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Synthesis of conducting polymeric nanoparticles in the presence of a polymerizable surfactant and their electrorheological response

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Abstract

Conducting poly(aniline-co-diphenylamine) (PANI-PDPA) nanoparticles were fabricated via chemical oxidative polymerization in an emulsified system as a novel electrorheological (ER) material. A polymerizable surfactant and an amphiphile, which act as both an emulsion stabilizer and a polymerizable monomer, were employed. Morphological and compositional analyses revealed that monodispersed spherical copolymeric nanoparticles were successfully obtained under controlled conditions. The rheological behaviors of the PANI-PDPA-based ER suspension were evaluated by carrying out its rotating shear test under various electric field strengths, in which its stress behaviors were qualitatively analyzed using a four-parametric model.

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Funding

This work was supported by National Research Foundation of Korea (2018R1A4A1025169).

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  1. Department of Polymer Science and Engineering, Inha University, Incheon, 22212, South Korea

    Wen Jiao Han & Hyoung Jin Choi

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  1. Wen Jiao Han
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  2. Hyoung Jin Choi
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Correspondence to Hyoung Jin Choi.

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Han, W.J., Choi, H.J. Synthesis of conducting polymeric nanoparticles in the presence of a polymerizable surfactant and their electrorheological response. Colloid Polym Sci 297, 781–784 (2019). https://doi.org/10.1007/s00396-019-04497-3

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  • DOI: https://doi.org/10.1007/s00396-019-04497-3

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