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Interfacial dilational properties of partly hydrolyzed polyacrylamide and gemini surfactant at the decane–water interface

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Abstract

The dilational viscoelastic properties of partly hydrolyzed polyacrylamide (HPAM) and surfactant (C12COONa-p-C9SO3Na) in the absence or presence of electrolyte were investigated at the decane–water interface by means of longitudinal method and the interfacial tension relaxation method. The polymer plays different roles in influencing the structure of HPAM–surfactant mix-adsorbed layer at different surfactant concentration. At low surfactant concentration, the addition of polymer could sharply decrease the dilational elasticity mainly due to the weakening of the “entanglement” among long alkyl chains in surfactant molecules, while the addition of the polymer may enhance the dilational elasticity due to the slow diffusivity of the polymer chains at higher surfactant concentration. And the added electrolyte, which results in screening of electrostatic interactions between the ionized groups, generally decreases the interfacial dilational elasticity and increases the dilational viscosity. The data obtained on the relaxation processes via interfacial tension relaxation measurement can explain the results from dilational viscoelasticity measurements very well.

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References

  1. Han DK, Yang CZ, Zhang ZQ, Lou ZH, Chang YI (1999) J Petrol Sci Eng. 22(1–3):181

    Article  CAS  Google Scholar 

  2. Wang DM, Cheng JC, Wu JZ (1998) SPE 49018:313

    Google Scholar 

  3. Zhang GG, Wang YJ, Wang YL (2001) Oilfield Chemistry 18:282

    Google Scholar 

  4. Moritis G (1996) Oil Gas J 15(4):39

    Google Scholar 

  5. Delamaide E (1994) SPE/DOE 27:819

    Google Scholar 

  6. Taylor KC, Nasr-El-Din HA (1998) J Petrol Sci Eng 19:265

    Article  CAS  Google Scholar 

  7. Gomez JMA, Rodriguez Patino JM (2007) J Phys Chem C 111:4790

    Article  CAS  Google Scholar 

  8. Juarez J, Galaz JG, Machi L, Burboa M, Gutierrez-Millan LE, Goycoolea FM, Valdez MA (2007) J Phys Chem B 111:2727

    Article  CAS  Google Scholar 

  9. Huang YP, Zhang L, Zhang L, Luo L, Zhao S, Yu JY (2007) J Phys Chem B 111:5640

    Article  CAS  Google Scholar 

  10. Hannisdal A, Orr R, Sjoblom J (2007) J Dispersion Sci Technol 28:361

    Article  CAS  Google Scholar 

  11. Martinez KD, Sanchez CC, Ruiz-Henestrosa VP, Rodriguez Patino JM, Pilosof AMR (2007) Food Hydrocolloids 21(5–6):813

    Article  CAS  Google Scholar 

  12. Martinez KD, Carrera Sanchez C, Pizones Ruiz-Henestrosa V, Rodriguez Patino JM, Pilosof AMR (2007) Food Hydrocolloids 21(5–6):804

    Article  CAS  Google Scholar 

  13. Rodriguez Patino JM, Caro AL, Rodriguez Nino MR, Mackie AR, Gunning AP, Morris VJ (2007) Food Chem 102(2):532

    Article  CAS  Google Scholar 

  14. Davis JP, Foegeding EA (2007) Colloids Surf B: Biointerfaces 54(2):200

    Article  CAS  Google Scholar 

  15. Wang YY, Dai YH, Zhang L, Tang K, Luo L, Gong QT, Zhao S, Li MZ, Wang EJ, Yu JY (2004) J Colloid Interface Sci 280(1):76

    Article  CAS  Google Scholar 

  16. Wang DX, Luo L, Zhang L, Zhao S, Wang L, Gong QT, Liao L, Chu YP, Yu JY (2007) J Dispersion Sci Technol 28(5):725

    Article  CAS  Google Scholar 

  17. Luo L, Wang DX, Zhang L, Zhao S, Yu JY (2007) J Dispersion Sci Technol 28(2):263

    Article  CAS  Google Scholar 

  18. Wang YY, Dai YH, Zhang L, Luo L, Zhao S, Li MZ, Wang EJ, Yu JY (2004) Macromolecules 37:2930

    Article  CAS  Google Scholar 

  19. Lucassen J, Van Den Tempel MJ (1972) Chem Eng Sci 27:1283

    Article  CAS  Google Scholar 

  20. Lucassen J, Van Den Tempel MJ (1972) J Colloid Interf Sci 41:491

    Article  CAS  Google Scholar 

  21. Cardenas-Valera AE, Bailey AI (1993) Colloids Surf A 79:115

    Article  CAS  Google Scholar 

  22. Murray BS, Ventura A, Lallemant C (1998) Colloids Surf A 143:211

    Article  CAS  Google Scholar 

  23. Yan F (2007) Ph.D. Dissertation, Beijing: Institute of Physics and Chemistry, Chinese Academy of Sciences

  24. Wang YY, Zhang L, Sun TL, Fang H, Zhao S, Yu JY (2003) Acta Phys Chim Sin 19(5):445

    Google Scholar 

  25. Sun TL, Zhang L, Wang YY, Zhao S, Yu JY (2003) Chem Chin Univ 24(12):2243

    CAS  Google Scholar 

  26. Rao A, Kim Y (2006) Langmuir 22:7964

    Article  CAS  Google Scholar 

  27. Noskov BA, Loglio G, Miller R (2004) J Phys Chem B 108:18615

    Article  CAS  Google Scholar 

  28. Wang YY, Zhang L, Sun TL, Zhao S, Yu JY (2004) J Colloid Interf Sci 270:163

    Article  CAS  Google Scholar 

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Correspondence to Lu Zhang or Sui Zhao.

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Zhang, L., Wang, XC., Yan, F. et al. Interfacial dilational properties of partly hydrolyzed polyacrylamide and gemini surfactant at the decane–water interface. Colloid Polym Sci 286, 1291–1297 (2008). https://doi.org/10.1007/s00396-008-1894-y

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  • DOI: https://doi.org/10.1007/s00396-008-1894-y

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