Abstract
In this paper, we report a simple and low-energy strategy for the preparation of silver decorated polymer colloids. The reported constrained-volume synthesis integrates polymer nanoprecipitation and metal deposition in a one-step continuous-flow fashion. The deposition of Ag nanoparticles (NPs) associated with different optical properties is easily controlled by varying processing parameters. The as-synthesized colloidal NPs have good antimicrobial properties. In addition, the sensitivity of the colloids towards hydrogen peroxide exhibits a linear response over a wide concentration range with a detection limit of 0.03 μM.
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Xu Y, Chen L, Wang X, Yao W, Zhang Q (2015) Recent advances in noble metal based composite nanocatalysts: colloidal synthesis, properties, and catalytic applications. Nanoscale 7:10559–10583
Burda C, Chen X, Narayanan R, El-Sayed MA (2005) Chemistry and properties of nanocrystals of different shapes. Chem Rev 105:1025–1102
Astruc D, Lu F, Aranzaes JR (2005) Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis. Angew Chem Int Ed 44:7852–7872
Na HB, Song IC, Hyeon T (2009) Inorganic nanoparticles for MRI contrast agents. Adv Mater 21:2133–2148
Khin MM, Nair AS, Babu VJ, Murugan R, Ramakrishna S (2012) A review on nanomaterials for environmental remediation. Energy Environ Sci 5:8075–8109
Prabhu S, Eldho KP (2012) Silver nanoparticles: mechanism of antimicrobial action, synthesis, medical applications, and toxicity. Effects Int Nano Lett 2:32
Tian J, Liu R, Wang G, Xu Y, Wang X, Yu H (2014) Dependence of metallic Ag on the photocatalytic activity and photoinduced stability of Ag/AgCl photocatalyst. Appl Surf Sci 319:324–331
Zhang Q, Ge J, Pham T, Goebl J, Hu Y, Lu Z, Yin Y (2009) Reconstruction of silver nanoplates by UV irradiation: tailored optical properties and enhanced stability. Angew Chem Int Ed 48:3516–3519
Gao C, Lu Z, Liu Y, Zhang Q, Chi M, Cheng Q, Yin Y (2012) Highly stable silver nanoplates for surface plasmon resonance biosensing. Angew Chem Int Ed 51:5629–5633
Sharma VK, Yngard RA, Lin Y (2009) Silver nanoparticles: green synthesis and their antimicrobial activities. Adv Colloid Interf Sci 145:83–96
Salam N, Banerjee B, Roy AS, Mondal P, Roy S, Bhaumik A, Islam SM (2014) Silver nanoparticles embedded over mesoporous organic polymer as highly efficient and reusable nanocatalyst for the reduction of nitroarenes and aerobic oxidative esterification of alcohols. Appl Catal A 477:184–194
Sarkar S, Guibal E, Quignard F, SenGupta A (2012) Polymer-supported metals and metal oxide nanoparticles: synthesis, characterization, and applications. J Nanopart Res 14:1–24
Sahiner N (2013) Soft and flexible hydrogel templates of different sizes and various functionalities for metal nanoparticle preparation and their use in catalysis. Prog Polym Sci 38:1329–1356
Farah AA, Alvarez-Puebla RA, Fenniri H (2008) Chemically stable silver nanoparticle-crosslinked polymer microspheres. J Colloid Interface Sci 319:572–576
Lu Y, Mei Y, Schrinner M, Ballauff M, Moller MW, Breu J (2007) In situ formation of Ag nanoparticles in spherical polyacrylic acid brushes by UV irradiation. J Phys Chem C 111:7676–7681
Lu Y, Yu M, Drechsler M, Ballauff M (2007) Ag nanocomposite particles: preparation, characterization and application. Macromol Symp 254:97–102
Liu R, Priestley RD (2016) Rational design and fabrication of core-shell nanoparticles through a one-step/pot strategy. J Mater Chem A 4:6680–6692
Yang P, Xu Y, Chen L, Wang X, Zhang Q (2015) One-pot synthesis of monodisperse noble metal@ resorcinol-formaldehyde (M@RF) and M@carbon core–shell nanostructure and their catalytic applications. Langmuir 31:11701–11708
Liu R, Qu F, Guo Y, Yao N, Priestley RD (2014) Au@ carbon yolk-shell nanostructures via one-step core-shell-shell template. Chem Commun 50:478–480
Liu R, Yeh YW, Tam VH, Qu F, Yao N, Priestley RD (2014) One-pot Stober route yields template for Ag@ carbon yolk-shell nanostructures. Chem Commun 50:9056–9059
Liu R, Sosa C, Yeh YW, Qu F, Yao N, Prud'homme RK, Priestley RD (2014) A one-step and scalable production route to metal nanocatalyst supported polymer nanospheres via flash nanoprecipitation. J Mater Chem A 2:17286–17290
He Y, Priestley RD, Liu R (2016) A one-step and scalable continuous-flow nanoprecipitation for catalytic reduction of organic pollutants in water. Ind Eng Chem Res 55:9851–9856
Han J, Zhu Z, Qian H, Wohl AR, Beaman CJ, Hoye TR, Macosko CW (2012) A simple confined impingement jets mixer for flash nanoprecipitation. J Pharm Sci 101:4018–4023
Saad WS, Prud’homme RK (2006) Principles of nanoparticle formation by flash nanoprecipitation. Nano Today 11:212–227
Johnson BK, Prud'homme RK (2003) Flash nanoprecipitation of organic actives and block copolymers using a confined impinging jets mixer. Aust J Chem 56:1021–10243
Johnson BK, Prud'homme RK (2003) Chemical processing and micromixing in confined impinging jets. AICHE J 49:2264–2282
Ma H, Geng Y, Lee YI, Hao J, Liu HG (2013) Free-standing poly (2-vinylpyridine) foam films doped with silver nanoparticles formed at the planar liquid/liquid interface. J Colloid Interface Sci 394:223–230
Liu YJ, He LB, Xu CH, Han M (2009) Photochemical fabrication of hierarchical Ag nanoparticle arrays from domain-selective Ag + −loading on block copolymer templates. Chem Commun 6566–6568
Zhang C, Pansare VJ, Prud'homme RK, Priestley RD (2012) Flash nanoprecipitation of polystyrene nanoparticles. Soft Matter 8:86–93
Sosa C, Liu R, Tang C, Qu F, Niu S, Bazant M, Prud'homme RK, Priestley RD (2016) Soft multi-faced and patchy colloids by constrained volume self-assembly. Macromolecules 49:3580–3585
Das MR, Sarma RK, Saikia R, Kale VS, Shelke MV, Sengupta P (2011) Synthesis of silver nanoparticles in an aqueous suspension of graphene oxide sheets and its antimicrobial activity. Colloids Surf B 83:16–22
Pasricha R, Gupta S, Srivastava AK (2009) A facile and novel synthesis of Ag–graphene-based nanocomposites. Small 5:2253–2259
Zhang Z, Wu Y, Wang Z, Zou X, Zhao Y, Sun L (2016) Fabrication of silver nanoparticles embedded into polyvinyl alcohol (Ag/PVA) composite nanofibrous films through electrospinning for antibacterial and surface-enhanced Raman scattering (SERS) activities. Mater Sci Eng C 69:462–469
Lee EM, Lee HW, Park JH, Han YA, Ji BC, Oh WT, Deng YL, Yeum JH (2008) Multihollow structured poly (methyl methacrylate)/silver nanocomposite microspheres prepared by suspension polymerization in the presence of dual dispersion agents. Colloid Polymer Sci 286:1379–1385
de Faria AF, Martinez DST, Meira SMM, de Moraes ACM, Brandelli A, Filho AGS, Alves OL (2014) Anti-adhesion and antibacterial activity of silver nanoparticles supported on graphene oxide sheets. Colloids Surf B 113:115–124
Vimala K, Murali Mohana Y, Samba Sivudua K, Varaprasada K, Ravindraa S, Narayana Reddya N, Padmab Y, Sreedharc B, Mohana Rajua K (2010) Fabrication of porous chitosan films impregnated with silver nanoparticles: a facile approach for superior antibacterial application. Colloid Surf B 76:248–258
Filippo E, Serra A, Manno D (2009) Poly (vinyl alcohol) capped silver nanoparticles as localized surface plasmon resonance-based hydrogen peroxide sensor. Sensors Actuators B Chem 138:625–630
Tagad C, Dugasani S, Aiyer R, Park S, Kulkarni A, Sabharwal S (2013) Green synthesis of silver nanoparticles and their application for the development of optical fiber based hydrogen peroxide sensor. Sens Actuator B 183:144–149
Vasileva P, Donkova B, Karadjova I, Dushkin C (2011) Synthesis of starch-stabilized silver nanoparticles and their application as surface plasmon resonance based-sensor of hydrogen peroxide. Colloids Surf A Physicochem Eng Asp 382:203–210
Acknowledgements
R.L. acknowledges the start-up funding from Tongji University and the Young Thousand Talented Program. Y.H. acknowledges the support of the National Younger Natural Science Foundation of China (21405004) and PhD Research Startup Funds of Anhui Normal University (2014bsqdjj43). R.D.P. acknowledges the support of the National Science Foundation (NSF) Materials Research Science and Engineering Center program through the Princeton Center for Complex Materials (DMR-1420541) and the usage of the PRISM Imaging and Analysis Center at Princeton University.
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Yuezhen He and Baojuan Wang equally contributed to this work.
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He, Y., Wang, B., Hu, X. et al. One-step constrained-volume synthesis of silver decorated polymer colloids with antimicrobial and sensing properties. Colloid Polym Sci 295, 521–527 (2017). https://doi.org/10.1007/s00396-017-4035-7
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DOI: https://doi.org/10.1007/s00396-017-4035-7