Abstract
A collection of 35 metallic artefacts comprising various typologies, some of which can be attributed to the Bronze Age and others to later periods, were studied to provide detailed information on elemental composition, manufacturing techniques and preservation state. Elemental analysis by micro-EDXRF and SEM–EDS was performed to investigate the use of different alloys and to study the presence of microstructural heterogeneities, as inclusions. X-ray radiography, optical microscopy and SEM–EDS were used to investigate manufacturing techniques and degradation features. Results showed that most of the artefacts were produced in a binary bronze alloy (Cu–Sn) with 10–15 wt% Sn and a low concentration of impurities. Other artefacts were produced in copper or in brass, the latest with varying contents of Zn, Sn and Pb. A variety of inclusions in the metal matrices were also found, some related to specific types of alloys, as (Cu–Ni)S2 in coppers, or ZnS in brasses. Microstructural observations revealed that the majority of the artefacts were subjected to cycles of thermomechanical processing after casting, being evident that among some artefacts different parts were subjected to distinct treatments. The radiographic images revealed structural heterogeneities related to local corrosion processes and fissures that seem to have developed in wear-tension zones, as in the handle of some daggers. Radiographic images were also useful to detect the use of different materials in one particular brass artefact, revealing the presence of a possible Cu–Sn solder.
Similar content being viewed by others
References
P.T. Craddock, Early Metal Mining and Production (The University Press, Cambridge, 1995)
M.L. Wayman, Mater. Charact. 45, 259 (2000)
J. Fonte, A.M.S. Bettencourt, E. Figueiredo, Estudos do Quaternário 9, 17 (2013)
R. Vilaça, Aspectos do povoamento da Beira Interior (Centro e Sul) nos Finais da Idade do Bronze (Trabalhos de Arqueologia 9—Instituto Português do Património Arquitectónico e Arqueológico, Lisboa, 1995)
A.M.S. Bettencourt, in Existe um Idade do Bronze Atlântico?, ed. by S.O. Jorge (Instituto Português de Arqueologia, Lisboa, 1998), p. 18
J. Castro Nunes, F. Bragança Gil, J.C. Senna-Martinez, F. Guerra, Artefacto metálico recolhido na Casa da Orca da Cunha Baica, concelho de Mangualde. Actas do I Colóquio Arqueológico de Viseu (Governo Civil do Distrito de Viseu, Viseu, 1989), p. 61
J. Loureiro, E. Figueiredo, R.J.C. Silva, M.F. Araújo, J. Fonte, A.M.S. Bettencourt, Estudos do Quaternário 11, 59 (2014)
I. Montero-Ruíz, A. Perea, in Metals and Mines: Studies in Archaeometallurgy, ed. by S. La Niece, D. Hook, P. Craddock (Archetype Publications, London, 2007), p. 136
P. Valério, M.F. Araújo, A. Canha, Nucl. Instrum. Methods B 263, 477 (2007)
E. Figueiredo, R.J.C. Silva, J.C. Senna-Martinez, M.F. Araújo, F.M. Braz Fernandes, L.J.I. Vaz, J. Archaeol. Sci. 37, 1623 (2010)
E. Figueiredo, P. Valério, M.F. Araújo, R.J.C. Silva, A.M. Monge Soares, X-Ray Spectrom. 40, 325 (2011)
E. Figueiredo, M.F. Araújo, R.J.C. Silva, R. Vilaça, Nucl. Instrum. Methods B 296, 26 (2013)
N. Schiavon, A. Celauro, M. Manso, A. Brunetti, F. Susanna, Appl. Phys. A 113, 865 (2013)
A. Celauro, N. Schiavon, A. Brunetti, L.-I. Mandredi, F. Susanna, A. Dekayir, V. Grazini, D. Pargny, D. Ferro, Appl. Phys. A 114, 711 (2014)
P. Valério, R.J.C. Silva, A.M.M. Soares, M.F. Araújo, A.P. Gonçalves, R.M. Soares, Nucl. Instrum. Methods B 358, 117 (2015)
P.T. Craddock, N.D. Meeks, Archaeometry 29, 187 (1987)
C. Carvalho, F.S. Lemos, C. Meireles, Conjunto Mineiro Romano em Montalegre. Actas das XVI Jornadas sobre a Função Social do Museu (Câmara Municipal e Ecomuseu do Barroso, Montalegre, 2006), p. 147
C.P. Thornton, C.E. Ehlers, Inst. Archaeo-Metall. Stud. 23, 3 (2003)
P.T. Craddock, in 2000 Years of Zinc and Brass, ed. by P.T. Craddock (British Museum Occasional Paper 50, British Museum, London, 1990), p. 1
T. Rehren, M. Martinón-Torres, in Archaeology, History and science: Integrating approaches to ancient materials, ed. by M. Martinón-Torres, T. Rehren (Left Coast Press, Walnut Creek, 2008), p. 167
D. Dungworth, J. Archaeol. Sci. 24, 901 (1997)
J. Bayley, in 2000 Years of Zinc and Brass, ed. by P.T. Craddock (British Museum Occasional Paper 50, British Museum, London, 1990), p. 7
H. Bronk, S. Röhrs, A. Bjeoumikhov, N. Langhoff, J. Schmalz, R. Wedell, H.E. Gorny, A. Herold, U. Waldschläger, Fresenius J. Anal. Chem. 371, 307 (2001)
E. Figueiredo, R.J.C. Silva, M.F. Araújo, J.C. Senna-Martinez, Microchim. Acta 168, 283 (2010)
E. Figueiredo, R.J.C. Silva, M.F. Araújo, F.M.B. Fernandes, Microsc. Microanal. 19, 1248 (2013)
D.A. Scott, Metallography and Microstructure of Ancient and Historic Metals (The Getty Conservation Institute & Archetype Books, Los Angeles, 1991), p. 69
P.C. Gutiérrez Neira, A. Zucchiatti, I. Montero-Ruiz, R. Vilaça, C. Bottanini, M. Gener, A. Climent-Font, Nucl. Instrum. Methods B 269, 3082 (2011)
N. Kallithrakas-Kontos, A.A. Katsanos, J. Touratsoglu, Nucl. Instrum. Methods B 171, 342 (2000)
A. Giumlia-Mair, E.J. Keall, A.N. Shugar, S. Stock, J. Archaeol. Sci. 29, 195 (2002)
E. Figueiredo, J.C. Senna-Martinez, R.J.C. Silva, M.F. Araújo, Mater. Manuf. Process. 24, 949 (2009)
L. Robbiola, J.M. Blengino, C. Fiaud, Corros. Sci. 12, 2083 (1998)
H.H. Coghlan, Notes on the Metallurgy of Copper and Bronze in the Old World (The University Press, Oxford, 1975)
H. Maryon, Am. J. Archaeol. 53, 93 (1949)
Acknowledgments
This work was funded by FEDER funds through the COMPETE 2020 Programme and National Funds through FCT—Fundação para a Ciência e Tecnologia under the project UID/CTM/50025/2013 to CENIMAT/I3N. C2TN/IST authors gratefully acknowledge the FCT support through the UID/Multi/04349/2013 project. EF acknowledges FCT for the grant SFRH/BPD/97360/2013. JF acknowledge FCT for the grant SFRH/BD/65143/2009. Part of this project has been done in the framework of the FCT project ENARDAS (PTDC/HISARQ/112983/2009).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Loureiro, J., Figueiredo, E., Silva, R.J.C. et al. Metal alloys, matrix inclusions and manufacturing techniques of Moinhos de Golas collection (North Portugal): a study by micro-EDXRF, SEM–EDS, optical microscopy and X-ray radiography. Appl. Phys. A 122, 820 (2016). https://doi.org/10.1007/s00339-016-0354-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-016-0354-7