Abstract
Calcium chloride reacted with sodium carbonate in the presence of a variety of self-assembled molecular aggregates formed by fluoroalkyl end-capped acrylic acid, 2-methacryloyloxyethane sulfonic acid, dimethylacrylamide, and acryloylmorpholine oligomers in aqueous solutions to afford the corresponding fluorinated oligomers/calcium carbonate composites in excellent to moderate isolated yields. These fluorinated calcium carbonate composites thus obtained were shown to have a good dispersibility not only in water but also in traditional organic media including fluorinated solvents. Dynamic light scattering measurements (DLS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that these fluorinated composites are nanometer-size-controlled particles and well dispersed in these media. Cross-linked fluoroalkyl end-capped acrylic acid co-oligomer containing poly(oxyethylene) units was also applied to the preparation of new cross-linked fluorinated calcium carbonate nanocomposites under similar conditions. The obtained cross-linked fluorinated calcium carbonate nanocomposites were found to have an extremely higher dispersibility in aqueous and organic media including fluorinated solvents, compared to that of the corresponding fluoroalkyl end-capped oligomer nanocomposites. In particular, it was verified that these fluorinated calcium carbonate nanocomposites are applicable to the dispersion above poly(methyl methacrylate) (PMMA) film surface. Interestingly, field-emission SEM (FE-SEM) images of the cross-section of the modified PMMA films showed that calcium carbonate particles dispersed into these PMMA films could be arranged regularly above the modified film surface. More interestingly, cross-linked fluorinated oligomeric aggregates were able to provide suitable host moieties for the crystallization of calcium carbonate.
Similar content being viewed by others
References
Zanetti M, Lomakin S, Camino G (2000) Macromol Mater Eng 279:1
Schmid G (ed) (2004) Nanoparticles—from theory to application, Wiley-VCH, Weinheim
Ajayan PM, Schadler LS, Braun PV (2003) Nanocomposite science and technology. Wiley-VCH, Weinheim (2003)
Gomez-Romero P, Sanchez C (2004) Functional hybrid materials. Wiley-VCH, Weinheim
Rothon RN (ed) (1995) Particulate-filled polymer composites. Wiley, New York
Reeder RJ (ed) (1983) Carbohydrates: mineralogy and chemistry. In: Reviews in mineralogy, vol 11. Mineralogy Society of America, Washington, DC
Chan C-M, Wu J, Li J-X, Cheung Y-K (2002) Polymer 43:2981
Yang Y, Kong XZ, Kan CY, Sun CG (1999) Polym Adv Technol 10:54
Bechthold N, Tiarks F, Willert M, Landfester K, Antonietti M (2000) Macromol Symp 151:549
Yu J, Yu J, Guo Z-X, Gao Y-F (2001) Macromol Rapid Commun 22:1261
Wu D, Wang X, Song Y, Jin R (2004) J Appl Polym Sci 92:2714
Jiang L, Dan Y(2004) Colloid Polym Sci 282:1374
Xie X-L, Liu Q-X, Li RK-Y, Zhou X-P, Zhang Q-X, Yu Z-Z, Mai Y-W (2004) Polymer 45:6665
Rong MZ, Zhang MQ, Zheng YX, Zeng HM, Walter R, Friedrich K (2001) Polymer 42:167
Rong MZ, Zhang MQ, Zheng YX, Zeng HM, Walter R, Friedrich K(2001) Polymer 42:3301
Hasegawa N, Okamoto H, Kato M, Usuki A (2000) J Appl Polym Sci 78:1918
Levita G, Marchetti A, Lazzeri A (1989) Polym Eng Sci 19:39
Johns K, Stead G (2000) J Fluorine Chem 104:5
Ameduri B, Boutevin B (2000) J Fluorine Chem 104:53
Sawada H (1996) Chem Rev 96:1779
Sawada H (2003) J Fluorine Chem 121:111
Sawada H, Fong Y-F, Minoshima Y, Yoshino Y, Matsumoto T, Nakayama M, Kosugi M, Migita T (1992) J Chem Soc Chem Commun 537
Kurach M, Kawase T, Takishita K, Tanedani T (2000) Polymer 41:397
Sawada H, Yoshino Y, Ikematsu Y, Kawase T (2000) Eur Polym J 36:231
Sawada H, Kawase T, Ikematsu Y, Yoshii Y, Oue M, Hayakawa Y(1996) J Chem Soc Chem Commun 179
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sawada, H., Shikauchi, Y., Kakehi, H. et al. Preparation and applications of novel fluoroalkyl end-capped oligomers/calcium carbonate nanocomposites. Colloid Polym Sci 285, 499–506 (2007). https://doi.org/10.1007/s00396-006-1566-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-006-1566-8