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Electrokinetics of soft particles

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Abstract

Theories of electrokinetics of soft particles, which are particles covered with an ion-penetrable surface layer of polyelectrolytes, are reviewed. Approximate analytic expressions are given, which describe various electrokinetics of soft particles both in dilute and concentrated suspensions, that is, electrophoretic mobility, electrical conductivity, sedimentation velocity and potential, dynamic electrophoretic mobility, colloid vibration potential, and electrophoretic mobility under salt-free condition.

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References

  1. von Smoluchowski M (1921) Electrische Endosmose und Strömungsströme. In: Greatz L (ed) Handbuch der Elektrizität und des Magnetismus Vol. 2. Barth, Leipzig, p 366

    Google Scholar 

  2. Hückel E (1924) Phys Z 25:204

    Google Scholar 

  3. Henry DC (1931) Proc R Soc Lond A 133:106

    CAS  Google Scholar 

  4. Overbeek J Th G (1943) Kolloid-Beihefte 54:287

    CAS  Google Scholar 

  5. Booth F (1950) Proc R Soc Lond A 203:514

    Article  CAS  Google Scholar 

  6. Wiersma PH, Loeb AL, Overbeek JTh G (1966) J Colloid Interface Sci 22:78

    Google Scholar 

  7. O’Brien RW, White LR (1978) J Chem Soc Faraday Trans 2 74:1607

    CAS  Google Scholar 

  8. Dukhin SS, Semenikhin NM (1970) Kolloid Zh 32:360

    CAS  Google Scholar 

  9. Dukhin SS, Derjaguin BV (1974) Electrokinetic phenomena. In: Matievic E (ed) Surface and colloid science, vol. 7. Wiley, New York

    Google Scholar 

  10. O’Brien RW, Hunter RJ (1981) Can J Chem 59:1878

    CAS  Google Scholar 

  11. Hunter RJ (1981) Zeta potential in colloid science. Academic, New York

    Google Scholar 

  12. Ohshima H, Healy TW, White LR (1983) J Chem Soc Faraday Trans 2(79):1613

    Google Scholar 

  13. van de Ven TGM (1989) Colloid hydrodynamics. Academic, New York

    Google Scholar 

  14. Hunter J (1989) Foundations of colloid science, vol. 2, chapter 13. Clarendon, Oxford

    Google Scholar 

  15. Dukhin SS (1993) Adv Colloid Interface Sci 44:1

    CAS  Google Scholar 

  16. Ohshima H (1994) J Colloid Interface Sci 168:269

    CAS  Google Scholar 

  17. Lyklema J (1995) Fundamentals of interface and colloid science, solid-liquid interfaces, vol. 2. Academic, New York

    Google Scholar 

  18. H. Ohshima (1996) J Colloid Interface Sci 180:299

    CAS  Google Scholar 

  19. Ohshima H, Furusawa K (eds) (1998) Electrical phenomena at interfaces, fundamentals, measurements, and applications, 2nd edn. Revised and expanded. Dekker, New York

    Google Scholar 

  20. Ohshima H (2000) Electrokinetic behavior of particles: theory. In: Somasundaran P (ed) Encyclopedia of surface and colloid science. Dekker, New York

    Google Scholar 

  21. Ohshima H (2001) J Colloid Interface Sci 239:587

    CAS  Google Scholar 

  22. Delgado AV (ed) (2002) Intrerfacial electrokinetics and electrophoresis. Dekker, New York

    Google Scholar 

  23. Spasic A, Hsu JP (eds) (2005) Finely dispersed particles. Micro-, nano-, Atto-engineering. CRC, Boca Raton

    Google Scholar 

  24. Ohshima H (2005) Colloids Surf A Physicochem Eng Asp 267:50

    CAS  Google Scholar 

  25. Ohshima H (2006) In: Akay M (ed) Wiley encyclopedia of biomedical engineering. Wiley, NY

    Google Scholar 

  26. Ohshima, H (2006) Theory of colloid and interfacial electric phenomena. Elsevier, Amsterdam

    Google Scholar 

  27. Donath E, Pastuschenko V (1979) Bioelectrochem Bioenerg 6:543

    CAS  Google Scholar 

  28. Jones S (1979) J Colloid Interface Sci 68:451

    CAS  Google Scholar 

  29. Wunderlich RW (1982) J Colloid Interface Sci 88:385

    CAS  Google Scholar 

  30. Levine S, Levine M, Sharp KA, Brooks DE (1983) Biophys J 42:127

    CAS  Google Scholar 

  31. Scharp KA, Brooks DE (1985) Biophys J 47:563

    Google Scholar 

  32. Ohshima H, Kondo T (1986) Colloid Polym Sci 264:1080

    CAS  Google Scholar 

  33. Ohshima H, Kondo T (1987) J Colloid Interface Sci 116:305

    CAS  Google Scholar 

  34. Ohshima H, Kondo T (1989) J Colloid Interface Sci 130:281

    CAS  Google Scholar 

  35. Ohshima H (1994) J Colloid Interface Sci 163:474

    CAS  Google Scholar 

  36. Ohshima H (1995) Adv Colloid Interface Sci 62:443

    Google Scholar 

  37. Ohshima H (1995) Colloids Surf A Physicochem Eng Asp 103:249

    CAS  Google Scholar 

  38. Ohshima H (1995) Electrophoresis 16:1360

    CAS  Google Scholar 

  39. Ohshima H (2000) J Colloid Interface Sci 228:190

    CAS  Google Scholar 

  40. Ohshima H (2006) Electrophoresis 27:526

    CAS  Google Scholar 

  41. Hermans JJ, Fujita H (1955) Koninkl Ned Akad Wetenschap Proc B58:182

    Google Scholar 

  42. Debye P, Bueche A (1948) J Chem Phys 16:573

    CAS  Google Scholar 

  43. Masliyah JH, Neale G, Malysa K, van de Ven TGM (1987) Chem Sci 42:245

    CAS  Google Scholar 

  44. Kuwabara S (1959) J Phys Soc Japan 14:527

    Google Scholar 

  45. Ohshima H (2000) J Colloid Interface Sci 225:233

    CAS  Google Scholar 

  46. Varoqui R (1982) Nouv J Chim 6:187

    CAS  Google Scholar 

  47. Ohshima H (1997) J Colloid Interface Sci 185:269

    CAS  Google Scholar 

  48. Ohshima H (1997) Colloid Polym Sci 275:480

    CAS  Google Scholar 

  49. Ohshima H (2001) Colloid Polym Sci 279:88

    CAS  Google Scholar 

  50. Ohshima H (2001) Colloids Surf A Physicochem Eng Asp 192:227

    CAS  Google Scholar 

  51. Dukhin SS, Zimmermann R, Werner C (2005) J Colloid Interface Sci 286:761

    CAS  Google Scholar 

  52. Duval JFL, van Leeuwen HP (2004) Langmuir 20:10324

    CAS  Google Scholar 

  53. Duval JFL (2005) Langmuir 21:3247

    CAS  Google Scholar 

  54. Yezek LP, Duval JFL, van Leeuwen HP (2005) Langmuir 21:6220

    CAS  Google Scholar 

  55. Duval JFL, Ohshima H (2006) Lamgmuir 22:3533

    CAS  Google Scholar 

  56. Saville DA (2000) J Colloid Interface Sci 222:137

    CAS  Google Scholar 

  57. Hill RJ, Saville DA, Russel WB (2003) J Colloid Interface Sci 258:561

    Google Scholar 

  58. Hill RJ, Saville DA, Russel WB (2003) J Colloid Interface Sci 263:478

    CAS  Google Scholar 

  59. Hill RJ, Saville DA (2005) Colloids Surf A Physicochem Eng Asp 267:31

    CAS  Google Scholar 

  60. Hill RJ (2004) Phys Rev E 70:051406

    Google Scholar 

  61. Lopez-Garcia JJ, Grosse C, Horno JJ (2003) J Colloid Interface Sci 265:327

    CAS  Google Scholar 

  62. Lopez-Garcia JJ, Grosse C, Horno JJ (2003) J Colloid Interface Sci 265:341

    CAS  Google Scholar 

  63. Ohshima H, Kondo (1991) Biophys Chem 39:191

    CAS  Google Scholar 

  64. Hsu JP, Hsu WC, Chang YI (1987) Colloid Polym Sci 265:911

    Google Scholar 

  65. Hsu JP, Fan YP (1995) J Colloid Interface Sci 172:230

    CAS  Google Scholar 

  66. Ohshima H, Makino K (1996) Colloids Surf A 109:71

    CAS  Google Scholar 

  67. Saville DA (1979) J Colloid Interface Sci 71:477

    CAS  Google Scholar 

  68. O’Brien RW (1981) J Colloid Interface Sci 81:234

    CAS  Google Scholar 

  69. Liu YC, Keh HJ (1998) Langmuir 14:1560

    CAS  Google Scholar 

  70. Ohshima H (2000) J Colloid Interface Sci 229:307

    CAS  Google Scholar 

  71. Booth F (1956) J Chem Phys 22:1954

    Google Scholar 

  72. Saville DA (1982) Adv Colloid Interface Sci 16:267

    CAS  Google Scholar 

  73. Ohshima H, Healy TW, White LR, O’Brien (1984) J Chem Soc Faraday Trans 2(80):1299

    Google Scholar 

  74. Keh HJ, Liu YC (1994) J Colloid Interface Sci 163:474

    Google Scholar 

  75. Ohshima H (2000) J Colloid Interface Sci 229:140

    CAS  Google Scholar 

  76. O’Brien (1988) J Fluid Mech 190:71

    CAS  Google Scholar 

  77. Mangelsdorf CS, White LR (1992) J Chem Soc Faraday Trans 88:3567

    CAS  Google Scholar 

  78. Mangelsdorf CS, White LR (1993) J Colloid Interface Sci 160:275

    CAS  Google Scholar 

  79. Ohshima H (1996) J Colloid Interface Sci 179:431

    CAS  Google Scholar 

  80. Ohshima H (2005) Langmuir 21:9818

    CAS  Google Scholar 

  81. Ohshima H (2001) J Colloid Interface Sci 233:142

    CAS  Google Scholar 

  82. Debye P (1933) J Chem Phys 1:13

    CAS  Google Scholar 

  83. Hermans JJ (1938) Phil Mag 25:426

    CAS  Google Scholar 

  84. Enderby JA (1951) Proc Phys Soc 207A:329

    Google Scholar 

  85. Booth F, Enderby JA (1952) Proc Phys Soc 208A:321

    Google Scholar 

  86. O’Brien RW (1988) J Fluid Mech 190:71

    CAS  Google Scholar 

  87. Ohshima H, Dukhin AS (1999) J Colloid Interface Sci 212:449

    CAS  Google Scholar 

  88. Dukhin AS, Ohshima H, Shilov VN, Goetz PJ (1999) Langmuir 15:3445

    CAS  Google Scholar 

  89. Dukhin AS, Shilov VN, Ohshima H, Goetz PJ (1999) Langmuir 15:6692

    CAS  Google Scholar 

  90. Dukhin AS, Shilov VN, Ohshima H, Goetz PJ (2000) Langmuir 16:2615

    CAS  Google Scholar 

  91. Dukhin AS, Goetz PJ (2002) Ultrasound for characterizing colloids, particle sizing, zeta potential, rheology. Elsevier, Amsterdam

    Google Scholar 

  92. Ohshima H (2005) Langmuir 21:12100

    CAS  Google Scholar 

  93. Ohshima H (2007) Colloids Surf B Biointerfaces 56:16

    CAS  Google Scholar 

  94. Ohshima H (2007) Colloids Surf A Physicochem Eng Asp (in press)

  95. Fuoss RM, Katchalsky A, Lifson S (1951) Proc Natl Acad Sci USA 37:579

    CAS  Google Scholar 

  96. Afrey T, Berg PW, Morawetz P (1951) J Polymer Sci 7:543

    Google Scholar 

  97. Imai N, Oosawa F (1952) Busseiron Kenkyu 52:42

    Google Scholar 

  98. Imai N, Oosawa F (1953) Busseiron Kenkyu 59:99

    Google Scholar 

  99. Ohshima H (2002) J. Colloid Interface Sci 247:18

    CAS  Google Scholar 

  100. Ohshima H (2002) J Colloid Interface Sci 248:499

    CAS  Google Scholar 

  101. Ohshima H (2004) J Colloid Interface Sci 269:255

    CAS  Google Scholar 

  102. Ohshima H, Makino K, Kato T, Fujimoto K, Kondo T, Kawaguchi H (1993) J Colloid Interface Sci 159:512

    CAS  Google Scholar 

  103. Mazda T, Makino K, Ohshima H (1995) Colloids Surf B 5:75; Erratum (1998) ibid 10:303

    CAS  Google Scholar 

  104. Takashima S, Morisaki H (1997) Colloids Surf B 9:205

    CAS  Google Scholar 

  105. Bos R, van der Mei HC, Busscher HJ (1998) Biophys Chem 74:251

    CAS  Google Scholar 

  106. Larsson A, Rasmusson M, Ohshima H (1999) Carbohydr Res 317:223

    CAS  Google Scholar 

  107. Morisaki H, Nagai S, Ohshima H, Ikemoto E, Kogure K (1999) Microbiology 145:2797

    CAS  Google Scholar 

  108. Rasmusson M, Vincent B, Marston N (2000) Colloid Polym Sci 278:253

    CAS  Google Scholar 

  109. Hayashi H, Tsuneda S, Hirata A, Sasaki H (2001) Colloids Surf B 22:149

    CAS  Google Scholar 

  110. Garcia-Salinas MJ, Romero-Cano MS, de las Nieves FJ (2001) Progr Colloid Polym Sci 118:180

    Article  CAS  Google Scholar 

  111. Kiers PJM, Bos R, van der Mei HC, Busscher HJ (2001) Microbiology 147:757

    CAS  Google Scholar 

  112. Molina-Bolivar JA, Galisteo-Gonzalez F, Hidalgo-Alvalez R (2001) Colloids Surf B Biointerfaces 21:125

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Faculty of Pharmaceutical Sciences and Institute of Colloid and Interface Science, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510, Japan

    Hiroyuki Ohshima

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  1. Hiroyuki Ohshima
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Correspondence to Hiroyuki Ohshima.

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Ohshima, H. Electrokinetics of soft particles. Colloid Polym Sci 285, 1411–1421 (2007). https://doi.org/10.1007/s00396-007-1740-7

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  • DOI: https://doi.org/10.1007/s00396-007-1740-7

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