Skip to main content
SpringerLink
Log in

A fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer/silica gel nanocomposite with no weight loss even at 800 °C equal to an original silica gel

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer [RF-(DOBAA)n-RF]/silica gel nanocomposite, which was prepared by reaction of the corresponding fluorinated oligomer with tetraethoxysilane and silica gel nanoparticles under alkaline conditions, exhibited no weight loss even at 800 °C equal to the original silica gel, although the corresponding parent RF-(DOBAA)n-RF oligomer was completely degraded at 600 °C. Thermogravimetric analyses/mass spectra of fluorinated nanocomposite showed that this nanocomposite decomposed around 280 °C to afford CO2 and H2O as the major evolved gaseous products including some minor fluoro- and hydrocarbons. X-ray photoelectron spectroscopy analyses also showed that the contents of C, F, and Si atoms in RF-(DOBAA)n-RF/SiO2 nanocomposite after the calcination at 800 °C were similar to those before the calcination. These findings suggest that the evolved gaseous products should be encapsulated quantitatively into nanometer-size-controlled silica matrices to give the fluorinated silica gel nanocomposite with no weight loss even at 800 °C equal to the original silica gel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Judeinstein P, Sanchez C (1996) J Mater Chem 6:511–525

    Article  CAS  Google Scholar 

  2. Wen J, Wilkes GL (1996) Chem Mater 8:1667–1681

    Article  CAS  Google Scholar 

  3. Laine RM, Sanchez C, Brinker CJ, Giannelis E (1998) Organic–inorganic hybrid materials. Materials Research Society, Warrendale, PA, USA

    Google Scholar 

  4. Brinker CJ, Scherer GW (1990) Sol–gel science. Academic, Boston

    Google Scholar 

  5. Misra M, Guest A, Tilley M (1998) Surf Coat Int 81:594–595

    CAS  Google Scholar 

  6. Hua Z, Qiu K-Y (1997) Polymer 31:521–526

    Google Scholar 

  7. Pedroso MAS, Dias ML, San Gil RAS, Mothe CG (2003) Colloid Polym Sci 281:19–26

    Article  CAS  Google Scholar 

  8. Matejka L, Plestil J (1997) Macromol Symp 122:191–196

    CAS  Google Scholar 

  9. Juangvanich N, Maurite KA (1998) J Appl Polym Sci 67:1799–1810

    Article  CAS  Google Scholar 

  10. Johns K, Stead G (2000) J Fluorine Chem 104:5–18

    Article  CAS  Google Scholar 

  11. Ameduri B, Boutevin B (2000) J Fluor Chem 104:53–62

    Article  CAS  Google Scholar 

  12. Berret J-F, Calvet D, Collet A, Viguier M (2003) Curr Opin Colloid Interface Sci 8:296–306

    Article  CAS  Google Scholar 

  13. Kujawa P, Goh CCE, Calvet D, Winnik FM (2001) Macromolecules 34:6387–6395

    Article  CAS  Google Scholar 

  14. Imae T (2003) Curr Opin Colloid Interface Sci 8:307–314

    Article  CAS  Google Scholar 

  15. Andruzzi L, Chiellini E, Galli G, Li X, Kang SH, Ober CK (2002) J Mater Chem 12:1684–1692

    Article  CAS  Google Scholar 

  16. Imae T, Tabuchi H, Funayama K, Sato A, Nakamura T, Amaya N (2000) Colloid Surf A Physicochem Eng Asp 167:73–81

    Article  CAS  Google Scholar 

  17. Jankova K, Hvilsted S (2005) J Fluorine Chem 126:241–250

    Article  CAS  Google Scholar 

  18. Lebreton P, Ameduri B, Boutevin B, Corpart J-M (2002) Macromol Chem Phys 203:522–537

    Article  CAS  Google Scholar 

  19. Sawada H (1996) Chem Rev 96:1779–1808

    Article  PubMed  CAS  Google Scholar 

  20. Sawada H, Kawase T (2001) Kobunshi Ronbunshu 58:147–160

    Google Scholar 

  21. Sawada H, Kawase T (2001) Kobunshi Ronbunshu 58:255–266

    CAS  Google Scholar 

  22. Sawada H (2000) J Fluorine Chem 105:219–220

    Article  CAS  Google Scholar 

  23. Harmer MK, Farneth WE, Sun Q (1996) J Am Chem Soc 118:7708–7715

    Article  CAS  Google Scholar 

  24. Cho J-W, Sul K-I (2001) Fiber Polym 2:135–140

    CAS  Google Scholar 

  25. Yano S, Okubo N, Takahashi K (1996) Macromol Symp 108:270–289

    Google Scholar 

  26. Fabbri P, Messori M, Montecchi M, Nannarone S, Pasquali L, Pilati F, Tonelli C, Toselli M (2006) Polymer 47:1055–1062

    Article  CAS  Google Scholar 

  27. Sawada H, Narumi T, Kajiwara A, Ueno K, Hamazaki K (2006) Colloid Polym Sci 284:551–555

    Article  CAS  Google Scholar 

  28. Gregg SJ, Sing KS, Sing W (1982) Adsorption, surface areas and porosity, 2nd edn. Academic, New York

    Google Scholar 

  29. Sawada H, Koizumi M, Tojo T, Ohnishi T, Tomoita T (2005) Polym Adv Technol 16:459–465

    Article  CAS  Google Scholar 

  30. Welton T (1999) Chem Rev 99:2071–2084

    Article  PubMed  CAS  Google Scholar 

  31. Sawada H, Yoshino Y, Kurachi M, Kawase T, Takishita K, Tanedani T (2000) Polymer 41:397–4000

    Article  CAS  Google Scholar 

Download references

Acknowledgement

We thank S. Nagasawa (Bruker AXS. K. K., Japan) for TG/Mass observation and Y. Yoshida (Kratos Analytical, Japan) for XPS observation. This work was partially supported by a grant-in-aid for Scientific Research from the Ministry of Education, Science, Sports and Culture, Japan.

Author information

Authors and Affiliations

  1. Department of Frontier Material Chemistry, Faculty of Science and Technology, Hirosaki University, Bunkyo-cho, Hirosaki, 036-8561, Japan

    Hideo Sawada, Tamikazu Narumi & Shun Kodama

  2. Nissan Research Center, Nissan Motor Co., Ltd., Yokosuka-shi, Kanagawa, 237-8523, Japan

    Motohisa Kamijo & Yasukazu Iwasaki

  3. Research and Development Division, Nippon Chemical Industrial Co., Ltd., Koto-ku, Tokyo, 136-8515, Japan

    Ryou Ebara & Masashi Sugiya

Authors
  1. Hideo Sawada
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tamikazu Narumi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shun Kodama
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Motohisa Kamijo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ryou Ebara
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Masashi Sugiya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yasukazu Iwasaki
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hideo Sawada.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sawada, H., Narumi, T., Kodama, S. et al. A fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer/silica gel nanocomposite with no weight loss even at 800 °C equal to an original silica gel. Colloid Polym Sci 285, 977–983 (2007). https://doi.org/10.1007/s00396-007-1641-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-007-1641-9

Keywords

Search

Navigation