Abstract
The chemical precipitation method is followed for the synthesis of Al-doped ZnO nanoparticles (NPs) with varying doping concentrations (0, 0.02, 0.04, 0.06, 0.08, and 0.10 M). A single hexagonal crystalline phase of wurtzite structure has been confirmed for all the samples by X-ray diffraction. Crystalline size and microstrain of the un-doped and doped ZnO (NPs) is determined by the Williamson–Hall (W–H) analysis. The optical properties like band gap and Urbach energy are found out by the UV–visible spectroscopy. The functional bonds are detailed by Fourier transmission infrared spectroscopy. The dielectric properties have been shown by doped sample due to hopping mechanisms as compared to the undoped. The loss factor (tanδ) follows an inverse direction as correspond to frequency due to the presence of dielectric dispersion.
Similar content being viewed by others
References
Y. Tian, S.R. Bakaul, T. Wu, Nanoscale 4, 1529–1540 (2012)
M. Bibes, A. Barthelemy, IEEE Trans. on Electron. Devices 54, 1003–1023 (2007)
R.K. Gupta, K. Ghosh, P.K. Kahol, Mat. Lett. 64, 2022–2024 (2010)
P. Sharma, A. Gupta, F.J. Owens, A. Inoue, K.V. Rao, J. Magn. Magn. Mat. 282, 115–121 (2004)
S.A. Wolf, D.D. Awschalom, R.A. Buhrman, J.M. Daughton, S. Von Molnar, M.L. Roukes, D.M. Treger, Science 294, 1488–1495 (2001)
A.A. Bergh, P.J. Dean, Light-Emitting Diodes (Oxford, Clarendon Press, 1976), p. 598
X. Duan, Y. Huang, Y. Cui, J. Wang, C.M. Lieber, Nature 409, 66 (2001)
Y. Du, S. Guo, Nanoscale 8, 2532–2543 (2016)
S.M. Komirenko, K.W. Kim, V.A. Kochelap, J.M. Zavada, Appl. Phys. Lett. 81, 4616–4618 (2002)
K.S. Kim, Y. Zhao, H. Jang, S.Y. Lee, J.M. Kim, K.S. Kim, B.H. Hong, Nature 457, 706 (2009)
F. Shangfeng, G. Weimin, L. Jian, C. Yunfa, L. Yun, Effect of Ga3+ doping on the electrical conductivity of nano-sized zinc oxide powders (2006)
E. Pál, I. Dékány, Coll. Surf. A Physicochem. Eng. Asp. 318, 141–150 (2008)
C.C. Wang, J.Y. Ying, Chem. Mater. 11, 3113–3120 (1999)
R. Yousefi, J. Beheshtian, S.M. Seyed-Talebi, H.R. Azimi, F. Jamali-Sheini, Chem. Asian J. 13, 194–203 (2018)
A. Kharatzadeh, F. Jamali-Sheini, R. Yousefi, Mater. Des. 107, 47–55 (2016)
R. Sáaedi, Yousefi, J. Appl. Phys. 122, 224505 (2017)
Y.C. Kong, D.P. Yu, B. Zhang, W. Fang, S.Q. Feng, Appl. Phys. Lett. 78, 407–409 (2001)
X. Zhang, Y. Chen, S. Zhang, C. Qiu, Sep. Purif. Tech. 172, 236–241 (2017)
J. Li, J. Xu, Q. Xu, G. Fang, J. Alloys Compd. 542, 151–156 (2012)
A.K. Zak, W.A. Majid, M.E. Abrishami, R. Yousefi, Solid State Sci. 13, 251–256 (2011)
L. Xu, Y.L. Hu, C. Pelligra, C.H. Chen, L. Jin, H. Huang, S.L. Suib, Chem. Mat. 21, 2875–2885 (2009)
R. Mahdavi, S.S.A. Talesh, Adv. Powder Technol. 28, 1418–1425 (2017)
E. Sernelius, K.F. Berggren, Z.C. Jin, I. Hamberg, C.G. Granqvist, Phys. Rev. B 37, 10244 (1988)
J.D. Wang, J.K. Liu, Q. Tong, Y. Lu, X.H. Yang, Ind. Eng. Chem. Res. 53, 2229–2237 (2014)
M. Ahmad, E. Ahmed, Y. Zhang, N.R. Khalid, J. Xu, M. Ullah, Z. Hong, Curr. Appl. Phy. 13, 697–704 (2013)
K. Saravana kumar, K. Ravi chandran, J. Mat. Sci. Mat. Electron. 23, 1462–1469 (2012)
A.A.A. Ahmed, Z.A. Talib, M.Z. bin Hussein, A. Zakaria, J. Solid State Chem. 191, 271–278 (2012)
N. Bouropoulos, G.C. Psarras, N. Moustakas, A. Chrissanthopoulos, S. Baskoutas, Phys. Status Solidi (a) 205, 2033–2037 (2008)
H.W. Lee, S.P. Lau, Y.G. Wang, K.Y. Tse, H.H. Hng, B.K. Tay, J. Cryst. Growth 268, 596–601 (2004)
R.B.H. Tahar, J. Eur. Ceram Soc. 25, 3301–3306 (2005)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sharma, N., Kumar, S. & Sharma, V. Structural and dielectric properties of Al x Zn1−xO (x = 0, 0.02, 0.04, 0.06, 0.08 and 0.10) nanoparticles. Appl. Phys. A 124, 373 (2018). https://doi.org/10.1007/s00339-018-1779-y
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-018-1779-y