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Absorption electronic spectrum of gaseous FeO: in situ detection with intracavity laser absorption spectroscopy in a nanoparticle-generating flame reactor

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Abstract

Absorption measurement of a gas-phase iron oxide (FeO) electronic spectrum is reported for the first time. FeO was obtained in a methane/oxygen/nitrogen flame doped with iron pentacarbonyl and monitored via the 611-nm band of the orange system with intracavity laser absorption spectroscopy. The measured spectral range extends from 16,250 to 16,450 cm−1 for the appropriate intracavity tuning element position. The presented measurements demonstrate sensitive detection of the gas-phase precursor, playing a key role in flame synthesis of iron oxide nanoparticles. The sensitivity of the intracavity technique does not depend on broadband cavity losses and allows conducting measurements in a highly scattering, particle-laden flame environment.

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Acknowledgments

This work was supported in part by the Israel Science Foundation (Grant No. 1069/08), the grant of the Israeli Ministry of Energy and Water Resources, and the Research Authority of The Open University of Israel (Grant No. 47324).

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Authors and Affiliations

  1. Department of Natural Sciences, The Open University of Israel, Raanana, 4353701, Israel

    Igor Rahinov

  2. School of Chemistry, Tel Aviv University, Tel Aviv, 69978, Israel

    Alexey Fomin, Marina Poliak & Sergey Cheskis

Authors
  1. Igor Rahinov
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  2. Alexey Fomin
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  3. Marina Poliak
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  4. Sergey Cheskis
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Correspondence to Igor Rahinov.

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Rahinov, I., Fomin, A., Poliak, M. et al. Absorption electronic spectrum of gaseous FeO: in situ detection with intracavity laser absorption spectroscopy in a nanoparticle-generating flame reactor. Appl. Phys. B 117, 317–323 (2014). https://doi.org/10.1007/s00340-014-5838-6

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  • DOI: https://doi.org/10.1007/s00340-014-5838-6

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