Ma.