Abstract.
Single and mixed micelle formation by sodium dodecyl sulfate (SDS) and sodium dodecylbenzene sulfonate (SDBS) and their mixtures in pure water and in the presence of water-soluble polymers such as Synperonic 85 (triblock polymer, TBP), hydroxypropylcellulose (HPC), and carboxymethylcellulose sodium salt (CMC) were studied with the help of conductivity, pyrene fluorescence, cyclic voltammetry, and viscosity measurements. Conductivity measurements showed a single aggregation process for pure surfactants and their mixtures both in pure water as well as in the presence of water-soluble polymers. Triple breaks corresponding to two aggregation processes for SDS, SDBS, and their mixture in the presence of TBP were observed from fluorescence measurements. The first one demonstrated the critical aggregation process due to the adsorption of surfactant monomers on TBP macromolecule. The second one was attributed to the participation of surfactant–polymer aggregates formed at the first one, in the micelle formation process. The aggregation number (N agg ) of single and mixed micelles and diffusion coefficient (D) of electroactive probe were computed from the fluorescence and cyclic voltammetry measurements, respectively. Both parameters, along with the viscosity results, indicated stronger SDS–polymer interactions in comparison to SDBS–polymer interactions. Mixed surfactant–polymer interactions showed compensating effects of both pure surfactants. The nature of mixed micelles was found to be ideal in all cases, as evaluated by applying the regular solution and Motomura's approximations.
Similar content being viewed by others
References
(a) Kwak JCT (1998) Polymer-surfactant systems, Surfactant science series, vol 77. Marcel Dekker, New York; (b) Jonsson B, Lindman B, Holmberg K, Kronberg B (eds) (1998) Surfactants and polymers in aqueous solutions. Wiley, New York; (c) Nagarajan R, Kalpakci B (1985) In: Dubin P (ed) Microdomains in polymer solutions. Plenum, New York, p 369; (d) Tsujii K (1998) Surface activity (principles, phenomena, and applications) Academic Press, London
Merta J, Stenius P (1995) Colloid Polym Sci 273:974
Kogrej K, Skerjane J (1999) Langmuir 15:425
Goddard ED (1986) Colloids Surf 19: 255,301
Glass JE (ed) (1989) In: Polymers in aqueous media: performance through association. Advances in chemistry series 223, Am Chem Soc, Washington, DC
Brackman JC, Engberts JBFN (1993) Chem Soc Rev 22:85
(a) Dubin PL, The SS, Chew CH, Gan LM (1990) J Colloid Interface Sci 23:2500; (b) Dubin PL, The SS, Gan LM, Chew CH (1990) Macromolecules 23:2500; (c) Dubin PL, Vea MEY, Fallon MA, The SS, Rigsbee DR, Gan LM (1990) Langmuir 6:6696
(a) Liu J, Takisawa N, Shirahama K (1998) J Phys Chem B 102:6696; (b) Liu J, Takisawa N, Shirahama K (1999) Colloid Polym Sci 277:247
(a) Bakshi MS, Kaur G, Kaur G (1999) J Macromolecular Sci A36:697; (b) Bakshi MS, Doe H (1999) Bull Chem Soc 72:2041; (c) Bakshi MS, Mahajan S (2000) J Jpn Oil Chem Soc 49:17; (d) Bakshi MS, Kaur G (2000) J Surfactants and Detergents 3:159; (e) Bakshi MS (2000) Colloid Polym Sci 278:524;(f) Bakshi MS, (2001) J Surfactants and Detergents 4:297
Murase Y, Tsujii K, Tanaka T (2000) Langmuir 16:6385
(a) MacNeill J, Hargreaves NG (1982) US Patent 4362758; (b) Hui YH (ed) (1992) Encyclopedia of food science and technology, vol 2. Wiley, New York, p 680 ff
Ozeki S, Ikeda S (1980) J Colloid Interface Sci 77:219
(a) Mukerjee P, Mysels KJ, Kapauan P (1967) J Phys Chem 71:4166; (b) Goddard ED, Benson GC (1957) Can J Chem 35:986
(a) Sugihara G, Hisatomi M (1998) J Jpn Oil Chem Soc 47:661; (b) Moroi Y (1992) Micelles, theoretical and applied aspects. Plenum, New York; (c) Sugihara G, Era Y, Funatsu M, Kunitake T, Lee S, Sasaki Y (1997) J Colloid Interface Sci 187:345; (d) Manabe M, Kawamura H, Yamashita Y, Tokunaga S (1990) In: Bloor BM, Wyn-Jones E (eds) The structure, dynamics and equilibrium properties of colloidal systems. Kluwer Academic Publishers, Netherlands pp 63–69
(a) Jones MN(1967) J Colloid Interface Sci 23:36; (b) Moroi Y, Akisada H, Saito M, Matuura R (1977) J Colloid Interface Sci 61:233
Pletnev M Yu, Trapejnikov AA (1978) Kolloidn Zh 40:948
(a) Nagarajan R, Ruckenstein E (1983) J Colloid Interface Sci 91:500; (b) Nagarajan R (1985) Colloids Surf 13:1
(a) Infelta PP (1979) Chem Phys Lett 61:88; (b) Almgrem M, Leofroth JE, Van Stam J (1986) J Phys Chem 90:5684; (c) Gehlen MH, Van der Auweraer M, Reekmans S, Neumann MG, De Schryver FC (1991) J Phys Chem 150:53; (d) Kim JH, Domach MM, Tilton RD (1999) Colloids Surf A 150:53
(a) Cabane B, Duplessix R (1985) Colloids Surf 13:19; (b) Zana R, Lang J, Lianos P (1982) Polym Prep (Am Chem Soc, Div Polym Chem) 39(1):39; (c) Lissi EA, Abuin E (1985) J Colloid Interface Sci 105:1; (d) Gilyani T, Wolfram E (1981) Colloids Surf 3:181
(a) Milliaris A (1987) J Phys Chem 91:6511; (b) Zana R, Yiu S, Strazielle C, Lianos P (1981) J Colloid Interface Sci 80:208
Hassan PA, Yakhmi JV (2000) Langmuir 16:7187
Bard AJ, Faulkner LR (1980) Electrochemical methods. Wiley,New York
(a) Clint JH (1975) J Chem Soc Faraday Trans 1 , 71:1327; (b) Rubingh DN (1979) In: Mittal KL (ed) Solution chemistry of surfactants, vol 1. Plenum, New York, p 337
(a) Lopez-Fontan JL, Suarez MJ, Mosquera V, Sarmiento F (2000) J Colloid Interface Sci 223:185; (b) Lopez-Fontan JL, Suarez MJ, Mosquera V, Sarmiento F (1999) PCCP 1:3583
(a) Motomura K, Matsukiyo M, Avatono M (1984) Colloid Polym Sci 262:948; (b) Puvvada S, Blankschein D (1992) J Phys Chem 96:5567; (c) Haque ME, Das AR, Rakshit AK, Monlik SP (1996) Langmuir 12:4084
(a) . Motomura K, Aratono K (1993) Miscibility in binary mixtures of surfactants. In: Ogino K, Abe M (eds) Mixed surfactant systems. Marcel Dekker, New York; (b) Aratono M, Villeneuve M, Takiue T, Ikeda N, Iyota H (1998) J Colloid Interface Sci 200:161
Asakawa T, FukitaT, Miyagishi S (1991) Langmuir 7:2112
Cavallaro G, Giammona G, La Manna G, Palazzo S, Pitarresi G, Turco Liveri V (1993) International J Pharm 90:195
Nakagawa J, Kamogawa K, Sakai H, Kawase T, Sawada H, Manosroi J, Manosroi A, Abe M (1998) Langmiur 2055
Mylonas Y, Staikos G (1999) Langmuir15:7172
(a) Desai PR, Jain NJ, Sharma RK, Bahadur P (2001) Colloids Surf A 178:57; (b) Muto S, Ino T, Meguro K (1972) J Am Oil Chem Soc 49:437
Griffiths PC, Whatton ML, Abbott RJ, Kwan W, Pitt AR, Howe AM King SM, Heenan RK (1999) J Colloid Interface Sci 215:114
Acknowledgment.
Thanks are due to Dr. Gurinder Kaur, Dept. of Applied Physics, for computational assistance. Research grant from the CSIR, New Delhi, [No. 01(1777)/02/EMR-II] is thankfully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bakshi, M.S., Kaur, R., Kaur, I. et al. Unlike surfactant–polymer interactions of sodium dodecyl sulfate and sodium dodecylbenzene sulfonate with water-soluble polymers. Colloid Polym Sci 281, 716–726 (2003). https://doi.org/10.1007/s00396-002-0822-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-002-0822-9