Abstract
ZnO nanorods/g-C3N4 photocatalytic composite was prepared, and its structural and optical properties have been studied. Bulk graphite phase carbon nitride (g-C3N4) was first prepared by a one-step thermal polymerization method, and ZnO nanorods were grown from the ZnO seed particles on the surface of g-C3N4 by a hydrothermal method. The effects of hydrothermal reaction time on the morphology and photocatalytic properties of ZnO nanorods/g-C3N4 composite were investigated. The hydrothermal reaction included two stages. The initial stage was dominated by the rapid deposition of Zn2+ precursor in hydrothermal solution on ZnO seed particles to form ZnO seed layer, and the second stage was the hydrothermal growth of ZnO nanorods from the ZnO seed layer. In the second stage, two processes occurred simultaneously, namely, the dissolution of seed layer and the growth of ZnO nanorods. Hence, the composite prepared with different hydrothermal time shows different photocatalytic degradation mechanism to methyl orange (MO) solution. The photocatalytic performance of the composite sample with the grown time of 2 h is mainly attributed to separation efficiency of photogenerated carriers. For the composite sample with the grown time of 3 h, due to the partial dissolution of seed layer, its photocatalytic performance is mainly attributed to the surface reaction of ZnO nanorods. For the composite samples with the hydrothermal grown time of 4 and 5 h, the dense ZnO nanorods on the surface of g-C3N4 improve the separation efficiency of the photogenerated carriers, and their photocatalytic performance is attributed to both carrier lifetime and surface reaction. As a result of synergy, the sample with the hydrothermal grown time of 3 h shows the best photocatalytic performance in all composite sample.
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References
L. Li, M. Mao, X. She, J. Yi, M. He, L. Pan, Z. Chen, H. Xu, H. Li, Direct Z-scheme photocatalyst for efficient water pollutant degradation: A case study of 2D g-C3N4/BiVO4. Mater. Chem. Phys. 241, 122308 (2020)
J. Yi, H. Li, Y. Gong, X. She, Y. Song, Xu. Yuanguo, J. Deng, S. Yuan, Xu. Hui, H. Li, Phase and interlayer effect of transition metal dichalcogenide cocatalyst toward photocatalytic hydrogen evolution: the case of MoSe2. Appl. Catal. B 243, 330–336 (2019)
H. Heidarpour, M. Padervand, M. Soltanieh, M. Vossoughi, Enhanced decolorization of rhodamine B solution through simultaneous photocatalysis and persulfate activation over Fe/C3N4 photocatalyst. Chem. Eng. Res. Des. 153, 709–720 (2020)
B. Gerislioglu, A. Ahmadivand, J. Adam, Infrared plasmonic photodetectors: the emergence of high photon yield toroidal metadevices. Mater. Today Chem. 14, 100206 (2019)
X. Li, K. Zhang, M. Zhou, K. Yang, S. Yang, X. Ma, Yu. Changlin, Yu. Xie, W. Huang, Q. Fan, A novel approach to synthesize nitrogen-deficient g-c3n4 for the enhanced photocatalytic contaminant degradation and electrocatalytic hydrogen evolution. NANO 15, 2050006 (2020)
V. Kumaravel, S. Mathew, J. Bartlett, S.C. Pillai, Photocatalytic hydrogen production using metal doped TiO2: A review of recent advances. Appl. Catalysis B Environ. 244, 1021–1064 (2019)
R. He, H. Liang, C. Li, J. Bai, Enhanced photocatalytic hydrogen production over Co3O4@g-C3N4 p-n junction adhering on one-dimensional carbon fiber. Coll. Surf. A 586, 124200 (2020)
X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J.M. Carlsson, K. Domen, M. Antonietti, A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nature Mater. 8, 76–80 (2009)
Y. Wang, S. Zhao, Y. Zhang, J. Fang, W. Chen, S. Yuan, Y. Zhou, Facile synthesis of self-assembled g-C3N4 with abundant nitrogen defects for photocatalytic hydrogen evolution. ACS Sustain. Chem. Eng. 6, 10200–10210 (2018)
J. Zhu, P. Xiao, H. Li, S.A. Carabineiro, Graphitic carbon nitride: synthesis, properties, and applications in catalysis. ACS Appl Mater Interfaces 6, 16449–16465 (2014)
J. Jiang, Mu. Zhao, H. Xing, Wu. Qiannan, X. Yue, Y. Lin, Insights into the synergetic effect for enhanced UV/visible-light activated photodegradation activity via Cu-ZnO photocatalyst. Appl. Surf. Sci. 478, 1037–1045 (2019)
Yu. Fucheng, D. Nan, B. Wang, Z. Liu, Y. Li, L. He, X. Tang, J. Zhang, Catalytic properties of the composite of La-doped ZnO nanorods and Ag2CrO4 nanoparticles. Appl. Phys. A 126, 482 (2020)
T. Huang, W. Zhang, S. Pan, L. Shi, J. Zhu, X. Wang, Fu. Yongsheng, General synthesis strategy for hollow porous prismatic graphitic carbon nitride: a high-performance photocatalyst for H2 production and degradation of RhB. J. Mater. Sci. 55, 6037–6050 (2020)
W. Luo, X. Chen, Z. Wei, D. Liu, W. Yao, Y. Zhu. Three-dimensional network structure assembled by g-C3N4 nanorods for improving visible-light photocatalytic performance. Appl. Catalysis B Environ. 255, 117761 (2019)
Y. Si, Z. Sun, L. Huang, M. Chen, Wu. Limin, A “ship-in-a-bottle” strategy to fabricate highly crystallized nanoporous g-C3N4 microspheres under pressurized conditions. J. Mater. Chem. A 7, 8952–8959 (2019)
Z. Zhu, F. Zhou, S. Zhan, Enhanced antifouling property of fluorocarbon resin coating (PEVE) by the modification of g-C3N4/Ag2WO4 composite step-scheme photocatalyst. Appl. Surf. Sci. 506, 144934 (2020)
R. Zhang, S. Niu, X. Zhang, Z. Jiang, J. Zheng, C. Guo, Combination of experimental and theoretical investigation on Ti-doped g-C3N4 with improved photo-catalytic activity. Appl. Surf. Sci. 489, 427–434 (2019)
Y. Cui, H. Wang, C. Yang, M. Li, Y. Zhao, F. Chen, Post-activation of in situ B-F codoped g-C3N4 for enhanced photocatalytic H2 evolution. Appl. Surf. Sci. 441, 621–630 (2018)
Z. Ren, F. Chen, K. Wen, J. Lu. Enhanced photocatalytic activity for tetracyclines degradation with Ag modified g-C3N4 composite under visible light. J. Photochem. Photobiol. A Chem. 389, 112217 (2020)
D. Zhu, S. Liu, M. Chen, J. Zhang, X. Wang, Flower-like-flake Fe3O4/g-C3N4 nanocomposite: facial synthesis, characterization, and enhanced photocatalytic performance. Colloids Surf., A 537, 372–382 (2018)
R. Zhang, K. Huang, H. Wei, D. Wang, Ou. Gang, N. Hussain, Z. Huang, C. Zhang, Wu. Hui, Ultra-low-temperature growth of CdS quantum dots on g-C3N4 nanosheets and their photocatalytic performance. Dalton Trans 47, 1417–1421 (2018)
S. Zuo, Xu. Haiming, W. Liao, X. Yuan, L. Sun, Q. Li, J. Zan, D. Li, D. Xia, Molten-salt synthesis of g-C3N4-Cu2O heterojunctions with highly enhanced photocatalytic performance. Colloids Surf. A 546, 307–315 (2018)
P. Yang, J. Wang, G. Yue, R. Yang, P. Zhao, L. Yang, X. Zhao, D. Astruc. Constructing mesoporous g-C3N4/ZnO nanosheets catalyst for enhanced visible-light driven photocatalytic activity. J. Photochem. Photobiol. A Chem. 388, 112169 (2020)
D.R. Paul, S. Gautam, P. Panchal, S.P. Nehra, P. Choudhary, A. Sharma, ZnO-Modified g-C3N4: a potential photocatalyst for environmental application. ACS Omega 5, 3828–3838 (2020)
W. Liu, M. Wang, C. Xu, S. Chen, Facile synthesis of g-C3N4/ZnO composite with enhanced visible light photooxidation and photoreduction properties. Chem. Eng. J. 209, 386–393 (2012)
S.W. Zhao, M. Zheng, H.L. Sun, S.J. Li, Q.J. Pan, Y.R. Guo, Construction of heterostructured g-C3N4/ZnO/cellulose and its antibacterial activity: experimental and theoretical investigations. Dalton Trans. 49, 3723–3734 (2019)
N. Ning, Y. Tian, J. Zhang, J. Kong, W. Lingchao, L. Zhao, H. Jianhui . Z-scheme 2D/3D g-C3N4@ZnO with enhanced photocatalytic activity for cephalexin oxidation under solar light. Chem. Eng. J. 352, 412–422 (2018)
A. Abdolhoseinzadeh, S. Sheibani, Enhanced photocatalytic performance of Cu2O nano-photocatalyst powder modified by ball milling and ZnO. Adv. Powder Technol. 31, 40–50 (2020)
Z. Wang, Y. Huo, Y. Fan, Wu. Rong, Wu. Hao, F. Wang, Xu. Xiaohong, Facile synthesis of carbon-rich g-C3N4 by copolymerization of urea and tetracyanoethylene for photocatalytic degradation of Orange II. J. Photochem. Photobiol. A 358, 61–69 (2018)
Q. Ma, Yu. Yuan Fang, J.S. Liu, Fu. Xinghua, H. Li, S. Chu, Y. Chen, Facile synthesis of ZnO morphological evolution with tunable growth habits: Achieving superior gas-sensing properties of hemispherical ZnO/Au heterostructures for trimethylamine. Phys. E 106, 180–186 (2018)
N. Abdel Aal, F. Al-Hazmi, A.A. Al-Ghamdi, A.A. Al-Ghamdi, F. El-Tantawy, F. Yakuphanoglu. Novel rapid synthesis of zinc oxide nanotubes via hydrothermal technique and antibacterial properties. Spectrochim. Acta Part A Mol. Biomol. Spectroscopy 135, 871–877 (2015)
X. Chen, R. Shi, Q. Chen, Z. Zhang, W. Jiang, Y. Zhu, T. Zhang, Three-dimensional porous g-C3N4 for highly efficient photocatalytic overall water splitting. Nano Energy 59, 644–650 (2019)
Qi. Zhang, X. Zhang, Facile fabrication of phosphorus-doped g-C3N4 exhibiting enhanced visible light photocatalytic degradation performance toward textile dye. Solid State Sci. 89, 150–155 (2019)
S. Prabhu, M. Pudukudy, S. Harish, M. Navaneethan, S. Sohila, K. Murugesan, R. Ramesh, Facile construction of djembe-like ZnO and its composite with g-C3N4 as a visible-light-driven heterojunction photocatalyst for the degradation of organic dyes. Mater. Sci. Semiconduct. Process. 106, 104754 (2020)
K.C. Verma, R.K. Kotnala, Oxygen vacancy induced by La and Fe into ZnO nanoparticles to modify ferromagnetic ordering. J. Solid State Chem. 237, 211–218 (2016)
Q. Zhong, H. Lan, M. Zhang, H. Zhu, Bu. Ming, Preparation of heterostructure g-C3N4/ZnO nanorods for high photocatalytic activity on different pollutants (MB, RhB, Cr(VI) and eosin). Ceram. Int. 46, 12192–12199 (2020)
S. Ma, S. Zhan, Y. Xia, P. Wang, Q. Hou, Q. Zhou, Enhanced photocatalytic bactericidal performance and mechanism with novel Ag/ZnO/g-C3N4 composite under visible light. Catal. Today 330, 179–188 (2019)
K. Ravichandran, E. Sindhuja, Fabrication of cost effective g-C3N4 + Ag activated ZnO photocatalyst in thin film form for enhanced visible light responsive dye degradation. Mater. Chem. Phys. 221, 203–215 (2019)
X. Lia, M. Li, J. Yang, X. Li, Hu. Tingjing, J. Wang, Y. Sui, Wu. Xingtong, L. Kong, Synergistic effect of efficient adsorption g-C3N4/ZnO composite for photocatalytic property. J. Phys. Chem. Solids 75, 441–446 (2014)
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This work was financially supported by the Entrustment of Scientific and Technological Projects by Chinese Enterprises and Institutions (LZSN-KJ-002, 2018040-G, ky2019047) and the Hubei Provincial Department of Education (B2018058).
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Yu, F., Li, Y., Liu, Z. et al. Preparation and photocatalytic properties of ZnO nanorods/g-C3N4 composite. Appl. Phys. A 127, 818 (2021). https://doi.org/10.1007/s00339-021-04964-1
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DOI: https://doi.org/10.1007/s00339-021-04964-1