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Production of multi-hollow polymer particles by the stepwise acid/alkali method

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Abstract

Recently, we reported that multi-hollow polymer particles can be prepared from carboxylated polymer particles by the stepwise alkali/acid method. In this article, an attempt was made to prepare similar particles from acid-swellable polymer particles by the stepwise treatment with acid and alkali, which was named the stepwise acid/alkali method. The acid-swellable particles were produced by emulsion terpolymerization of styrene, butyl acrylate, and dimethyl 2-amino ethyl methacrylate. The effects of initial pH value, temperature, and time in the acid and alkali treatment processes on the multi-hollow structure were examined.

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Correspondence to M. Okubo.

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Part CLXV of the series “Studies on Suspension and Emulsion”

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Okubo, M., Mori, H. Production of multi-hollow polymer particles by the stepwise acid/alkali method. Colloid Polym Sci 275, 634–639 (1997). https://doi.org/10.1007/s003960050129

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  • DOI: https://doi.org/10.1007/s003960050129

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