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Preparation of polymer particles having ethyleneurea groups at their surfaces by emulsifier-free seeded emulsion polymerization and wet adhesion of its emulsion film

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Abstract.

Polymer emulsion having ethyleneurea groups at particle surfaces was produced by emulsifier-free seeded emulsion copolymerization of n-butyl methacrylate (BMA) and methacrylamide ethylethyleneurea (EU) with poly(BMA) seed particles utilizing the starved-fed monomer addition method. This emulsion film, prepared by casting the polymer emulsion on an alkyd resin plate, had a superior adhesion in water, as well as on stainless steel. Such superior wet adhesions seem to be based on a large amount of EU predominantly localized at the particle surfaces.

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References

  1. Kreis RW, Sherman AM (1988) The waterborne & higher-solids coating symposium, 222

  2. Siesel B (1998) Progress in Organic Coating 34:214

    Google Scholar 

  3. Kameya M (2000) Finechemical 29(9):17

    Google Scholar 

  4. Matsuda M (2001) J Adhesion Soc Japan 37:24

    CAS  Google Scholar 

  5. Matsuda M, Sugitani T, Goh HB (1999) Tosou & Toryou 591:35

    Google Scholar 

  6. Rhone-Poulenc Technical Bulletin (1995) SIPOMER WAM-II

  7. Okubo M, Matsuda M, Terada A, Kagawa Y, Kondo S (2003) J Appl Polym Sci (in press)

  8. Vijayendran BR (1979) J Appl Polym Sci 23:893

    Google Scholar 

  9. Brandrup J, Immergut EH, Grulke EA,(1999) Polymer Handbook, 4th edn. Wiley, New York

  10. Vandezande GA, Smith OW, Bassett DR (1997) Vinyl acetate polymerization. In: Lovell PA, El-Aasser MS (eds) Emulsion polymerization and emulsion polymers. Wiley, New York, pp 563–587

  11. Bassett DR, Hamielec AE(1981) ACS Symposium Series 165:371

    CAS  Google Scholar 

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Author notes

  1. Mitsuo Matsuda

    Present address: R & D Application Laboratory, Rhodia Nicca Ltd., 910–8670, Fukui, Japan

Authors and Affiliations

  1. Graduate School of Science and Technology, Kobe University, 657–8501, Kobe , Japan

    Masayoshi Okubo, Yasuyuki Kagawa, Mitsuo Matsuda & Akinori Terada

Authors
  1. Masayoshi Okubo
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  2. Yasuyuki Kagawa
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  3. Mitsuo Matsuda
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  4. Akinori Terada
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Corresponding author

Correspondence to Masayoshi Okubo.

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Part CCXLIX of the series "Studies on suspension and emulsion"

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Okubo, M., Kagawa, Y., Matsuda, M. et al. Preparation of polymer particles having ethyleneurea groups at their surfaces by emulsifier-free seeded emulsion polymerization and wet adhesion of its emulsion film. Colloid Polym Sci 282, 88–91 (2003). https://doi.org/10.1007/s00396-003-0981-3

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  • DOI: https://doi.org/10.1007/s00396-003-0981-3

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