Skip to main content
Log in

Comparative study of radiation defect dynamics in 3C-SiC by X-ray diffraction, Raman scattering, and ion channeling

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

At moderately elevated temperatures, radiation defects in SiC exhibit pronounced dynamic annealing, which remains poorly understood. Here, we study 3C-SiC bombarded at 100 \(^{\circ }\)C with pulsed beams of 500 keV Ar ions. Radiation damage is monitored by a combination of X-ray diffraction, Raman scattering, and ion channeling. Similar damage buildup behavior but with different defect relaxation time constants, ranging from \(\sim 1\) to \(\sim 6\) ms, is observed for the different types of lattice defects probed by these techniques. A correlation between relaxation times and the nature of the defects is proposed. These results reveal additional complexity of radiation defect dynamics in SiC and demonstrate that results of different defect characterization techniques are needed for a better understanding of dynamic annealing processes in solids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. A. Fissel, Artificially layered heteropolytypic structures based on SiC polytypes: molecular beam epitaxy, characterization and properties. Phys. Rep. 379, 149 (2003)

    Article  ADS  Google Scholar 

  2. L.L. Snead, T. Nozawa, Y. Katoha, T.-S. Byun, S. Kondo, D.A. Petti, Handbook of SiC properties for fuel performance modeling. J. Nucl. Mater. 371, 329 (2007)

    Article  ADS  Google Scholar 

  3. L. Jamison, K. Sridharan, S. Shannon, I. Szlufarska, Temperature and irradiation species dependence of radiation response of nanocrystalline silicon carbide. J. Mater. Res. 29, 2871 (2014)

    Article  ADS  Google Scholar 

  4. H. Inui, H. Mori, A. Suzuki, H. Fujita, Electron-irradiation-induced crystalline-to-amorphous transition in \(\beta\)-SiC single crystals. Philos. Mag. B 65, 1 (1992)

    Article  Google Scholar 

  5. W.J. Weber, N. Yu, L.M. Wang, Irradiation-induced amorphization in \(\beta\)-SiC. J. Nucl. Mater. 253, 53 (1998)

    Article  Google Scholar 

  6. J.B. Wallace, L.B. Bayu Aji, L. Shao, S.O. Kucheyev, Time constant of defect relaxation in ion-irradiated 3C-SiC. Appl. Phys. Lett. 106, 202102 (2015)

    Article  ADS  Google Scholar 

  7. J.B. Wallace, L.B. Bayu Aji, T.T. Li, L. Shao, S.O. Kucheyev, Damage buildup in Ar-ion-irradiated 3C-SiC at elevated temperatures. J. Appl. Phys. 118, 105705 (2015)

    Article  ADS  Google Scholar 

  8. L.B. Bayu Aji, J.B. Wallace, S.O. Kucheyev, Effects of collision cascade density on radiation defect dynamics in SiC. Sci. Rep. 7, 44703 (2017)

    Article  ADS  Google Scholar 

  9. L.B. Bayu Aji, T.T. Li, J.B. Wallace, S.O. Kucheyev, Dose-rate dependence of damage buildup in 3C-SiC. J. Appl. Phys. 121, 235106 (2017)

    Article  ADS  Google Scholar 

  10. A. Boulle, A. Debelle, J.B. Wallace, L.B. Bayu Aji, S.O. Kucheyev, The amorphization of 3C-SiC irradiated at moderately elevated temperatures as revealed by X-ray diffraction. Acta Mater. 140, 250 (2017)

    Article  Google Scholar 

  11. M.T. Myers, S. Charnvanichborikarn, L. Shao, S.O. Kucheyev, Pulsed ion beam measurement of the time constant of dynamic annealing in Si. Phys. Rev. Lett. 109, 095502 (2012)

    Article  ADS  Google Scholar 

  12. J.B. Wallace, S. Charnvanichborikarn, L.B. Bayu Aji, M.T. Myers, L. Shao, S.O. Kucheyev, Radiation defect dynamics in Si at room temperature studied by pulsed ion beams. J. Appl. Phys. 118, 135709 (2015)

    Article  ADS  Google Scholar 

  13. L.C. Feldman, J.W. Mayer, S.T. Picraux, Materials Analysis by Ion Channeling (Academic Press, New York, 1982)

    Google Scholar 

  14. J.F. Ziegler, M.D. Ziegler, J.P. Biersack, SRIM—the stopping and range of ions in matter. Nucl. Instr. Methods B 268, 1818 (2010)

    Article  ADS  Google Scholar 

  15. M. Souilah, A. Boulle, A. Debelle, RaDMaX: a graphical program for the determination of strain and damage profiles in irradiated crystals. J. Appl. Cryst. 49, 311 (2016)

    Article  Google Scholar 

  16. A. Debelle, A. Boulle, A. Chartier, F. Gao, W.J. Weber, Interplay between atomic disorder, lattice swelling, and defect energy in ion-irradiation-induced amorphization of SiC. Phys. Rev. B 90, 174112 (2014)

    Article  ADS  Google Scholar 

  17. J.H. Parker Jr., D.W. Feldman, M. Ashkin, Raman scattering by silicon and germanium. Phy. Rev. 155, 712 (1967)

    Article  ADS  Google Scholar 

  18. G. Roma, Linear response calculation of first order Raman spectra of point defects in silicon carbide. Phys. Stat. Sol. A 213, 2995 (2016)

    Article  ADS  Google Scholar 

  19. H. Harima, Raman scattering characterization on SiC. Microelectron. Eng. 83, 126 (2006)

    Article  Google Scholar 

  20. J. Huguet-Garcia, A. Jankowiak, S. Miro, R. Podor, E. Meslin, L. Thomé, Y. Serruys, J.-M. Costantini, Characterization of the ion-amorphization process and thermal annealing effects on third generation SiC fibers and 6H-SiC. EPJ Nuclear Sci. Technol. 1, 8 (2015)

    Article  Google Scholar 

  21. S. Sorieul, J.-M. Costantini, L. Gosmain, L. Thomé, J.-J. Grob, Raman spectroscopy study of heavy-ion-irradiated \(\alpha\)-SiC. J. Phys. Condens. Matter 18, 5235 (2006)

    Article  Google Scholar 

  22. K.A. Levenberg, A method for the solution of certain problems in least squares. Q. Appl. Math. 2, 164 (1944)

    Article  MathSciNet  Google Scholar 

  23. A. Boulle, A. Debelle, Statistical nature of atomic disorder in irradiated crystals. Phys. Rev. Lett. 116, 245501 (2016)

    Article  ADS  Google Scholar 

  24. J.B. Wallace, L.B. Bayu Aji, L. Shao, S.O. Kucheyev, Fractal analysis of collision cascades in pulsed-ion-beam-irradiated solids. Sci. Rep. 7, 17574 (2017)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

Work at LLNL was performed under the auspices of the U.S. DOE by LLNL under Contract DE-AC52-07NA27344. J.B.W acknowledges the LGSP for funding.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. B. Bayu Aji.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bayu Aji, L.B., Stavrou, E., Wallace, J.B. et al. Comparative study of radiation defect dynamics in 3C-SiC by X-ray diffraction, Raman scattering, and ion channeling. Appl. Phys. A 125, 28 (2019). https://doi.org/10.1007/s00339-018-2325-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00339-018-2325-7

Navigation