Abstract
We have studied the influence of glycerol on the rheological behavior of viscoelastic surfactant solutions. The measurements were carried out on the system CTAB and NaSal. This system shows two viscosity maxima with increasing NaSal concentration. When water is replaced by glycerol, the viscosities and the structural relaxation times at the viscosity maxima decrease while they increase at the viscosity minimum. As a result of the opposite changes the two maxima are replaced by a single maxima when 40% water is replaced by glycerol. The change of the viscosities is a consequence of a change of the structural relaxation times while the storage moduli remain constant. The opposite changes are a result of different mechanisms for the relaxation times. At the maxima, the relaxation times are reptation controlled and depend on the intermicellar interaction energy. At the minimum, relaxation times are kinetically controlled and depend on the intramolecular interaction.
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References
Hoffmann H, Löbl M, Rehage H, Wunderlich I (1985) Tenside Deterg 22:290
Herb C, Prud’homme R (1994) Structure and flow in surfactant solutions. American Chemical Society, Washington
Clausen T, Vinson P, Minter J, Davis H, Talmon Y, Miller W (1992) J Phys Chem 96:474
Shikata T, Hirata H, Kotaka T (1987) Langmuir 3:1081
Kern F, Lemarechal P, Candau S, Cater M (1992) Langmuir 8:437
Cates M (1996) J Phys Condens Matter 8:9167
Danino D, Bernheim G, Talmon Y (2001) Colloids Surf. A 183:113
Hoffmann H, Schulz S, Gradzielski M, Rauscher A (1992) Langmuir 8:2140
Yan Y, Hoffmann H, Makarsky A, Richter W, Talmon Y (2007) J Phys Chem B 111:6374
Walker L (2001) Curr Opin Colloid Interface Sci 6:451
Acharya D, Kunieda H (2006) Adv Colloid Interface Sci 123:401
Hartmann V, Cressely R (1998) Rheol Acta 37:115
Shukla A, Rehage H (2008) Langmuir 24:8507
Croce V, Cosgrove T, Maitland G, Hughes T, Karlsson G (2003) Langmuir 19:8536
Kim W, Yang S (2000) J Colloid Interface Sci 232:225
Varade D, Rodrguez-Abreu C, Shrestha L, Aramaki K (2007) J Phys Chem B 111:10438
Fisher P, Rehage H (1997) Langmuir 13:7012
Turner M, Cates M (1991) Langmuir 7(8):1590
Turner M, Marques C, Cates M (1993) Langmuir 9:695
Cohen B, Huppert D, Agmon N (2001) J Phys Chem A 105:7165
Cohen B, Huppert D (2000) J Am Chem Soc 122:9838
Rønne C, Thrane L, Wallqvist A, Mikkelsen K, Keidingb S (1997) J Chem Phys 107:8
D’Errico G, Ortona O, Capuano F, Vitagliano V (2004) J Chem Eng Data 49:1665
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Hoffmann, H., Abdel-Rahem, R. Influence of co-solvent on the rheological behavior of aqueous viscoelastic surfactant solutions. Colloid Polym Sci 288, 603–612 (2010). https://doi.org/10.1007/s00396-010-2196-8
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DOI: https://doi.org/10.1007/s00396-010-2196-8