Abstract.
Azobenzene-containing polymers exhibit strong surface-relief features when irradiated with polarized light. Currently proposed theories do not explain all the observed features. Here we propose a theory based on elastic deformation of the polymer due to interaction between dipoles ordered through polarized light irradiation. The effects are due to the presence of a boundary layer. The observation of both wells and humps dependent on the architecture of the polymer can be explained with the present theory.
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Received: 29 June 2001 / Revised version: 9 November 2001 / Published online: 17 January 2002
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Gaididei, Y., Christiansen, P. & Ramanujam, P. Theory of photoinduced deformation of molecular films . Appl Phys B 74, 139–146 (2002). https://doi.org/10.1007/s003400100779
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DOI: https://doi.org/10.1007/s003400100779