Abstract
We show that second harmonic generation from lithographically prepared arrays of symmetric gold nanorods can be increased by two orders of magnitude by choosing the nanoparticle size to be resonant with the 800-nm wavelength of the 50-fs pump laser. The angular variation of the second-harmonic yield, which is defined by the pitch of the nanorod array, can be predicted using standard diffraction theory. This in turn makes it possible to bound approximately the relative contributions of dipole and quadrupole oscillations to the total second-harmonic yield; the two contributions appear to be of similar magnitude. Resonant ultrafast irradiation also changes the nanorod morphology, apparently due to surface melting and refreezing. At higher fluence, the intensity dependence of the second-harmonic yield changes from quadratic to cubic, an indication that the reshaping influences the mechanism of second-harmonic generation.
Similar content being viewed by others
References
Y.R. Shen, The Principles of Nonlinear Optics (John Wiley and Sons, New York, 1984)
J.I. Dadap, J. Shan, K.B. Eisenthal, T.F. Heinz, Phys. Rev. Lett. 83, 4045 (1999)
J.I. Dadap, J. Shan, T.F. Heinz, J. Opt. Soc. Am. B 21, 1328 (2004)
H. Tuovinen, M. Kauranen, K. Jefimovs, P. Vahimaa, T. Vallius, J. Turunen, N.V. Tkachenko, H. Lemmetyinen, J. Nonlinear Opt. Phys. Mater. 11, 421 (2002)
B. Lamprecht, A. Leitner, F.R. Aussenegg, Appl. Phys. B 68, 419 (1999)
B. Lamprecht, J.R. Krenn, A. Leitner, F.R. Aussenegg, Phys. Rev. Lett. 83, 4421 (1999)
M.D. McMahon, R. Lopez, R.F. Haglund, E.A. Ray, P.H. Bunton, Phys. Rev. B 73, 041401 (2006)
B.K. Canfield, S. Kujala, M. Kauranen, K. Jefimovs, T. Vallius, J. Turunen, Appl. Phys. Lett. 86, 183109 (2005)
B.K. Canfield, S. Kujalal, K. Jefimovs, T. Vallius, J. Turunen, M. Kauranen, J. Opt. A 7, 110 (2005)
C.F. Bohren, D.R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley-Interscience, New York, 1983)
N.I. Zheludev, V. I. Emel’yanov, J. Opt. A 6, 26 (2004)
M.D. McMahon, R. Lopez, H.M. Meyer, L.C. Feldman, R.F. Haglund, Appl. Phys. B 80, 915 (2005)
J. Nappa, G. Revillod, I. Russier-Antoine, E. Benichou, C. Jonin, P.F. Brevet, Phys. Rev. B 71, 165407 (2005)
N. Bloembergen, R.K. Chang, S.S. Jha, C.H. Lee, Phys. Rev. 174, 813 (1968)
W. Lukosz, R.E. Kunz, J. Opt. Soc. Am. 67, 1607 (1977)
W. Lukosz, R.E. Kunz, J. Opt. Soc. Am. 67, 1615 (1977)
H.F. Arnoldus, J. Opt. Soc. Am. A 22, 190 (2005)
H.F. Arnoldus, J.T. Foley, Opt. Commun. 246, 45 (2005)
J. Enderlein, T. Ruckstuhl, S. Seeger, Appl. Opt. 38, 724 (1999)
E. Hecht, Optics (Addison-Wesley, Reading, Massachusetts, 1998)
F. Stietz, J. Bosbach, T. Wenzel, T. Vartanyan, A. Goldmann, F. Träger, Phys. Rev. Lett. 84, 5644 (2000)
T. Vartanyan, J. Bosbach, F. Stietz, F. Träger, Appl. Phys. B 73, 391 (2001)
J. Viereck, F. Stietz, M. Stuke, T. Wenzel, F. Träger, Surf. Sci. 383, 749 (1997)
A. Habenicht, M. Olapinski, F. Burmeister, P. Leiderer, J. Boneberg, Science 309, 2043 (2005)
V. Kotaidis, C. Dahmen, G. von Plessen, F. Springer, A. Plech, J. Chem. Phys. 124, 184702 (2006)
E.G. Gamaly, A.V. Rode, B. Luther-Davies, J. Appl. Phys. 85, 4213 (1999)
E.C. Hao, G.C. Schatz, R.C. Johnson, J.T. Hupp, J. Chem. Phys. 117, 5963 (2002)
R.C. Johnson, J.T. Li, J.T. Hupp, G.C. Schatz, Chem. Phys. Lett. 356, 534 (2002)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
78.67.Bf; 42.65.Ky; 65.80.+n
Rights and permissions
About this article
Cite this article
McMahon, M., Ferrara, D., Bowie, C. et al. Second harmonic generation from resonantly excited arrays of gold nanoparticles. Appl. Phys. B 87, 259–265 (2007). https://doi.org/10.1007/s00340-006-2569-3
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00340-006-2569-3