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Optical, phonon and fluorescence properties of PVA-GO-ZnO free standing films

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Abstract

We report optical properties of ZnO nanorods dispersed graphene oxide (GO)—polyvinyl alcohol (PVA) free standing composite films (PVA-GO-ZnO) which are prepared by ex-situ method. It has been found that the loading of ZnO nanorods altered the influence of GO on PVA matrix. Optical absorption results show the band related to π → π* transitions of aromatic C–C bonds in GO, which is shifted to higher wavelength side when loading ZnO in GO-PVA. Raman spectral studies show that the incorporation of ZnO in GO-PVA film decreases the interaction of GO with hydroxyl groups in PVA matrix. Steady state and time resolved photoluminescence show the suppression of PVA luminescence and decay time due to interactions with GO, which is recovered after the loading of ZnO in the PVA-GO.

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References

  1. P. Johari, V.B. Shenoy, ACS Nano 5(9), 7640–7647 (2011)

    Article  Google Scholar 

  2. W. Choi, J. Lee, Graphene: synthesis and applications (CRC Press, Boca Raton, 2011)

    Google Scholar 

  3. L.A. Agapito, H.P. Cheng, J. Phys. Chem. C 111(38), 14266–14273 (2007)

    Article  Google Scholar 

  4. E. Goki, G. Fanchini, G. Chhowalla, Nat. Nanotechnol. 3, 270–274 (2008)

    Article  Google Scholar 

  5. S. Li, A.N. Aphale, I.G. Macwan, P.K. Patra, W.K. Gonzalez, J. Miksovska, M. Leblanc, A.C.S. Appl, Mater. Interfaces 4, 7069–7075 (2012)

    Article  Google Scholar 

  6. Y. Ni, F. Zhang, F. Kokot Anal. Chim. Acta 769, 40–48 (2013)

    Article  Google Scholar 

  7. T. Zhou, X. Zhou, D. Xing, Biomaterials 35, 4185–4194 (2014)

    Article  Google Scholar 

  8. I.K. Moon, J.I. Kim, H. Lee, K. Hur, W.C. Kim, H. Lee, Sci. Rep. 3, 1112 (2003)

    Article  Google Scholar 

  9. C. Selvaraj, S. Kumar, N. Munichandraiah, L.G. Scanlon, J. Electrochem. Soc. 161(4), A554–A560 (2014)

    Article  Google Scholar 

  10. L. Zhang, Z.Y. Zhang, R.P. Liang, Y.H. Li, J.D. Qiu, Anal. Chem. 86, 4423–4430 (2014)

    Article  Google Scholar 

  11. A. Kundu, S. Nandi, R.K. Layek, A.K. Nandi, A.C.S. Appl, Mater. Interfaces 5, 7392–7399 (2013)

    Article  Google Scholar 

  12. S. Ram, T.K. Mandal, Chem. Phys. 303, 121 (2004)

    Article  Google Scholar 

  13. B. Karthikeyan, R. Udayabhaskar, S. Hariharan, Appl. Phys. Lett. 109, 021904 (2016)

    Article  ADS  Google Scholar 

  14. M. Aslam, M.A. Kalyar, Z.A. Raza, Polym. Bull. 76, 73 (2019). https://doi.org/10.1007/s00289-018-2367-1

    Article  Google Scholar 

  15. S. Gahlot, V. Kulshrestha, A.C.S. Appl, Mater. Interfaces 7, 264–272 (2015)

    Article  Google Scholar 

  16. T. Cheng-an, Z. Hao, W. Fang, Z. Hui, Z. Xiaorong, W. Jianfang, Polym. Polym. Compos. 25, 11–16 (2017)

    Google Scholar 

  17. J. Ma, Y. Li, X. Yin, Y. Xu, J. Yue, J. Bao, T. Zhou, RSC Adv. 6, 49448–49458 (2016)

    Article  Google Scholar 

  18. J. Lee, D. Bhattacharya, A.J. Easteal, J.B. Metson, Curr. Appl. Phys. 8, 42 (2008)

    Article  ADS  Google Scholar 

  19. X.M. Sui, C.L. Shao, Y.C. Liu, Appl. Phys. Lett. 87, 113115 (2005)

    Article  ADS  Google Scholar 

  20. M. Xiong, G. Gu, B. You, L. Wu, J. Appl. Polym. Sci. 90, 1923 (2003)

    Article  Google Scholar 

  21. K.S. Hemalatha, K. Rukmani, N. Suriyamurthy, B.M. Nagabhushana, Mater. Res. Bull. 51, 438–446 (2014)

    Article  Google Scholar 

  22. R. Kandulna, R.B. Choudhary, Polym. Bull. 75(7), 3089–3107 (2017)

    Article  Google Scholar 

  23. S. Abed, M.S. Aida, K. Bouchouit, A. Arbaoui, K. Iliopoulos, B. Sahraoui, Opt. Mater. 33, 968–972 (2011)

    Article  ADS  Google Scholar 

  24. B. Kulyk, V. Kapustianyk, V. Tsybulskyy, O. Krupkab, B. Sahraoui, J. Alloy Compd. 502, 24–27 (2010)

    Article  Google Scholar 

  25. V. Kapustianyk, B. Turko, A. Kostruba, Z. Sofiani, B. Derkowska, S. Dabos-Seignon, B. Barwin´ski, Y. Eliyashevskyi, B. Sahraoui, Opt. Commun. 269, 346–350 (2007)

    Article  ADS  Google Scholar 

  26. Z. Sofiani, B. Sahraoui, M. Addou, R. Adhiri, M.A. Lamrani, L. Dghoughi, N. Fellahi, B. Derkowska, W. Bala, J. Appl. Phys. 101, 063104 (2007)

    Article  ADS  Google Scholar 

  27. R. Udayabhaskar, B. Karthikeyan, J. Appl. Phys. 114, 033912 (2013)

    Article  Google Scholar 

  28. G. Attia, M.F.H.A. El-kader, Int. J. Electrochem. Sci. 8, 5672–5687 (2013)

    Google Scholar 

  29. Z. Xu, H. Gao, H. Guoxin, Carbon 49, 4731–4738 (2011)

    Article  Google Scholar 

  30. Y. Liu, C.Y. Liu, Y. Liu, Appl. Surf. Sci. 257, 5513–5518 (2011)

    Article  ADS  Google Scholar 

  31. K.E. Peiponen, E.M. Vartiainen, Phy. Rev. B 44, 15 (1991)

    Article  Google Scholar 

  32. K.E. Peiponen, J.J. Saarinen, Rep. Prog. Phys. 72, 056401 (2009)

    Article  ADS  Google Scholar 

  33. W. Xu, N. Mao, J. Zhang, Small 9, 1206–1224 (2013)

    Article  Google Scholar 

  34. T. Zhou, F. Chen, K. Liu, H. Deng, Q. Zhang, J. Feng, Q. Fu, Nanotechnology 22, 045704 (2011)

    Article  ADS  Google Scholar 

  35. M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, L.G. Can-cado, A. Jorio, R. Saito, Phys. Chem. Chem. Phys. 9, 1276–1290 (2007)

    Article  Google Scholar 

  36. J. Li, C.Y. Liu, Eur. J. Inorg. Chem. 8, 1244–1248 (2010)

    Article  ADS  Google Scholar 

  37. K.K. Dey, P. Kumar, R.R. Yadav, A. Dhar, A.K. Srivastava, RSC Adv. 3444, 10123 (2014)

    Article  Google Scholar 

  38. D.R. Dreyer, S. Park, W. Christopher, R.S. Bielawski, C. Ruoff, Soc. Rev. 39, 228–240 (2010)

  39. C. Chen, H. He, Y. Lu, K. Wu, Z. Ye, ACS Appl. Mater. Interfaces 5(13), 6354–6359 (2013)

    Article  Google Scholar 

  40. S.S. Mousavi, B. Sajad, M.H. Majlesara, Mater. Des. 162, 249–255 (2019)

    Article  Google Scholar 

Download references

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Karthikeyan, B. Optical, phonon and fluorescence properties of PVA-GO-ZnO free standing films. Appl. Phys. A 125, 847 (2019). https://doi.org/10.1007/s00339-019-3136-1

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