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On the fracture mechanism of partially healed interfaces of glassy polymers: an ATR-FTIR investigation

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Abstract

Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) has been employed to analyse the surfaces of poly(2,6-dimethyl-1,4-phenylene-oxide) (PPO) samples prior to contact and after fracture of the PPO–PPO auto-adhesive joints which formed during the contact of two identical PPO samples at temperatures of 146 or 156 °С that are lower than the PPO bulk glass transition temperature by 70 or 60 °С, respectively. The differences in the intensity of ATR-FTIR spectra for the original and fractured PPO surfaces found have been discussed in the frameworks of the molecular mechanisms of fracture.

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Authors and Affiliations

  1. Laboratory of Physics of Strength, A.F. Ioffe Physical-Technical Institute, Russian Academy of Sciences, 26 Politekhnicheskaya, St. Petersburg, 194021, Russia

    Yuri M. Boiko & Rustam I. Mamalimov

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  1. Yuri M. Boiko
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  2. Rustam I. Mamalimov
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Correspondence to Yuri M. Boiko.

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Boiko, Y.M., Mamalimov, R.I. On the fracture mechanism of partially healed interfaces of glassy polymers: an ATR-FTIR investigation. Colloid Polym Sci 292, 1003–1007 (2014). https://doi.org/10.1007/s00396-014-3181-4

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  • DOI: https://doi.org/10.1007/s00396-014-3181-4

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