Abstract
Semi-organic nonlinear optical (NLO) 2-amino-5-nitropyridinium bromide (2A5NPBr) single crystals have been grown by slow evaporation solution technique (SEST) with the growth period of 60 days. The single-crystal XRD analysis confirms the unit cell parameters of the grown crystal. The crystallinity of grown 2A5NPBr was analyzed by powder X-ray diffraction (PXRD) measurement. The presence of functional groups of 2A5NPBr crystal was confirmed by Fourier transform infrared (FTIR) spectrum analysis. The optical transmittance of the grown crystal was analyzed by UV–Vis–NIR analysis. It shows good transparency in the visible and NIR region and it is favorable for nonlinear optical (NLO) device applications. The chemical etching study was carried out and it reveals that the grown crystal has less dislocation density. The photoconductivity study reveals that the grown crystal possesses positive photoconductive nature. The thermal stability of the crystal has been investigated by thermogravimetric (TG) and differential thermal analysis (DTA). The dielectric constant and dielectric loss as a function of frequency were measured. The electronic polarizability (α) of 2A5NPBr molecule has been calculated theoretically by different ways such as Penn analysis, Clausius–Mossotti relation, Lorentz–Lorenz equation, optical bandgap, and coupled dipole method (CDM). The obtained values of electronic polarizability (α) are in good agreement with each other. Laser damage threshold (LDT) of 2A5NPBr crystal has been measured using Nd:YAG laser with the wavelength of 1064 nm. Third-order nonlinear optical property of the grown crystal was studied by Z-scan technique using He–Ne laser of wavelength 632.8 nm.
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References
L. Tutt, T. Boggess, A review of optical limiting mechanisms and devices using organics, fullerenes, semiconductors and other materials. Prog. Quantum Electron. 17, 299–338 (1993)
DZ Chemla (Ed), Nonlinear optical properties of organic molecules and crystals, 1st edn., (Academic Press, Orlando, 1987)
C. Aakeröy, A. Beatty, M. Nieuwenhuyzen, M. Zou, A structural study of 2-amino-5-nitropyridine and 2-amino-3-nitropyridine: intermolecular forces and polymorphism. J. Mater. Chem. 8, 1385–1389 (1998)
G. Anandha babu, P. Ramasamy, A. Chandramohan, Studies on the synthesis, structure, growth and physical properties of an organic NLO crystal: 2-amino-5-nitropyridinium phenolsulfonate. Mater. Res. Bull. 46, 2247–2251 (2011)
G. Anandha Babu, P. Ramasamy, J. Philip, Studies on the growth and physical properties of nonlinear optical crystal: 2-amino-5-nitropyridinium-toluenesulfonate. Mater. Res. Bull. 46, 631–634 (2011)
K. Senthil, S. Kalainathan, F. Hamada, Y. Kondo, Bulk crystal growth and nonlinear optical characterization of a stilbazolium derivative crystal: 4-[2-(3,4-dimethoxyphenyl)ethenyl]-l methylpyridinium tetraphenylborate (DSTPB) for NLO device fabrication. RSC Adv. 5, 79298–79308 (2015)
X. Wang, H. Fang, Q. Ren, J. Sun, T. Li, G. Zhang et al., Preparation, spectrographic characterization, thermal, second and third order nonlinear optical properties of 4,5-bis(foroylsulfanyl)-1,3-dithiole-2-thione. Laser Phys. 19, 1858–1866 (2009)
J. Pécaut, J. Lévy, R. Masse, Structural evidence in 2-amino-5-nitropyridinium halides (Cl–, Br–) of herringbone motifs favourable to efficient quadratic non-linear optical properties. J. Mater. Chem. 3, 999–1003 (1993)
S. Dhanuskodi, A. Pricilla Jeyakumari, S. Manivannan, Semiorganic NLO material for short-wavelength generation 2-amino-5-nitropyridinium bromide. J. Cryst. Growth 282, 72–78 (2005)
C. Indumathi, SAC Raj, Optical studies of polymorphic 2-amino-5-nitropyridinium bromide., Int. J. ChemTech Res., 6, 1611–1613 ISSN: 0974–4290. (2014)
W. Kaminsky, From CIF to virtual morphology using the WinXMorphprogram. J. Appl. Crystallogr. 40, 382–385 (2007)
A. Ibanez, J. Levy, C. Mouget, E. Prieur, Crystal growth of a promising nonlinear optical material: 2-amino-5-nitropyridinium chloride. J. Solid State Chem. 129, 22–29 (1997)
J. Tauc, R. Grigorovici, A. Vancu, Optical properties and electronic structure of amorphous germanium. Phys. Status Solidi (B) 15, 627–637 (1966)
A. Jeyakumari, S. Manivannan, S. Dhanuskodi, Spectral and optical studies of 2-amino-5-nitropyridinium dihydrogen phosphate: a semiorganic nonlinear optical material., Spectrochim. Acta Part A Mol. Biomol. Spectr., 67, 83–86 (2017)
T. Chen, Z. Sun, C. Song, Y. Ge, J. Luo, W. Lin et al., Bulk crystal growth and optical and thermal properties of the nonlinear optical crystall-histidinium-4-nitrophenolate 4-nitrophenol (LHPP). Cryst. Growth Des. 12, 2673–2678 (2012)
V. Sivasubramani, M. Anis, S. Hussaini, G. Muley, M. Senthil Pandian, P. Ramasamy, Bulk growth of organic non-linear optical (NLO) l-arginine 4-nitrophenolate 4-nitrophenol dihydrate (LAPP) single crystals by Sankaranarayanan–Ramasamy (SR) method. Mater. Res. Innov. 21, 426–433 (2017)
M. Mahadevan, P. Anandan, K. Ramachandran, M. Arivanandhan, Y. Hayakawa, Studies on the growth aspects and characterization of sodium para-nitro phenolate single crystals for nonlinear optical applications. Optik Int. J. Light Electron Opt. 125, 5515–5518 (2017)
T. Chen, Z. Sun, L. Li, S. Wang, Y. Wang, J. Luo et al., Growth and characterization of a nonlinear optical crystal-2,6-diaminopyridinium 4-nitrophenolate 4-nitrophenol (DAPNP). J Cryst. Growth 338, 157–161 (2012)
M. Kumar, S. Sudhahar, G. Bhagavannarayana, R. Kumar, Crystal growth, structural and optical properties of an organic ion-complex crystal: 4-N,N-dimethylamino-4′-N′-methylstilbazolium iodide. Optik Int. J. Light Electron Opt. 125, 5641–5646 (2017)
A. Gill, S. Kalainathan, G. Bhagavannarayana, Organic nonlinear optical crystal 4-hydroxy-N-methyl 4-stilbazolium besylate synthesis and characterization. Mater. Lett. 64, 1989–1991 (2017)
A. Senthil, P. Ramasamy, Investigation on the SR method growth, etching, birefringence, laser damage threshold and thermal characterization of strontium bis (hydrogen l-malate) hexahydrate single crystal. J. Cryst. Growth 401, 200–204 (2014)
K Sangwal Etching of crystals: theory, experiment and application, 1st edn., (North Holland Physics Publishing, Amsterdam, 1987)
N Joshi Photoconductivity, 1st edn., (Marcel Dekker, New York, 1990)
RH Bube, Photoconductivity of solids, 1st edn., (Wiley Inter Science, New York, 1981)
B. Boaz, S. Navis Priya, J. Linet, P. Deva Prasath, S. Das, Photoconductivity and dielectric studies on NLO active NPNa and NPLi single crystals. Opt. Mater. 29, 827–832 (2007)
D. Xue, K. Kitamura, Dielectric characterization of the defect concentration in lithium niobate single crystals. Solid State Commun. 122, 537–541 (2002)
JD Jackson, Classical electrodynamics, 49th edn., P 321, (Wiley Eastern, New Delhi, 1978)
D. Penn, Wave-number-dependent dielectric function of semiconductors. Phys. Rev. 128, 2093–2097 (1962)
C. Balarew, R. Duhlev, Application of the hard and soft acids and bases concept to explain ligand coordination in double salt structures. J. Solid State Chem. 55, 1–6 (1984)
P.V. Rysselberghe, Remarks concerning the Clausius-Mossotti Law. J. Phys. Chem. 36, 1152–1155 (1932)
M. Born, E. Wolf, 2nd edn., (Osnovy optiki, Moscow, 1973)
M. Renne, B. Nijboer, Microscopic derivation of macroscopic Van der Waals forces. Chem. Phys. Lett. 1, 317–320 (1967)
B. Nijboer, M. Renne, Microscopic derivation of macroscopic van der waals forces. Chem. Phys. Lett. 2, 35–38 (1968)
P. Karuppasamy, V. Sivasubramani, M. Pandian, P. Ramasamy, Growth and characterization of semi-organic third order nonlinear optical (NLO) potassium 3,5-dinitrobenzoate (KDNB) single crystals. RSC Adv. 6, 109105–109123 (2016)
K. Nivetha, S. Kalainathan, M. Yamada, Y. Kondo, F. Hamada, Investigation on the growth, structural, HOMO–LUMO and optical studies of 1-ethyl-2-[2-(4-hydroxy-phenyl)-vinyl]-pyridinium iodide (HSPI)-a new stilbazolium derivative for third-order NLO applications. RSC Adv. 6, 35977–35990 (2016)
K. Chauhan, S. Arora, Diamagnetic and photoabsorption characterisation of gel-grown cadmium oxalate single crystals. Cryst. Res. Technol. 44, 189–196 (2009)
P. Vasudevan, S. Sankar, S. Gokul Raj, Studies on second harmonic generation efficiency of organic material l-arginine maleate dihydrate. Optik Int. J. Light Electron Opt. 124, 4155–4158 (2013)
K. Senthil, S. Kalainathan, A. Kumar, P. Aravindan, Investigation of synthesis, crystal structure and third-order NLO properties of a new stilbazolium derivative crystal: a promising material for nonlinear optical devices. RSC Adv. 4, 56112–56127 (2014)
N. Boling, M. Crisp, G. Dubé, Laser induced surface damage, Appl. Opt. 12, 650–660 (1973)
D. Joseph Daniel, P. Ramasamy, Studies on semi-organic non linear optical single crystal: Lithium formate monohydrate (HCO2Li⋅H2O). Opt. Mater. 36, 971–976 (2014)
K. Rajesh, P. Kumar, Structural, Linear, and Nonlinear Optical and Mechanical Properties of New Organic L-Serine Crystal., J. Mater., 1–5 (2014) (2014)
N. Vijayan, G. Bhagavannarayana, R. Ramesh Babu, R. Gopalakrishnan, K. Maurya, P. Ramasamy, A comparative study on solution- and Bridgman-Grown single crystals of benzimidazole by high-resolution X-ray diffractometry, Fourier transform infrared, microhardness, laser damage threshold, and second-harmonic generation measurements. Cryst. Growth Des. 6, 1542–1546 (2006)
S. Martin Britto Dhas, M. Suresh, G. Bhagavannarayana, S. Natarajan, Growth and characterization of l-Tartaric acid, an NLO material. J. Cryst. Growth 309, 48–52 (2007)
X. Liu, X. Wang, X. Yin, S. Liu, W. He, L. Zhu et al., Bulk growth and physical properties of diguanidinium phosphate monohydrate (G2HP) as a multi-functional crystal. Crystengcomm 16, 930–938 (2014)
E. Van Stryland, H. Vanherzeele, M. Woodall, M. Soileau, A. Smirl, S. Guha et al., Two photon absorption, nonlinear refraction, and optical limiting in semiconductors. Opt. Eng. 24, 613–623 (1985)
C. Mendonca, D. Correa, F. Marlow, T. Voss, P. Tayalia, E. Mazur, Three-dimensional fabrication of optically active microstructures containing an electroluminescent polymer., Appl. Phys. Lett., 95, 113309 (1–3) (2009)
K. DeLong, K. Rochford, G. Stegeman, Effect of two-photon absorption on all-optical guided-wave devices. Appl. Phys. Lett. 55, 1822–1823 (2017)
M. Sheik-Bahae, A. Said, T. Wei, D. Hagan, E. Van Stryland, Sensitive measurement of optical nonlinearities using a single beam. IEEE J. Quantum Electron. 26, 760–769 (1990)
S. Shettigar, G. Umesh, K. Chandrasekharan, B. Kalluraya, Third order nonlinear optical properties and two photon absorption in newly synthesized phenyl sydnone doped polymer. Synth. Met. 157, 142–146 (2007)
M. Zhao, B. Singh, P. Prasad, A systematic study of polarizability and microscopic third-order optical nonlinearity in thiophene oligomers. J. Chem. Phys. 89, 5535–5541 (1988)
R. Jauhar, S. Kalainathan, P. Murugakoothan, Three dimensional organic framework of 2-amino 4, 6 dimethoxypyrimidine p-toluenesulfonic acid monohydrate: synthesis, single crystal growth and its properties. J. Cryst. Growth 424, 42–48 (2015)
M. Nirosha, S. Kalainathan, S. Sarveswari, V. Vijayakumar, A. Srikanth, Growth, spectral, optical, thermal, surface analysis and third order nonlinear optical properties of an organic single crystal: 1-(2-Methyl-6-nitro-4-phenyl-3-quinolyl) ethanone, Spectrochim. Acta Part A Mol. Biomol. Spectr., 137, (2015) pp. 23–28
I. Bincy, R. Gopalakrishnan, Studies on synthesis, growth and characterization of a novel third order nonlinear optical 4-dimethylaminopyridinium p-Toluenesulfonate single crystal. Opt. Mater. 37, 267–276 (2014)
T. Thilak, M. Ahamed, G. Vinitha, Third order nonlinear optical properties of potassium dichromate single crystals by Z-scan technique. Optik Int. J. Light Electron Opt. 124, 4716–4720 (2013)
A. Arunkumar, P. Ramasamy, Bulk single crystals of ammonium acid phthalate grown by the Sankaranarayanan–Ramasamy method for optical limiting applications. J. Cryst. Growth 401, 195–199 (2014)
M. Krishna Kumar, S. Sudhahar, P. Pandi, G. Bhagavannarayana, R. Mohan Kumar, Studies of the structural and third-order nonlinear optical properties of solution grown 4-hydroxy-3-methoxy-4′-N′-methylstilbazolium tosylate monohydrate crystals. Opt. Mater. 36, 988–995 (2014)
F. Li, N. Zong, F. Zhang, J. Yang, F. Yang, Q. Peng et al., Investigation of third-order optical nonlinearity in KBe2BO3F2 crystal by Z-scan. Appl. Phys. B 108, 301–305 (2012)
Y. Zhou, E. Wang, J. Peng, J. Liu, C. Hu, R. Huang et al., Synthesis and the third-order optical nonlinearities of two novel charge-transfer complexes of a heteropoly blue type (C9H7NO)4 H7PMo12O40·3H2O (C9H7NO = quinolin-8-ol) and (phen)3 H7PMo12O40·CH3CN·H.2O (phen = 1,10-phenanthroline), Polyhedron, 18,1419–1423 (1999)
D. Wang, T. Li, S. Wang, J. Wang, Z. Wang, X. Xu, F. Zhang, Study on nonlinear refractive properties of KDP and DKDP crystals. RSC Adv. 6, 14490–14495 (2016)
Acknowledgements
The authors thank DST-SERB for financial support in the Grant No. SB/EMQ-015/2013. The authors acknowledge Prof. S. Kalainathan (Centre for Crystal Growth) and D. Rajan Babu (School of Advanced Sciences), VIT University, Vellore, Tamilnadu, India for providing the Z-scan, LDT, and refractive index measurements.
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Vediyappan, S., Arumugam, R., Pichan, K. et al. Crystal growth and characterization of semi-organic 2-amino-5-nitropyridinium bromide (2A5NPBr) single crystals for third-order nonlinear optical (NLO) applications. Appl. Phys. A 123, 780 (2017). https://doi.org/10.1007/s00339-017-1394-3
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DOI: https://doi.org/10.1007/s00339-017-1394-3