Abstract
Polyurethane (PU)/silica nanocomposites (PSNs) were synthesized using the “grafting from” technique by incorporation of inorganic nano-sized silica building blocks into a polyurethane matrix. Structurally well-dispersed and stable hybrids were obtained via a two-step functionalized reaction. Firstly, 3-aminopropyltriethoxysilane (APTS) was employed to encapsulate silica as the core surface. Secondly, the PU shell was tethered to the silica core surface via surface functionalization. In order to obtain complete encapsulation of silica with APTS, different ratios of APTS to silica were investigated. The mechanism of the incorporation process was also revealed. PSNs hybrids were characterized by attenuated total reflectance and Fourier transform infrared spectroscopies, differential scanning calorimetry, thermogravimetric analysis, and transmission electron microscopy.
Similar content being viewed by others
References
Huang HH, Orler B, Wikes GL (1987) Macromolecules 20:1322
Kohjiya S, Ochiai K, Yamashita S (1990) J Non-Cryst Solids 119:132
Morikawa A, Iyoku Y, Kakimoto M, Imai Y (1992) Polym J 24:107
Mascia L, Kioul A (1994) J Mater Sci Lett 13:641
Kim JH, Lee YM (2001) J Membr Sci 193:209
Park HB, Kim JK, Nam SY, Lee YM (2003) ) J Membr Sci 220:59
Jeffrey P, Krzystof M (2001) Chem Mater 13:3436
Timothy VW, Timothy EP (2001) J Am Chem Soc 123:7497
Timothy VW, Timothy EP (1999) J Am Chem Soc 121:7409
Spange S (2000) Prog Polym Sci 25:781
Zhou Q, Wang SX, Fan XW (2002) Langmuir 18:3324
Chen S, Ijin Kim, Faust R (2003) J Am Chem Soc Polym Prepr 44:463
Chujo Y, Saegusa T (1992) Adv Polym Sci 100:11
Chujo Y (1996) Curr Opin Solid State Mater Sci 1:806
Penczek P, Frisch KC, Szczepaniak B, Rudnik E (1993) J Polym Sci Polym Chem Ed 31:1211
Tang W, Farries RJ, Macknight WJ, Eisenbach CD (1994) Macromolecules 27:2814
Kim BK, Seo JW, Jeong HM (2003) Eur Polym J 39:85
Chen TK, Tien YI, Wei KH (2000) Polymer 41:1345
Kickelbick G (2003) Prog Polym Sci 28:83
Yao KJ, Song M, Hourston DJ, Luo DZ (2001) Polymer 43:1017
Tortora M, Gorrasi G, Vittiria V, Gali G, Ritrovati S Chiellini E (2002) Polymer 43:6147
Tien YI, Wei KH (2001) Polymer 42:3214
Torrό-Palau AM, Fernández-García JC, Orgilés-Barcelό AC, Martín-Martínez JM (2001) Int J Adhesion Adhesives 21:1
Nunes RCR, Pereira RA, Fonseca JLC, Pereira MR (2001) Polym Testing 20:707
Kusakabe K, Yoneshige S, Morooka S (1998) J Membrane Sci 149:29
Nunes RCR, Fonseca JLC, Pereira MR (2000) Polym Testing 19:93
LeBaron PC, Wang Z, Pinnavaia TJ (1999) Appl Clay Sci 15:11
Gu YS, Chen L, Chen S (2003) Nanjing Gongye Daxue Xuebao 25:107
Chen S, Chen L (2003) Colloid Polym Sci 281:288
Pasquet V, Spitz R (1990) Makromol Chem 191:3087
Bauer F, Gläsel HJ, Decker U, Ernst H, Freyer A, Hartmann E, Sauerland V, Mehnert R (2003) Progr Org Coatings 47:147
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chen, S., Sui, J. & Chen, L. Positional assembly of hybrid polyurethane nanocomposites via incorporation of inorganic building blocks into organic polymer. Colloid Polym Sci 283, 66–73 (2004). https://doi.org/10.1007/s00396-004-1093-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-004-1093-4