Abstract
We report here the results of a field campaign in which a portable Fourier transform infrared (FTIR) spectrometer was used to measure gas emissions from Yasur volcano, Vanuatu, in January 2005. By collecting FTIR spectra at a high rate (about 1 Hz), we were able to observe a marked difference in the proportions of SO2 and HCl in emissions released during Strombolian eruptions (SO2/HCl molar ratio up to ∼30 or more) compared with the intervening passive emissions discharged from the magmatic vent (SO2/HCl ∼2). This contrast can be explained by sourcing gas at different depths with respect to levels at which SO2 and HCl exsolve from the melt: deeper volatile exsolution supplies relatively SO2-rich gas responsible for the ephemeral explosions at the top of the conduit; while degassing of shallow magma, depleted in sulfur but rich in chlorine, contributes to the passive emission.
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References
C. Oppenheimer, Volcanic degassing, In: The Crust, Vol. 3, Treatise on Geochemistry, ed. by R.L. Rudnick, H.D. Holland, K.K. Turekian, (Elsevier-Pergamon, Oxford 2003), pp. 123–166
G. Mercalli, I vulcani attivi della terra. Morfologia, dinamismo, prodotti, distribuzione geografica, cause (Hoepli, Milano, 1907)
B. Chouet, N. Hamisevicz, T.R. McGetchin, J. Geophys. Res. 79, 4961 (1974)
A. Weill, G. Brandeis, S. Vergniolle, F. Baudin, J. Bilbille, J. Févre, B. Piron, X. Hill, Geophys. Res. Lett. 19, 2357 (1992)
R. Seyfried, M. Hort, Bull. Volcanol. 60, 627 (1999)
P.W. Francis, C. Oppenheimer, D. Stevenson, Nature 366, 554 (1993)
E.A. Parfitt, J. Volcanol. Geotherm. Res. 134, 77 (2004)
Yu.B. Slezin, J. Volcanol. Geotherm. Res. 122, 7 (2003)
M. Burton, P. Allard, F. Murè, C. Oppenheimer, FTIR remote sensing of fractional magma degassing at Mount Etna, Sicily. In: Volcanic Degassing, ed. by C. Oppenheimer, D.M. Pyle, J. Barclay, (Geological Society, Special publication 213, 2003), pp. 281–293
P. Allard, M. Burton, F. Murè, Nature 433, 407 (2005)
M. Burton, P. Allard, L. Brusca, F. Murè, High resolution spectroscopic analysis of volcanic gas composition during passive and explosive degassing at Stromboli volcano, Italy, paper presented at the Assembly, European Geophysical Society, Nice, France, 25–30 March, 2001
Z. Bacsik, J. Mink, G. Keresztury, Appl. Spectrosc. Rev. 39, 295 (2004)
Z. Bacsik, J. Mink, G. Keresztury, Appl. Spectrosc. Rev. 40, 327 (2005)
K. Notsu, T. Mori, G. Igarashi, Y. Tohjima, H. Wakita, Geochem. J. 27, 361 (1993)
T. Mori, K. Notsu, Y. Tohjima, H. Wakita, Geophys. Res. Lett. 20, 1355 (1993)
P. Francis, A. Maciejewski, C. Oppenheimer, C. Chaffin, T. Caltabiano, Geophys. Res. Lett. 22, 1717 (1995)
C. Oppenheimer, P. Francis, M. Burton, A. Maciejewski, L. Boardman, Appl. Phys. B 67, 505 (1998)
T. Mori, K. Notsu, Geophys. Res. Lett. 24, 2047 (1997)
A. Nabyl, J. Dorel, M. Lardy, New Zeal. J. Geol. Geophys. 40, 549 (1997)
J. Barclay, personal communication (2006)
P. Francis, C. Chaffin, A. Maciejewski, C. Oppenheimer, Geophys. Res. Lett. 23, 249 (1996)
S.P. Love, F. Goff, D. Counce, C. Siebe, H. Delgado, Nature 396, 563 (1998)
T. Mori, M. Sato, Y. Shimoike, K. Notsu, Earth Planets Space 54, 249 (2002)
G.M. Sawyer, C. Oppenheimer, Adv. Fluorine Sci. (2006), unpublished
M.R. Burton, C. Oppenheimer, L.A. Horrocks, P.W. Francis, Geophys. Res. Lett. 28, 843 (2001)
C. Oppenheimer, M. Edmonds, P. Francis, M.R. Burton, Variation in HCl/SO2 gas ratios observed by Fourier transform spectroscopy at Soufrière Hills Volcano, Montserrat. In: The Eruption of Soufrière Hills Volcano, Montserrat, from 1995 to 1999, ed. by T.H. Druitt, P. Kokelaar (Geological Society, London, Memoir, 21, 2002), pp. 621–639
D.J. Edwards, A. Dudhia, Reference Forward Model: high level algorithms definition, ESA document PO-MA-OXF-GS-0004 (1996)
L.S. Rothman, D. Jacquemart, A. Barbe, D.C. Benner, M. Birk, L.R. Brown, M.R. Carleer, C. Chackerian, K. Chance, L.H. Coudert, V. Dana, V.M. Devi, J.M. Flaud, R.R. Gamache, A. Goldman, J.M. Hartmann, K.W. Jucks, A.G. Maki, J.Y. Mandin, S.T. Massie, J. Orphal, A. Perrin, C.P. Rinsland, M.A.H. Smith, J. Tennyson, R.N. Tolchenov, R.A. Toth, J. Vander Auwera, P. Varanasi, G. Wagner, J. Quantum. Spectrosc. Radiat. Transf. 96, 139 (2005)
C.D. Rodgers, J. Geophys. Res. 95, 5587 (1990)
L.A. Horrocks, C. Oppenheimer, M.R. Burton, H.J. Duffell, N.M. Davies, N.A. Martin, W. Bell, J. Geophys. Res. 106, 27, 647 (2001)
E.A. Parfitt, L. Wilson, Geophys. J. Int. 121, 226 (1995)
C. Jaupart, S. Vergniolle, Nature 331, 58 (1988)
S. Vergniolle, C. Jaupart, J. Geophys. Res. 95, 2793 (1990)
R. Seyfried, A. Freundt, J. Geophys. Res. 105, 23, 727 (2000)
S. Vergniolle, M. Boichu, J. Caplan-Auerbach, J. Volcanol. Geotherm. Res. 137, 109 (2004)
M.R. Carroll, J.D. Webster, Rev. Mineral. 30, 231 (1994)
N. Spilliaert, N. Metrich, P. Allard, Geophys. Res. Abstr. 8, 10551 (2006)
P. Francis, M.R. Burton, C. Oppenheimer, Nature 396, 567 (1998)
M. Burton, F. Murè, http://www.ct.ingv.it/Report/RptVg20030107FTIR.pdf (2002)
L. Horrocks, M. Burton, P. Francis, C. Oppenheimer, Geophys. Res. Lett. 26, 3497 (1999)
M.R. Burton, C. Oppenheimer, L.A. Horrocks, P.W. Francis, Geology 28, 915 (2000)
H. Duffell, C. Oppenheimer, D.M. Pyle, B. Galle, A.J.S. McGonigle, M. Burton, J. Volcanol. Geotherm. Res. 126, 327 (2003)
M. Burton H.M. Mader M. Polacci, P. Allard, Eos Trans. AGU 86, Fall Meet. Suppl., Abstract V13G-01 (2005)
H. Shinohara, J.B. Witter, Geophys. Res. Lett. 32, L20308 (2005)
T.P. Fischer, K. Roggensack, P.R. Kyle, Geology 30, 1059 (2002)
M. Edmonds, R.A. Herd, B. Galle, C. Oppenheimer, Bull. Volcanol. 65, 578 (2003)
N. Bobrowski, G. Honninger, B. Galle, U. Platt, Nature 423, 273 (2003)
C. Oppenheimer, P.R. Kyle, V.I. Tsanev, A.J.S. McGonigle, T.A. Mather, D. Sweeney, Atmosph. Environ. 39, 6000 (2005)
C. Oppenheimer, V.I. Tsanev, C.F. Braban, R.A. Cox, J.W. Adams, A. Aiuppa, N. Bobrowski, P. Delmelle, J. Barclay, A.J.S. McGonigle, Geochim. Cosmochim. Acta 70, 2935 (2006)
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07.57.Ty; 91.40.Vg; 91.40.Yt; 91.40.Zz
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Oppenheimer, C., Bani, P., Calkins, J. et al. Rapid FTIR sensing of volcanic gases released by Strombolian explosions at Yasur volcano, Vanuatu. Appl. Phys. B 85, 453–460 (2006). https://doi.org/10.1007/s00340-006-2353-4
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DOI: https://doi.org/10.1007/s00340-006-2353-4